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Journal Articles

Fixed point observations and characterization of radioactive caesium in Tama river

Hagiwara, Kenta*; Ochi, Kotaro; Koike, Yuya*

Radioisotopes, 70(4), p.227 - 237, 2021/05

Behavior of radioactive caesium in river water and sediment in Tama river was investigated during 2012-2016. Concentrations of radioactive caesium in river water and sediment were decreased with time exponentially. Concentrations of suspended radioactive caesium, and radioactive caesium in sediment temporarily increased when sediments were resuspended due to rain. On the other hand, dissolved radioactive caesium was not easily impacted by this factor. Sequential extraction, elemental and crystal phase analysis were performed on the sediments and examined the chemical state of radioactive caesium as well as the adsorption mechanism. Radioactive caesium in sediment was present in a stable chemical form, and there is possibility that radioactive caesium was incorpolated in biotite.

Journal Articles

Single crystal growth and various electronic states in Yb-based compounds

Hirose, Yusuke*; Yoshiuchi, Shingo*; Nishimura, Naoto*; Sakaguchi, Junya*; Enoki, Kentaro*; Iwakawa, Ken*; Miura, Yasunao*; Sugiyama, Kiyohiro*; Onuki, Yoshichika; Settai, Rikio*; et al.

Journal of the Korean Physical Society, 62(12), p.1858 - 1861, 2013/06

 Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)

Journal Articles

Spin-orbital short-range order on a honeycomb-based lattice

Nakatsuji, Satoru*; Kuga, Kentaro*; Kimura, Kenta*; Satake, Ryuta*; Katayama, Naoyuki*; Nishibori, Eiji*; Sawa, Hiroshi*; Ishii, Rieko*; Hagiwara, Masayuki*; Bridges, F.*; et al.

Science, 336(6081), p.559 - 563, 2012/05

 Times Cited Count:121 Percentile:95.25(Multidisciplinary Sciences)

Frustrated magnetic materials can remain disordered to the lowest temperatures. Such is the case for Ba$$_3$$CuSb$$_2$$O$$_9$$, which is magnetically anisotropic at the atomic scale but curiously isotropic on mesoscopic length and time scales. We find that the frustration on the triangular lattice is imprinted in a nanostructured honeycomb lattice of Cu$$^{2+}$$ ions that resists a coherent static Jahn-Teller distortion. The resulting two-dimensional random-bond spin-1/2 system on the honeycomb lattice has a broad spectrum of spin-dimer like excitations and low-energy spin degrees of freedom that retain.

Journal Articles

Magnetic-field-induced metallic state in $$beta$$-US$$_2$$

Sugiyama, Kiyohiro*; Hirose, Yusuke*; Enoki, Kentaro*; Ikeda, Shugo*; Yamamoto, Etsuji; Tateiwa, Naoyuki; Haga, Yoshinori; Kida, Takanori*; Hagiwara, Masayuki*; Kindo, Koichi*; et al.

Journal of the Physical Society of Japan, 80(Suppl.A), p.SA104_1 - SA104_3, 2011/07

 Times Cited Count:3 Percentile:26.78(Physics, Multidisciplinary)

Journal Articles

Structural analysis of 1-ethyl-3-methylimidazolium bifluoride melt

Matsumoto, Kazuhiko*; Hagiwara, Rika*; Ito, Yasuhiko*; Kohara, Shinji*; Suzuya, Kentaro

Nuclear Instruments and Methods in Physics Research B, 199, p.29 - 33, 2003/01

 Times Cited Count:34 Percentile:88.13(Instruments & Instrumentation)

The structure of 1-ethyl-3-methylimidazolium bifluoride (EMImF$$cdot$$HF) melt has been analyzed at 333 K by a high-energy synchrotron X-ray diffraction method. The total correlation function of the EMImF$$cdot$$HF melt was similar to that of the solid state, indicating that not only the short-range but also the intermediate-range ordering in the solid are partially preserved in the liquid state. The intra-molecular F-F correlation in the anions clearly appears in the total correlation function of the EMImF$$cdot$$HF melt, whereas prominent peaks are not observed in the case of a room temperature molten salt, 1-ethyl-3-methylimidazolium fluorohydrogenate (EMImF$$cdot$$2.3HF).

Journal Articles

The Structures of alkylimidazolium fluorohydrogenate molten salts studied by high-energy X-ray diffraction

Hagiwara, Rika*; Matsumoto, Kazuhiko*; Tsuda, Tetsuya*; Ito, Yasuhiko*; Kohara, Shinji*; Suzuya, Kentaro; Matsumoto, Hajime*; Miyazaki, Yoshinori*

Journal of Non-Crystalline Solids, 312-314, p.414 - 418, 2002/10

 Times Cited Count:32 Percentile:85.30(Materials Science, Ceramics)

The structures of a series of XF$$^{.}$$2.3HF (X= 1-methylimidazolium (MI), 1-ethyl-3-methylimidazolium (EMI), 1-butyl-3-methylimidazolium (BMI), 1-hexyl-3-methyl-imidazolium (HMI)) room temperature molten salts have been investigated by high-energy synchrotron X-ray diffraction technique. The correlation peaks appeared in the total correlation function are mainly ascribed to intra-molecular correlation of alkylimidazolium cations. However, it is suggested that the peak at around 3.6 $$AA$$ is ascribed not only to intra-molecular but also inter-molecular correlation of the cation. The contribution of the latter is also supported by the first sharp diffraction peak of the total structure factor found at almost the same position as that of a Bragg peak in the simulated X-ray diffraction pattern of solid EMIF$$^{.}$$HF with a layered structure, corresponding to the layer separation of

Journal Articles

A Highly conductive RTMS; Alkylimidazolium fluorohydrogenates

Hagiwara, Rika*; Matsumoto, Kazuhiko*; Tsuda, Tetsuya*; Kohara, Shinji*; Suzuya, Kentaro; Ito, Yasuhiko*

Proceedings of 6th International Symposium on Molten Salts Chemistry and Technology (MS6), p.136 - 139, 2001/10

no abstracts in English

Oral presentation

Magnetic property of antiferromagnet UCd$$_{11}$$

Yamamoto, Etsuji; Hirose, Yusuke*; Enoki, Kentaro*; Mitamura, Katsuya*; Sugiyama, Kiyohiro*; Takeuchi, Tetsuya*; Hagiwara, Masayuki*; Kindo, Koichi*; Haga, Yoshinori; Settai, Rikio*; et al.

no journal, , 

no abstracts in English

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