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Journal Articles

Mechanistic origin of grain size and oxygen interstitial effects on strain-induced $$alpha^{primeprime}$$ martensitic transformation in Ti-12Mo alloy

Chong, Y.*; Tsuru, Tomohito; Mitsuhara, Masatoshi*; Guo, B.*; Gholizadeh, R.*; Inoue, Koji*; Godfrey, A.*; Tsuji, Nobuhiro*

Communications Materials (Internet), 6, p.50_1 - 50_11, 2025/03

Strain-induced $$alpha^{primeprime}$$ martensitic phase transformation (SIMT) critically affects the mechanical properties of metastable $$beta$$ titanium alloys. In this study, the effects of $$beta$$ grain size and oxygen content on SIMT in a Ti-12wt.%Mo alloy were systematically investigated. It is found that SIMT is promoted by a decrease in grain size and in oxygen content. The mechanistic origins of the anomalous grain size dependency and the acute oxygen content dependency of SIMT are discussed based on multi-scale microstructural characterization and state-of-the-art simulations. Grain refinement does not raise the energy barrier for SIMT but rather provides more nucleation sites for strain-induced $$alpha^{primeprime}$$ martensite, thereby promoting SIMT in fine-grained Ti-12wt.%Mo alloy. In contrast, for the Ti-12wt.%Mo-0.3 wt.%O alloy, oxygen atoms substantially increase the energy barrier for SIMT, due to a change in the local configuration of oxygen atoms during the phase transformation. In addition, atom probe tomography reveals for the first time that oxygen atoms segregate at $$alpha^{primeprime}/beta$$ phase boundaries, thereby further restricting the growth of $$alpha^{primeprime}$$ martensite.

Journal Articles

Quantum spin wave excited from a Cr-Dy single-molecule magnet

Ling, B.-K.*; Chang, M.*; Zhai, Y.-Q.*; Deng, J.*; Kofu, Maiko*; Guo, H.*; Zhao, J.*; Fu, Z.*; Zheng, Y.-Z.*

Journal of the American Chemical Society, 147(13), p.10935 - 10942, 2025/03

 Times Cited Count:1 Percentile:83.04(Chemistry, Multidisciplinary)

Journal Articles

Direct observations of dynamic and reverse transformation of Ti-6Al-4V alloy and pure titanium

Guo, B.*; Chen, H.*; Chong, Y.*; Mao, W.; Harjo, S.; Gong, W.; Zhang, Z.*; Jonas, J. J.*; Tsuji, Nobuhiro*

Acta Materialia, 268, p.119780_1 - 119780_11, 2024/04

 Times Cited Count:10 Percentile:94.16(Materials Science, Multidisciplinary)

Journal Articles

Oxygen interstitials make metastable $$beta$$ titanium alloys strong and ductile

Chong, Y.*; Gholizadeh, R.*; Guo, B.*; Tsuru, Tomohito; Zhao, G.*; Yoshida, Shuhei*; Mitsuhara, Masatoshi*; Godfrey, A.*; Tsuji, Nobuhiro*

Acta Materialia, 257, p.119165_1 - 119165_14, 2023/09

 Times Cited Count:41 Percentile:98.38(Materials Science, Multidisciplinary)

Metastable $$beta$$ titanium alloys possess excellent strain-hardening capability, but suffer from a low yield strength. As a result, numerous attempts have been made to strengthen this important structural material in the last decade. Here, we explore the contributions of grain refinement and interstitial additions in raising the yield strength of a Ti-12Mo (wt.%) metastable $$beta$$ titanium alloy. Surprisingly, rather than strengthening the material, grain refinement actually lowers the ultimate tensile strength in this alloy. This unexpected and anomalous behavior is attributed to a significant enhancement in strain-induced $$alpha^{primeprime}$$ martensite phase transformation, where in-situ synchrotron X-ray diffraction analysis reveals, for the first time, that this phase is much softer than the parent $$beta$$ phase. Instead, a combination of both oxygen addition and grain refinement is found to realize an unprecedented strength-ductility synergy in a Ti-12Mo-0.3O (wt.%) alloy. The advantageous effect of oxygen solutes in this ternary alloy is twofold. Firstly, solute oxygen largely suppresses strain-induced transformation to the $$alpha^{primeprime}$$ martensite phase, even in a fine-grained microstructure, thus avoiding the softening effect of excessive amounts of $$alpha^{primeprime}$$ martensite. Secondly, oxygen solutes readily segregate to twin boundaries, as revealed by atom probe tomography. This restricts the growth of $${332}langle113rangle$$ deformation twins, thereby promoting more extensive twin nucleation, leading to enhanced microstructural refinement. The insights from our work provide a cost-effective rationale for the design of strong yet tough metastable $$beta$$ titanium alloys, with significant implications for more widespread use of this high strength-to-weight structural material.

