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Journal Articles

Spectroscopic study of Np(V) oxidation to Np(VI) in 3 mol/dm$$^{3}$$ nitric acid at elevated temperatures

Ban, Yasutoshi; Hakamatsuka, Yasuyuki; Tsutsui, Nao; Urabe, Shunichi; Hagiya, Hiromichi; Matsumura, Tatsuro

Radiochimica Acta, 102(9), p.775 - 780, 2014/09

 Times Cited Count:3 Percentile:27.05(Chemistry, Inorganic & Nuclear)

Optical absorption spectra of Np in 3 mol/dm$$^{3}$$ nitric acid at elevated temperatures were measured using an optical glass cell with a water jacket having a light path of 1 cm, and molar extinction coefficients of Np(VI), $$varepsilon$$$$_{T}$$, were obtained at various temperature. The values of $$varepsilon$$$$_{T}$$ was found to decrease with increasing the temperature, and could be described by the equation $$varepsilon$$$$_{T}$$ = -0.14${it T}$+85.5, where ${it T}$ is the temperature. Oxidation of Np(V) to Np(VI) in 3 mol/dm$$^{3}$$ nitric acid at elevated temperatures was observed using the optical glass cell. Oxidation of Np(V) proceeded as pseudo-first order with respect to Np(V) concentration. The rate equation in the temperature range of 336-362 K was obtained as follows: -d[Np(V)]$$_{t}$$/dt = 2.2$$times$$10$$^{7}$$ exp[-65$$times$$10$$^{3}$$/(${it RT}$)][Np(V)]$$_{t}$$, where ${it R}$ and [Np(V)]$$_{t}$$ indicate the gas constant and Np(V) concentration at time ${it t}$, respectively.

Journal Articles

Separation and recovery of Cm from Cm-Pu mixed oxide samples containing Am impurity

Hayashi, Hirokazu; Hagiya, Hiromichi; Kim, S.-Y.*; Morita, Yasuji; Akabori, Mitsuo; Minato, Kazuo

Journal of Radioanalytical and Nuclear Chemistry, 296(3), p.1275 - 1286, 2013/06

 Times Cited Count:3 Percentile:28.43(Chemistry, Analytical)

$$^{244}$$Cm was separated and recovered as an oxalate from $$^{244}$$Cm-$$^{240}$$Pu mixed oxide which had been $$^{244}$$Cm oxide sample prepared 40 years ago. Plutonium ions were removed from the solution prepared by dissolution of $$^{244}$$Cm-$$^{240}$$Pu mixed oxide in nitric acid, by using an anion exchange resin column. Curium oxalate, a precursor compound of curium oxide, was prepared from the purified curium solution and supplied for the syntheses and measurements of the thermochemical properties of curium compounds.

Journal Articles

Extraction and flow sheet studies for U and Pu separation by N,N-di(2-ethyl)hexylbutanamide

Ban, Yasutoshi; Hagiya, Hiromichi; Sato, Makoto; Asakura, Toshihide; Morita, Yasuji

Proceedings of 3rd International ATALANTE Conference (ATALANTE 2008) (CD-ROM), 4 Pages, 2008/05

Since N,N-dialkylamide (monoamide) compounds extract tetravalent and hexavalent actinides, they have been proposed as alternative extractants to TBP. In the present work, numerical calculations for estimating separation performance of N,N-di(2-ethyl)hexyl-butanamide (D2EHBA) for U(VI) and Pu(IV) were carried out. A flow sheet was obtained which separate more than 99.9% of Pu(IV) from U(VI) by adjusting nitric acid concentration. Extraction properties of D2EHBA for macro concentrations of U (0.63-1.22 mol/dm$$^{3}$$(M)) and Pu (6.3 mM) were studied in a batch manner. D2EHBA diluted to 1.5 M by n-dodecane extracted up to 0.8 M of U(VI) without forming precipitation and third phase. Distribution ratios of Pu(IV) were relatively high compared with the ones obtained at tracer concentrations of Pu(IV).

Journal Articles

Applicability of a model predicting iodine-129 profile in a silver nitrate silica-gel column for dissolver off-gas treatment of fuel reprocessing

Mineo, Hideaki; Goto, Minoru; Iizuka, Masaru*; Fujisaki, Susumu; Hagiya, Hiromichi*; Uchiyama, Gunzo

Separation Science and Technology, 38(9), p.1981 - 2001, 2003/05

 Times Cited Count:17 Percentile:59.17(Chemistry, Multidisciplinary)

no abstracts in English

Oral presentation

Separation and recovery of Cm from Cm-Pu mixed oxide

Hayashi, Hirokazu; Hagiya, Hiromichi; Morita, Yasuji; Akabori, Mitsuo; Minato, Kazuo

no journal, , 

no abstracts in English

Oral presentation

R&D of MA separation processes for P&T system using ADS, 1; Research program

Matsumura, Tatsuro; Tsubata, Yasuhiro; Urabe, Shunichi; Ichimura, Seiji; Hagiya, Hiromichi; Tsujimoto, Kazufumi

no journal, , 

no abstracts in English

Oral presentation

R&D of MA separation processes for P&T system using ADS, 2; Solvent extraction process for MA/Ln separation

Matsumura, Tatsuro; Tsubata, Yasuhiro; Urabe, Shunichi; Shibata, Mitsunobu; Ichimura, Seiji; Hagiya, Hiromichi*; Tsujimoto, Kazufumi

no journal, , 

no abstracts in English

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