Iron coupled with hydroxylamine turns on the "switch" for free radical degradation of organic pollutants under high pH conditions

Tian, Q.*; Feng, L.*; Wu, C.*; Wen, J.*; Qiu, X.*; Tanaka, Kazuya; Onuki, Toshihiko*; Yu, Q.*

Journal of Colloid and Interface Science, 669, p.1006 - 1014, 2024/09

https://doi.org/10.1016/j.jcis.2024.05.021

Transport model comparison studies of intermediate-energy heavy-ion collisions

Walter, H.*; Colonna, M.*; Cozma, D.*; Danielewicz, P.*; Ko, C. M.*; Kumar, R.*; Ono, Akira*; Tsang, M. Y. B*; Xu, J.*; Zhang, Y.-X.*; et al.

Progress in Particle and Nuclear Physics, 125, p.103962_1 - 103962_90, 2022/07

https://doi.org/10.1016/j.ppnp.2022.103962

Transport models are the main method to obtain physics information on the nuclear equation of state and in-medium properties of particles from low to relativistic-energy heavy-ion collisions. The Transport Model Evaluation Project (TMEP) has been pursued to test the robustness of transport model predictions to reach consistent conclusions from the same type of physical model. To this end, calculations under controlled conditions of physical input and set-up were performed by the various participating codes. These included both calculations of nuclear matter in a periodic box, which test individual ingredients of a transport code, and calculations of complete collisions of heavy ions. Over the years, five studies were performed within this project. They show, on one hand, that in box calculations the differences between the codes can be well understood and a convergence of the results can be reached. These studies also highlight the systematic differences between the two families of transport codes, known under the names of Boltzmann-Uehling-Uhlenbeck (BUU) and Quantum Molecular Dynamics (QMD) type codes. On the other hand, there still exist substantial differences when these codes are applied to real heavy-ion collisions. The results of transport simulations of heavy-ion collisions will have more significance if codes demonstrate that they can verify benchmark calculations such as the ones studied in these evaluations.

Synthesis and characterisation of a new graphitic C-S compound obtained by high pressure decomposition of CS

Klotz, S.*; Baptiste, B.*; Hattori, Takanori; Feng, S. M.*; Jin, Ch.*; Bneut, K.*; Guigner, J. M.*; Estve, I.*

Carbon, 185, p.491 - 500, 2021/11

https://doi.org/10.1016/j.carbon.2021.09.048

Carbon disulphide (CS) is one of the simplest molecular systems made of double covalent bonds. Under high pressure, the molecular structure is expected to break up to form extended crystalline or polymeric solids. Here we show that by compression at 300 K to approximately 10 GPa using large-volume high pressure techniques, an instantaneous reaction leads to a mixture of pure sulphur and a well-defined compound with stoichiometry close to CS which can be recovered to ambient pressure. We present neutron and X-ray diffraction as well as Raman data which show that this material consists of sulphur bonded to sp graphite layers of nanometric dimensions. The compound is a semiconductor with a gap of 45 meV, as revealed by temperature dependent resistivity measurements, and annealing at temperatures above 200C allow to reduce its sulphur content up to CS. Its structural and electronic properties are fundamentally different to "Bridgman black" reported from previous high pressure experiments on CS.

Enhancement of fatigue resistance by overload-induced deformation twinning in a CoCrFeMnNi high-entropy alloy

Lam, T.-N.*; Lee, S. Y.*; Tsou, N.-T.*; Chou, H.-S.*; Lai, B.-H.*; Chang, Y.-J.*; Feng, R.*; Kawasaki, Takuro; Harjo, S.; Liaw, P. K.*; et al.

Acta Materialia, 201, p.412 - 424, 2020/12

https://doi.org/10.1016/j.actamat.2020.10.016

Comparison of heavy-ion transport simulations; Collision integral with pions and resonances in a box

Ono, Akira*; Xu, J.*; Colonna, M.*; Danielewicz, P.*; Ko, C. M.*; Tsang, M. B.*; Wang, Y,-J.*; Wolter, H.*; Zhang, Y.-X.*; Chen, L.-W.*; et al.

