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Francisco, P. C. M.; Matsumura, Daiju; Kikuchi, Ryosuke*; Ishidera, Takamitsu; Tachi, Yukio
Environmental Science & Technology, 56(5), p.3011 - 3020, 2022/03
Times Cited Count:2 Percentile:7.36(Engineering, Environmental)Zhang, R.*; Nadeau, K.*; Gautier, E. A.*; Babay, P. A.*; Ramella, J. L.*; Virgolici, M.*; Serban, A. E.*; Fugaru, V.*; Kimura, Yoshiki; Venchiarutti, C.*; et al.
Geostandards and Geoanalytical Research, 46(1), p.43 - 56, 2021/11
Times Cited Count:10 Percentile:49.23(Geochemistry & Geophysics)Francisco, P. C. M.; Tachi, Yukio
ACS Earth and Space Chemistry (Internet), 4(12), p.2366 - 2377, 2020/12
Times Cited Count:4 Percentile:17.18(Chemistry, Multidisciplinary)Sugiura, Yuki; Tomura, Tsutomu*; Ishidera, Takamitsu; Doi, Reisuke; Francisco, P. C. M.; Shiwaku, Hideaki; Kobayashi, Toru; Matsumura, Daiju; Takahashi, Yoshio*; Tachi, Yukio
Journal of Radioanalytical and Nuclear Chemistry, 324(2), p.615 - 622, 2020/05
Times Cited Count:8 Percentile:48.12(Chemistry, Analytical)
and Si under anoxic and reducing conditions; Structural characteristics of ferrous silicate co-precipitatesFrancisco, P. C. M.; Mitsui, Seiichiro; Ishidera, Takamitsu; Tachi, Yukio; Doi, Reisuke; Shiwaku, Hideaki
Geochimica et Cosmochimica Acta, 270, p.1 - 20, 2020/02
Times Cited Count:23 Percentile:73.33(Geochemistry & Geophysics)Dei, Shuntaro; Tachi, Yukio; Amano, Yuki; Sugiura, Yuki; Francisco, P. C. M.; Takahashi, Yoshio*
no journal, ,
Francisco, P. C. M.; Shiwaku, Hideaki; Ishidera, Takamitsu; Tachi, Yukio
no journal, ,
The long-lived fission product Se-79 is a significant contributor to predicted radioactivity in geological repositories long after their closure. One possible retardation in repositories is by incorporation into Fe-sulfides like pyrite (FeS2). In this study, we clarify the role of polysulfides in the incorporation of Se into pyrite. Polysulfides are intermediate-oxidation sulfide species that are likely produced by diagenetic and microbial processes in repository host rocks. The present results show that reaction of Se(-II) with polysulfides resulted in the initial formation of elemental selenium. Aging at anoxic conditions led to the incorporation of Se into pyrite. These results highlight the role of polysulfides in retaining Se. We also investigate the effects of aging in air to determine the effects of changes in the redox conditions. The results show that oxidation did not affect Se retention.
Francisco, P. C. M.; Mitsui, Seiichiro; Ishidera, Takamitsu; Tachi, Yukio
no journal, ,
Francisco, P. C. M.; Ishidera, Takamitsu; Tachi, Yukio
no journal, ,
Dei, Shuntaro; Tachi, Yukio; Amano, Yuki; Francisco, P. C. M.; Sugiura, Yuki; Takahashi, Yoshio*
no journal, ,
no abstracts in English
Francisco, P. C. M.; Ishidera, Takamitsu; Shiwaku, Hideaki; Kikuchi, Ryosuke*; Tachi, Yukio
no journal, ,
Dei, Shuntaro; Sugiura, Yuki; Amano, Yuki; Francisco, P. C. M.; Takahashi, Yoshio*; Tachi, Yukio
no journal, ,
Uranium (U) is considered one of the important radionuclides for safety assessment of the geological disposal because U(VI) can form soluble carbonate complexes. Calcite is expected to precipitate as a secondary mineral in sedimentary rocks, and radionuclides migration may be retarded by incorporation into the calcite crystal structure. Although some laboratory experiments have reported U uptake by calcite, the distribution and chemical form of U in natural calcite is difficult to determine due to interference from coexisting elements. In this study, micro X-ray analyses were carried out on deep sedimentary rock samples to identify the distribution and chemical form of U in natural calcite.
Francisco, P. C. M.; Tachi, Yukio
no journal, ,
Francisco, P. C. M.; Matsumura, Daiju; Kikuchi, Ryosuke*; Ishidera, Takamitsu; Tachi, Yukio
no journal, ,
Dei, Shuntaro; Miyakawa, Kazuya; Sasamoto, Hiroshi; Tachi, Yukio; Amano, Yuki; Francisco, P. C. M.; Sugiura, Yuki; Takahashi, Yoshio*
no journal, ,
no abstracts in English
Francisco, P. C. M.; Kikuchi, Ryosuke*; Matsumura, Daiju; Shiwaku, Hideaki; Ishidera, Takamitsu; Tachi, Yukio
no journal, ,