Journal Articles

Unexpected dynamic transformation from $$alpha$$ phase to $$beta$$ phase in zirconium alloy revealed by in-situ neutron diffraction during high temperature deformation

Guo, B.*; Mao, W.; Chong, Y.*; Shibata, Akinobu*; Harjo, S.; Gong, W.; Chen, H.*; Jonas, J. J.*; Tsuji, Nobuhiro*

Acta Materialia, 242, p.118427_1 - 118427_11, 2023/01

 Times Cited Count:12 Percentile:68.62(Materials Science, Multidisciplinary)

Journal Articles

Ultrahigh yield strength and large uniform elongation achieved in ultrafine-grained titanium containing nitrogen

Chong, Y.*; Tsuru, Tomohito; Guo, B.*; Gholizadeh, R.*; Inoue, Koji*; Tsuji, Nobuhiro*

Acta Materialia, 240, p.118356_1 - 118356_15, 2022/11

 Times Cited Count:36 Percentile:94.74(Materials Science, Multidisciplinary)

In this study, we systematically investigated the influences of nitrogen content and grain size on the tensile properties and deformation behaviors of titanium at room temperature. By high-pressure torsion and annealing, we obtained ultrafine-grained (UFG) Ti-0.3wt.%N alloy with a fully recrystallized microstructure, which combined an unprecedented synergy of ultrahigh yield strength (1.04 GPa) and large uniform elongation (10%). The hardening and strain-hardening mechanisms of Ti-0.3wt.%N alloy were comprehensively studied via deformation substructure observation and first-principles calculations. It is revealed that the contributions of nitrogen to the excellent strength/ductility balance in UFG Ti-0.3wt.%N were twofold. On one hand, nitrogen atoms inside the grains strongly impeded the motion of $$<a>$$ dislocations on prismatic plane due the shuffling of nitrogen from octahedral to hexahedral site, giving rise to a six-fold increase in the friction stress than pure Ti. Moreover, the greatly reduced stacking fault energy difference between prismatic and pyramidal planes in Ti-0.3wt.%N alloy facilitated an easier activation of $$<c+a>$$ dislocations, which contributed to an enhanced strain-hardening rate. On the other hand, some nitrogen atoms segregated near the grain boundaries, a phenomenon discovered in $$alpha$$-titanium for the first time. These segregated nitrogen atoms served as an additional contributor to the yield strength of UFG Ti-0.3wt.%N, by raising the barrier against dislocation slip transfer between grains. Our experimental and theoretical calculation work provide insights for the design of affordable high strength titanium without a large sacrifice of ductility, shedding lights on a more widespread use of this high strength to weight material.

Journal Articles

First observation of the decay of the 13/2$$^+$$ isomer in $$^{183}$$Hg and $$B$$(${it M}$2) systematics of neutron transitions across the nuclear chart

Huang, H.*; Zhang, W. Q.*; Andreyev, A. N.; Liu, Z.*; Seweryniak, D.*; Li, Z. H.*; Guo, C. Y.*; Barzakh, A. E.*; Van Duppen, P.*; Andel, B.*; et al.

Physics Letters B, 833, p.137345_1 - 137345_8, 2022/10

 Times Cited Count:1 Percentile:17.31(Astronomy & Astrophysics)

Journal Articles

The $$^{59}$$Fe(n,$$gamma$$)$$^{60}$$Fe cross section from the surrogate ratio method and its effect on the $$^{60}$$Fe nucleosynthesis

Yan, S. Q.*; Li, X. Y.*; Nishio, Katsuhisa; Lugaro, M.*; Li, Z. H.*; Makii, Hiroyuki; Pignatari, M.*; Wang, Y. B.*; Orlandi, R.; Hirose, Kentaro; et al.

Astrophysical Journal, 919(2), p.84_1 - 84_7, 2021/10

 Times Cited Count:5 Percentile:33.27(Astronomy & Astrophysics)

Journal Articles

Ultra-fine CeO$$_{2}$$ particles triggered strong interaction with LaFeO$$_{3}$$ framework for total and preferential CO oxidation

Zheng, Y.*; Xiao, H.*; Li, K.*; Wang, Y.*; Li, Y.*; Wei, Y.*; Zhu, X.*; Li, H.-W.*; Matsumura, Daiju; Guo, B.*; et al.

