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Journal Articles

Electrochemical reaction mechanisms under various charge-discharge operating conditions for Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ in a lithium-ion battery

Konishi, Hiroaki*; Hirano, Tatsumi*; Takamatsu, Daiko*; Gunji, Akira*; Feng, X.*; Furutsuki, Sho*; Okumura, Takafumi*; Terada, Shohei*; Tamura, Kazuhisa

Journal of Solid State Chemistry, 262, p.294 - 300, 2018/06

https://doi.org/10.1016/j.jssc.2018.03.028

Times Cited Count：9 Percentile：49.17(Chemistry, Inorganic & Nuclear)

The potential in each state of charge (SOC) during charging of Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ is higher than that during discharging. To clarify the effect of chargedischarge operating conditions on the electrochemical reaction, Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ was charged and discharged under various charge-discharge operating ranges, and OCP, crystal structure, and oxidation states of the ransition metals were evaluated by electrochemical measurement, XRD, and XAFS. These results indicate that OCP, lattice parameters, and oxidation states of the transition metals of Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ in each SOC are not constant. The XRD results indicate that two phases, namely, LiNi $_{0.33}$ Mn $_{0.33}$ Co $_{0.33}$ O $_{2}$ -like and Li $_{2}$ MnO $_{3}$ -like, exist in Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ .

Journal Articles

Mechanisms responsible for two possible electrochemical reactions in Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ used for lithium ion batteries

Konishi, Hiroaki*; Hirano, Tatsumi*; Takamatsu, Daiko*; Gunji, Akira*; Feng, X.*; Furutsuki, Sho*; Okumura, Takafumi*; Terada, Shohei*; Tamura, Kazuhisa

Journal of Solid State Chemistry, 258, p.225 - 231, 2018/02

https://doi.org/10.1016/j.jssc.2017.10.024

Times Cited Count：8 Percentile：44.83(Chemistry, Inorganic & Nuclear)

Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ is known as one of the cathode electrode material for Li ion batteries and its structure during charge and discharge process was investigated using electrochemical method and X-ray diffraction. It was found that in the charge process the structure changes in the order of Li $_{2}$ MnO $_{3}$ , LiNi $_{0.33}$ Mn $_{0.33}$ Co $_{0.33}$ O $_{2}$ , and Li $_{2}$ MnO $_{3}$ . On the other hand, in the discharge process, the structure changes in the order of Li $_{2}$ MnO $_{3}$ and LiNi $_{0.33}$ Mn $_{0.33}$ Co $_{0.33}$ O $_{2}$ .

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Electrochemical reaction mechanisms under various charge-discharge operating conditions for LiNiMnCoO in a lithium-ion battery

Mechanisms responsible for two possible electrochemical reactions in LiNiMnCoO used for lithium ion batteries

Electrochemical reaction mechanisms under various charge-discharge operating conditions for Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ in a lithium-ion battery

Mechanisms responsible for two possible electrochemical reactions in Li $_{1.2}$ Ni $_{0.13}$ Mn $_{0.54}$ Co $_{0.13}$ O $_{2}$ used for lithium ion batteries