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transitionsYang, Q.*; Yang, X.*; Wang, Y.*; Fei, Y.*; Li, F.*; Zheng, H.*; Li, K.*; Han, Y.*; Hattori, Takanori; Zhu, P.*; et al.
Nature Communications (Internet), 15, p.7778_1 - 7778_9, 2024/09
Times Cited Count：9 Percentile：88.46(Multidisciplinary Sciences)Luminescent materials that simultaneously embody bright singlet and triplet excitons hold great potential in optoelectronics, signage, and information encryption. However, achieving high-performance white-light emission is severely hampered by their inherent unbalanced contribution of fluorescence and phosphorescence. Herein, we address this challenge by pressure treatment engineering via hydrogen bonding cooperativity effect to realize the mixture of n-- transitions, where the triplet state emission was boosted from 7% to 40% in isophthalic acid (IPA). A superior white-light emission based on hybrid fluorescence and phosphorescence was harvested in pressure-treated IPA, and the photoluminescence quantum yield was increased to 75% from the initial 19% (blue-light emission). In-situ high-pressure IR spectra, X ray diffraction, and neutron diffraction reveal continuous strengthening of the hydrogen bonds with the increase of pressure. Furthermore, this enhanced hydrogen bond is retained down to the ambient conditions after pressure treatment, awarding the targeted IPA efficient intersystem crossing for balanced singlet/triplet excitons population and resulting in efficient white-light emission. This work not only proposes a route for brightening triplet states in organic small molecule, but also regulates the ratio of singlet and triplet excitons to construct high-performance white-light emission.
Baccou, J.*; Glantz, T.*; Ghione, A.*; Sargentini, L.*; Fillion, P.*; Damblin, G.*; Sueur, R.*; Iooss, B.*; Fang, J.*; Liu, J.*; et al.
Nuclear Engineering and Design, 421, p.113035_1 - 113035_16, 2024/05
Times Cited Count：6 Percentile：97.32(Nuclear Science & Technology)
; Bandgap narrowing, metallization, and remarkable enhancement of photoelectric activityFang, Y.*; Kong, L.*; Wang, R.*; Zhang, Z.*; Li, Z.*; Wu, Y.*; Bu, K.*; Liu, X.*; Yan, S.*; Hattori, Takanori; et al.
Materials Today Physics (Internet), 34, p.101083_1 - 101083_7, 2023/05
Times Cited Count：8 Percentile：74.51(Materials Science, Multidisciplinary)The layered van der Waals halides are particularly sensitive to external pressure, suggesting a feasible route to pinpoint their structure with extraordinary behavior. However, a very sensitive pressure response usually lead to a detrimental phase transition and/or lattice distortion, making the approach of materials manipulation in a continuous manner remain challenging. Here, the extremely weak interlayer coupling and high tunability of layered RhI crystals are observed. A pressure-driven phase transition occurs at a moderate pressure of 5 GPa, interlinking to a change of layer stack mode. Strikingly, such a phase transition does not affect the tendency of quasi-linear bandgap narrowing, and a metallization with an ultra-broad tunability of 1.3 eV redshift is observed at higher pressures. Moreover, the carrier concentration increases by 4 orders of magnitude at 30 GPa, and the photocurrent enhances by 5 orders of magnitude at 7.8 GPa. These findings create new opportunities for exploring, tuning, and understanding the van der Waals halides by harnessing their unusual feature of a layered structure, which is promising for future devices based on materials-by-design that are atomically thin.
H - CF cocrystal towards graphane structureWang, Y.*; Dong, X.*; Tang, X.*; Zheng, H.*; Li, K.*; Lin, X.*; Fang, L.*; Sun, G.*; Chen, X.*; Xie, L.*; et al.