ACS Applied Materials & Interfaces, 12(37), p.42274 - 42284, 2020/09

 Times Cited Count:27 Percentile:70.49(Nanoscience & Nanotechnology)

Journal Articles

Magnetic-field and composition tuned antiferromagnetic instability in the quantum spin-liquid candidate NaYbO$$_2$$

Guo, J.*; Zhao, X.*; Kawamura, Seiko; Ling, L.*; Wang, J.*; He, L.*; Nakajima, Kenji; Li, B.*; Zhang, Z.*

Physical Review Materials (Internet), 4(6), p.064410_1 - 064410_7, 2020/06

 Times Cited Count:22 Percentile:65.03(Materials Science, Multidisciplinary)

Journal Articles

Spectroscopic and first-principles investigations of iodine species incorporation into ettringite; Implications for iodine migration in cement waste forms

Guo, B.*; Xiong, Y.*; Chen, W.*; Saslow, S. A.*; Kozai, Naofumi; Onuki, Toshihiko*; Dabo, I.*; Sasaki, Keiko*

Journal of Hazardous Materials, 389, p.121880_1 - 121880_11, 2020/05

 Times Cited Count:55 Percentile:89.33(Engineering, Environmental)

Journal Articles

Passive sweat collection and colorimetric analysis of biomarkers relevant to kidney disorders using a soft microfluidic system

Zhang, Y.*; Guo, H.*; Kim, S. B.*; Wu, Y.*; Ostojich, D.*; Park, S. H.*; Wang, X.*; Weng, Z.*; Li, R.*; Bandodkar, A. J.*; et al.

Lab on a Chip, 19(9), p.1545 - 1555, 2019/05

 Times Cited Count:189 Percentile:99.70(Biochemical Research Methods)

This paper introduces two important advances in recently reported classes of soft, skin-interfaced microfluidic systems for sweat capture and analysis: (1) a simple, broadly applicable means for collection of sweat that bypasses requirements for physical/mental exertion or pharmacological stimulation and (2) a set of enzymatic chemistries and colorimetric readout approaches for determining the concentrations of creatinine and urea in sweat, across physiologically relevant ranges. The results allow for routine, non-pharmacological capture of sweat across patient populations, such as infants and the elderly, that cannot be expected to sweat through exercise, and they create potential opportunities in the use of sweat for kidney disease screening/monitoring.

Journal Articles

The $$^{95}$$Zr($$n, gamma$$)$$^{96}$$Zr cross section from the surrogate ratio method and its effect on $$s$$-process nucleosynthesis

Yan, S. Q.*; Li, Z. H.*; Wang, Y. B.*; Nishio, Katsuhisa; Lugaro, M.*; Karakas, A. I.*; Makii, Hiroyuki; Mohr, P.*; Su, J.*; Li, Y. J.*; et al.

Astrophysical Journal, 848(2), p.98_1 - 98_8, 2017/10

 Times Cited Count:8 Percentile:28.75(Astronomy & Astrophysics)

Journal Articles

Uniaxial pressure effect on the magnetic ordered moment and transition temperatures in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ ($$T$$ = Co,Ni)

Tam, D. M.*; Song, Y.*; Man, H.*; Cheung, S. C.*; Yin, Z.*; Lu, X.*; Wang, W.*; Frandsen, B. A.*; Liu, L.*; Gong, Z.*; et al.

Physical Review B, 95(6), p.060505_1 - 060505_6, 2017/02

 Times Cited Count:24 Percentile:68.44(Materials Science, Multidisciplinary)

Journal Articles

Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning

Frandsen, B. A.*; Liu, L.*; Cheung, S. C.*; Guguchia, Z.*; Khasanov, R.*; Morenzoni, E.*; Munsie, T. J. S.*; Hallas, A. M.*; Wilson, M. N.*; Cai, Y.*; et al.

Nature Communications (Internet), 7, p.12519_1 - 12519_8, 2016/08

 Times Cited Count:37 Percentile:76.46(Multidisciplinary Sciences)

Journal Articles

Examination of the surrogate ratio method for the determination of the $$^{93}$$Zr(n,$$gamma$$)$$^{94}$$Zr cross section with $$^{90,92}$$Zr($$^{18}$$O,$$^{16}$$O)$$^{92,94}$$Zr reactions

Yan, S. Q.*; Li, Z. H.*; Wang, Y. B.*; Nishio, Katsuhisa; Makii, Hiroyuki; Su, J.*; Li, Y. J.*; Nishinaka, Ichiro; Hirose, Kentaro; Han, Y. L.*; et al.