Physical Review C, 100(4), p.044617_1 - 044617_35, 2019/10

AA2019-0025.pdf:2.76MB

https://doi.org/10.1103/PhysRevC.100.044617

International comparison of heavy-ion induced reaction models were discussed in the international conference "Transport2017" held in April 2017. Owing to their importance for safety assessment of heavy-ion accelerators and dosimetry of astronauts, various models to simulate heavy-ion induced reaction models are developed. This study is intended to clarify the difference among them to pinpoint their problems. In the comparison study, 320 protons and neutrons were packed in a 20-fm-large cube to calculate the number and energies of collisions during the time evolution. The author contributed to this study by running calculation using JQMD (JAERI Quantum Molecular Dynamics). This study showed that time step in the calculation is one of the biggest causes of the discrepancies. For example, the calculation by JQMD comprises 1-fm/c time steps, each of which is composed of transport, scattering and decay phases. Therefore a sequence of scattering, and decay followed by another scattering in 1 fm/c cannot be considered. Moreover, in JQMD particles are labeled by sequential numbers and scattering reactions are simulated by the order. Therefore scattering between low ID numbers, that between high ID numbers and that between the first (low ID) pair is overlooked in JQMD. Above indications obtained in this study must be kept in our mind for future JQMD upgrades.

Comparison of heavy-ion transport simulations; Collision integral in a box

Zhang, Y.-X.*; Wang, Y,-J.*; Colonna, M.*; Danielewicz, P.*; Ono, Akira*; Tsang, M. B.*; Wolter, H.*; Xu, J.*; Chen, L.-W.*; Cozma, D.*; et al.

Physical Review C, 97(3), p.034625_1 - 034625_20, 2018/03

https://doi.org/10.1103/PhysRevC.97.034625

International comparison of heavy-ion induced reaction models were discussed in the international conference "Transport2017" held in April 2017. Owing to their importance for safety assessment of heavy-ion accelerators and dosimetry of astronauts, various models to simulate heavy-ion induced reaction models are developed. This study is intended to clarify the difference among them to pinpoint their problems. In the comparison study, 320 protons and 320 neutrons were packed in a 20-fm-large cube to calculate the number of particle-particle collisions as well as the energies of collisions during the time evolution. In addition to the calculation, their algorithms were compared. The author contributed to this study by running calculation using JQMD (JAERI Quantum Molecular Dynamics). The results were compared with those calculated by the other 15 codes from over the world. Algorithm comparison showed that JQMD calculates collision probabilities from protons at first and collisions by neutrons are simulated later, which might be unreasonable. On the other hand, it was clarified that the calculation by JQMD agrees with those by the others. Despite the fact that some codes deviate from the average by a factor of 2, JQMD exhibited stable performance.

Li(Zn,Mn)As as a new generation ferromagnet based on a I-II-V semiconductor

Deng, Z.*; Jin, C. Q.*; Liu, Q. Q.*; Wang, X. C.*; Zhu, J. L.*; Feng, S. M.*; Chen, L. C.*; Yu, R. C.*; Arguello, C.*; Goko, Tatsuo*; et al.

Nature Communications (Internet), 2, p.1425_1 - 1425_5, 2011/08

https://doi.org/10.1038/ncomms1425

In a prototypical ferromagnet (Ga,Mn)As based on a III-V semiconductor, substitution of divalent Mn atoms into trivalent Ga sites leads to severely limited chemical solubility and metastable specimens available only as thin films. The doping of hole carriers via (Ga,Mn) substitution also prohibits electron doping. To overcome these difficulties, Masek et al. theoretically proposed systems based on a I-II-V semiconductor LiZnAs, where isovalent (Zn,Mn) substitution is decoupled from carrier doping with excess/deficient Li concentrations. Here we show successful synthesis of Li(ZnMn)As in bulk materials. We reported that ferromagnetism with a critical temperature of up to 50 K is observed in nominally Li-excess compounds, which have p-type carriers.