Angewandte Chemie; International Edition, 58(5), p.1468 - 1473, 2019/01
Times Cited Count：51 Percentile：83.96(Chemistry, Multidisciplinary)Pressure-induced polymerization (PIP) of aromatics is a novel method to construct sp
-carbon frameworks, and nanothreads with diamond-like structures were synthesized by compressing benzene and its derivatives. Here by compressing benzene-hexafluorobenzene cocrystal(CHCF), we identified H-F-substituted graphane with a layered structure in the PIP product. Based on the crystal structure determined from the in situ neutron diffraction and the intermediate products identified by the gas chromatography-mass spectrum, we found that at 20 GPa CHCF forms tilted columns with benzene and hexafluorobenzene stacked alternatively, which leads to a [4+2] polymer, and then transfers to short-range ordered hydrogenated-fluorinated graphane. The reaction process contains [4+2] Diels-Alder, retro-Diels-Alder, and 1-1' coupling, and the former is the key reaction in the PIP. Our studies confirmed the elemental reactions of the CHCF for the first time, which provides a novel insight into the PIP of aromatics.
isobars from the 
island of inversionMorales, A. I.*; Benzoni, G.*; Watanabe, H.*; Tsunoda, Yusuke*; Otsuka, T.*; Nishimura, Shunji*; Browne, F.*; Daido, R.*; Doornenbal, P.*; Fang, Y.*; et al.
Physics Letters B, 765, p.328 - 333, 2017/02
Times Cited Count：38 Percentile：92.42(Astronomy & Astrophysics)
NiMorales, A. I.*; Benzoni, G.*; Watanabe, H.*; Nishimura, Shunji*; Browne, F.*; Daido, R.*; Doornenbal, P.*; Fang, Y.*; Lorusso, G.*; Patel, Z.*; et al.
Physical Review C, 93(3), p.034328_1 - 034328_14, 2016/03
Times Cited Count：26 Percentile：83.44(Physics, Nuclear)
Mn; Probing collectivity up to N=44 in Fe isotopic chainBenzoni, G.*; Morales, A. I.*; Watanabe, H.*; Nishimura, Shunji*; Coraggio, L.*; Itaco, N.*; Gargano, A.*; Browne, F.*; Daido, R.*; Doornenbal, P.*; et al.
Physics Letters B, 751, p.107 - 112, 2015/12
Times Cited Count：20 Percentile：75.34(Astronomy & Astrophysics)
spectroscopy of the even-even nucleus 
PtLi, G. S.*; Liu, M. L.*; Zhou, X. H.*; Zhang, Y. H.*; Liu, Y. X.*; Zhang, N. T.*; Hua, W.*; Zheng, Y. D.*; Fang, Y. D.*; Guo, S.*; et al.
Physical Review C, 89(5), p.054303_1 - 054303_9, 2014/05
Times Cited Count：5 Percentile：36.43(Physics, Nuclear)High-spin states of Pt have been reinvestigated using the 
Yb(
O, 4
) reaction at a beam energy of 88 MeV. The previously known positive parity band associated with the 
(
being 
or 
) configuration has been revised and extended significantly. A new negative parity band has been established and proposed to be based on the 
configuration. Possible structure evolution of the yrast line from predominantly vibrational to rotational with increasing spin is discussed with the help of E
over spin curves. Additionally, calculations of Total Routhian surfaces have been performed to investigate the band properties.
Walsh, M.*; Andrew, P.*; Barnsley, R.*; Bertalot, L.*; Boivin, R.*; Bora, D.*; Bouhamou, R.*; Ciattaglia, S.*; Costley, A. E.*; Counsell, G.*; et al.
Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 8 Pages, 2011/03
bands in 
AuZhang, Y. H.*; Zhou, X. H.*; He, J. J.*; Liu, Z.*; Fang, Y. D.*; Guo, W. T.*; Lei, X. G.*; Guo, Y. X.*; Ndontchueng, M. M.*; Ma, L.*; et al.
International Journal of Modern Physics E, 15(7), p.1437 - 1445, 2006/10
Times Cited Count：3 Percentile：27.66(Physics, Nuclear)Search for low-spin signature inversion in the bands in odd-odd Au have been made through in-beam -ray spectroscopy techniques. The bands in the three nuclei have been identified and extended up to high-spin states. In particlular, the interband connection between the band and the ground-state band in 
Au have been established, leading to a firm spin-and-parity assignment for the band. The low-spin signature inversion is found in the bands in Au.