Physical Review C, 94(1), p.015804_1 - 015804_5, 2016/07

 Times Cited Count:7 Percentile:46.14(Physics, Nuclear)

Journal Articles

Development of the evaluation methodology for the material relocation behavior in the core disruptive accident of sodium-cooled fast reactors

Tobita, Yoshiharu; Kamiyama, Kenji; Tagami, Hirotaka; Matsuba, Kenichi; Suzuki, Toru; Isozaki, Mikio; Yamano, Hidemasa; Morita, Koji*; Guo, L.*; Zhang, B.*

Journal of Nuclear Science and Technology, 53(5), p.698 - 706, 2016/05

AA2015-0794.pdf:2.46MB

 Times Cited Count:32 Percentile:93.52(Nuclear Science & Technology)

The in-vessel retention (IVR) of core disruptive accident (CDA) is of prime importance in enhancing safety characteristics of sodium-cooled fast reactors (SFRs). In the CDA of SFRs, molten core material relocates to the lower plenum of reactor vessel and may impose significant thermal load on the structures, resulting in the melt through of the reactor vessel. In order to enable the assessment of this relocation process and prove that IVR of core material is the most probable consequence of the CDA in SFRs, a research program to develop the evaluation methodology for the material relocation behavior in the CDA of SFRs has been conducted. This program consists of three developmental studies, namely the development of the analysis method of molten material discharge from the core region, the development of evaluation methodology of molten material penetration into sodium pool, and the development of the simulation tool of debris bed behavior.

Journal Articles

The Martian surface radiation environment; A Comparison of models and MSL/RAD measurements

Matthi$"a$, D.*; Ehresmann, B.*; Lohf, H.*; K$"o$hler, J.*; Zeitlin, C.*; Appel, J.*; Sato, Tatsuhiko; Slaba, T. C.*; Martin, C.*; Berger, T.*; et al.

Journal of Space Weather and Space Climate (Internet), 6, p.A13_1 - A13_17, 2016/03

 Times Cited Count:74 Percentile:92.73(Astronomy & Astrophysics)

The Radiation Assessment Detector (RAD) on the Mars Science Laboratory (MSL) has been measuring the radiation environment on the surface of Mars since August 6th 2012. In this work, several models such as GEANT4, PHITS, and HZETRN/OLTARIS are used to predict the radiation environment caused by galactic cosmic rays on Mars in order to compare and validate them with the experimental results. Although good agreement is found in many cases for GEANT4, PHITS and HZETRN/OLTARIS, some models still show large, sometimes order of magnitude, discrepancies in certain particle spectra. We have found that RAD data is helping make better choices of input parameters and physical models. These results help to predict dose rates for future manned missions as well as to perform shield optimization studies.

Journal Articles

Origin of the spin Seebeck effect in compensated ferrimagnets

Gepr$"a$gs, S.*; Kehlberger, A.*; Coletta, F.*; Qiu, Z.*; Guo, E.-J.*; Schulz, T.*; Mix, C.*; Meyer, S.*; Kamra, A.*; Althammer, M.*; et al.

Nature Communications (Internet), 7, p.10452_1 - 10452_6, 2016/02

 Times Cited Count:173 Percentile:97.41(Multidisciplinary Sciences)

Journal Articles

Development of assessment method for a self-leveling behavior of debris bed and analyses of experiments

Tagami, Hirotaka; Cheng, S.; Tobita, Yoshiharu; Guo, L.*; Zhang, B.*; Morita, Koji*

Proceedings of 22nd International Conference on Nuclear Engineering (ICONE-22) (DVD-ROM), 8 Pages, 2014/07

The object of this study is to develop new analytical methods to simulate unique phenomena in self-leveling behavior and implement it to SFR safety analysis code. The new methods are developed with assuming that the debris bed behaves as Bingham fluid from this feature. They are categorized into two main parts. The first part is particle interaction models to model the effect of particle-particle collisions. The second part is a large deformation method, which simulates Bingham fluid characteristic of debris bed. An experimental study of self-leveling behavior is analyzed to validate the new methods. The assessment results show that these methods provide a basis to develop analytical methods of self-leveling behavior of debris bed in the safety assessment of SFRs.

42 (Records 1-20 displayed on this page)