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Sheng, J.*; Wang, L.*; Candini, A.*; Jiang, W.*; Huang, L.*; Xi, B.*; Zhao, J.*; Ge, H.*; Zhao, N.*; Fu, Y.*; et al.
Proceedings of the National Academy of Sciences of the United States of America, 119(51), p.e2211193119_1 - e2211193119_9, 2022/12
Yoshida, Shuhei*; Fu, R.*; Gong, W.; Ikeuchi, Takuto*; Bai, Y.*; Feng, Z.*; Wu, G.*; Shibata, Akinobu*; Hansen, N.*; Huang, X.*; et al.
IOP Conference Series; Materials Science and Engineering, 1249, p.012027_1 - 012027_6, 2022/08
Times Cited Count:0 Percentile:0.83Rathore, E.*; Juneja, R.*; Sarkar, D.*; Roychowdhury, S.*; Kofu, Maiko; Nakajima, Kenji; Singh, A. K.*; Biswas, K.*
Materials Today Energy (Internet), 24, p.100953_1 - 100953_9, 2022/03
Times Cited Count:12 Percentile:87.17(Chemistry, Physical)Zhang, P.*; Tang, X.*; Wang, Y.*; Wang, X.*; Gao, D.*; Li, Y.*; Zheng, H.*; Wang, Y.*; Wang, X.*; Fu, R.*; et al.
Journal of the American Chemical Society, 142(41), p.17662 - 17669, 2020/10
Times Cited Count:17 Percentile:70.69(Chemistry, Multidisciplinary)Solid-state topochemical polymerization (SSTP) is a promising method to construct functional crystalline polymeric materials, but in contrast to various reactions that happen in solution, only very limited types of SSTP reactions are reported. Diels-Alder (DA) and dehydro-DA (DDA) reactions are textbook reactions for preparing six-membered rings in solution but are scarcely seen in solid-state synthesis. Here, using multiple cutting-edge techniques, we demonstrate that the solid 1,4-diphenylbutadiyne (DPB) undergoes a DDA reaction under 10-20 GPa with the phenyl as the dienophile. The crystal structure at the critical pressure shows that this reaction is "distance-selected". The distance of 3.2 between the phenyl and the phenylethynyl facilitates the DDA reaction, while the distances for other DDA and 1,4-addition reactions are too large to allow the bonding. The obtained products are crystalline armchair graphitic nanoribbons, and hence our studies open a new route to construct the crystalline carbon materials with atomic-scale control.
Wu, P.*; Fan, F.-R.*; Hagihara, Masato*; Kofu, Maiko; Peng, K.*; Ishikawa, Yoshihisa*; Lee, S.*; Honda, Takashi*; Yonemura, Masao*; Ikeda, Kazutaka*; et al.
New Journal of Physics (Internet), 22(8), p.083083_1 - 083083_9, 2020/08
Times Cited Count:6 Percentile:55.6(Physics, Multidisciplinary)Thermoelectric material SnSe has aroused world-wide interests in the past years, and its inherent strong lattice anharmonicity is regarded as a crucial factor for its outstanding thermoelectric performance. However, the understanding of lattice anharmonicity in SnSe system remains inadequate, especially regarding how phonon dynamics are affected by this behavior. In this work, we present a comprehensive study of lattice dynamics on NaSnSeS by means of neutron total scattering, inelastic neutron scattering, Raman spectroscopy as well as frozen-phonon calculations. Lattice anharmonicity is evidenced by pair distribution function, inelastic neutron scattering and Raman measurements. By separating the effects of thermal expansion and multi-phonon scattering, we found that the latter is very significant in high-energy optical phonon modes. The strong temperature-dependence of these phonon modes indicate the anharmonicity in this system. Moreover, our data reveals that the linewidths of high-energy optical phonons become broadened with mild doping of sulfur. Our studies suggest that the thermoelectric performance of SnSe could be further enhanced by reducing the contributions of high-energy optical phonon modes to the lattice thermal conductivity via phonon engineering.
Queiser, M.*; Vogt, A.*; Seidlitz, M.*; Reiter, P.*; Togashi, Tomoaki*; Shimizu, Noritaka*; Utsuno, Yutaka; Otsuka, Takaharu*; Homma, Michio*; Petkov, P.*; et al.
Physical Review C, 96(4), p.044313_1 - 044313_13, 2017/10
Times Cited Count:5 Percentile:41.77(Physics, Nuclear)no abstracts in English
Shinohara, Koji; Kusama, Yoshinori; Takechi, Manabu; Morioka, Atsuhiko; Ishikawa, Masao*; Oyama, Naoyuki; Tobita, Kenji; Ozeki, Takahisa; Takeji, Satoru; Moriyama, Shinichi; et al.
Nuclear Fusion, 41(5), p.603 - 612, 2001/05
Times Cited Count:82 Percentile:90.53(Physics, Fluids & Plasmas)no abstracts in English
Kramer, G. J.; Iwase, Makoto; Kusama, Yoshinori; Morioka, Atsuhiko; Nemoto, Masahiro; Nishitani, Takeo; Shinohara, Koji; Takeji, Satoru; Tobita, Kenji; Ozeki, Takahisa; et al.
Nuclear Fusion, 40(7), p.1383 - 1396, 2000/07
Times Cited Count:46 Percentile:77.8(Physics, Fluids & Plasmas)no abstracts in English
Kusama, Yoshinori; Kramer, G. J.; Kimura, Haruyuki; Saigusa, Mikio*; Ozeki, Takahisa; Tobita, Kenji; Oikawa, Toshihiro; Shinohara, Koji; Kondoh, Takashi; Moriyama, Shinichi; et al.
Nuclear Fusion, 39(11Y), p.1837 - 1843, 1999/11
Times Cited Count:66 Percentile:87.09(Physics, Fluids & Plasmas)no abstracts in English
Kramer, G. J.; Cheng, C. Z.*; Fu, G. Y.*; Kusama, Yoshinori; Nazikian, R. M.*; Ozeki, Takahisa; Tobita, Kenji
Physical Review Letters, 83(15), p.2961 - 2964, 1999/10
Times Cited Count:24 Percentile:75.09(Physics, Multidisciplinary)no abstracts in English
Kusama, Yoshinori; Nazikian, R.*; Kramer, G. J.*; Kimura, Haruyuki; Saigusa, Mikio*; Ozeki, Takahisa; Fu, G. Y.*; Tobita, Kenji; Oikawa, Toshihiro; Shinohara, Koji; et al.
Fusion Energy 1998, 2, p.537 - 544, 1998/10
no abstracts in English
Kusama, Yoshinori; Kimura, Haruyuki; Ozeki, Takahisa; Saigusa, Mikio*; Kramer, G. J.*; Oikawa, Toshihiro; Moriyama, Shinichi; Nemoto, Masahiro; Fujita, Takaaki; Tobita, Kenji; et al.
Nuclear Fusion, 38(8), p.1215 - 1223, 1998/08
Times Cited Count:41 Percentile:76.77(Physics, Fluids & Plasmas)no abstracts in English