Brightening triplet excitons enable high-performance white-light emission in organic small molecules via integrating n-- transitions

Yang, Q.*; Yang, X.*; Wang, Y.*; Fei, Y.*; Li, F.*; Zheng, H.*; Li, K.*; Han, Y.*; Hattori, Takanori; Zhu, P.*; et al.

Nature Communications (Internet), 15, p.7778_1 - 7778_9, 2024/09

https://doi.org/10.1038/s41467-024-52196-7

Luminescent materials that simultaneously embody bright singlet and triplet excitons hold great potential in optoelectronics, signage, and information encryption. However, achieving high-performance white-light emission is severely hampered by their inherent unbalanced contribution of fluorescence and phosphorescence. Herein, we address this challenge by pressure treatment engineering via hydrogen bonding cooperativity effect to realize the mixture of n-- transitions, where the triplet state emission was boosted from 7% to 40% in isophthalic acid (IPA). A superior white-light emission based on hybrid fluorescence and phosphorescence was harvested in pressure-treated IPA, and the photoluminescence quantum yield was increased to 75% from the initial 19% (blue-light emission). In-situ high-pressure IR spectra, X ray diffraction, and neutron diffraction reveal continuous strengthening of the hydrogen bonds with the increase of pressure. Furthermore, this enhanced hydrogen bond is retained down to the ambient conditions after pressure treatment, awarding the targeted IPA efficient intersystem crossing for balanced singlet/triplet excitons population and resulting in efficient white-light emission. This work not only proposes a route for brightening triplet states in organic small molecule, but also regulates the ratio of singlet and triplet excitons to construct high-performance white-light emission.

PANDORA Project for the study of photonuclear reactions below

Tamii, Atsushi*; Pellegri, L.*; Sderstrm, P.-A.*; Allard, D.*; Goriely, S.*; Inakura, Tsunenori*; Khan, E.*; Kido, Eiji*; Kimura, Masaaki*; Litvinova, E.*; et al.

European Physical Journal A, 59(9), p.208_1 - 208_21, 2023/09

https://doi.org/10.1140/epja/s10050-023-01081-w

no abstracts in English

The Fe(n,)Fe cross section from the surrogate ratio method and its effect on the Fe nucleosynthesis

Yan, S. Q.*; Li, X. Y.*; Nishio, Katsuhisa; Lugaro, M.*; Li, Z. H.*; Makii, Hiroyuki; Pignatari, M.*; Wang, Y. B.*; Orlandi, R.; Hirose, Kentaro; et al.

Astrophysical Journal, 919(2), p.84_1 - 84_7, 2021/10

https://doi.org/10.3847/1538-4357/ac12ce

Implementation of tetrahedral-mesh geometry in Monte Carlo radiation transport code PHITS

Furuta, Takuya; Sato, Tatsuhiko; Han, M. C.*; Yeom, Y. S.*; Kim, C. H.*; Brown, J. L.*; Bolch, W. E.*

Physics in Medicine & Biology, 62(12), p.4798 - 4810, 2017/06

https://doi.org/10.1088/1361-6560/aa6b45

A new function to treat tetrahedral-mesh geometry, a type of polygon-mesh geometry, was implemented in the Particle and Heavy Ion Transport code Systems (PHITS). Tetrahedral-mesh is suitable to describe complex geometry including curving shapes. In addition, construction of three-dimensional geometry using CAD software becomes possible with file format conversion. We have introduced a function to create decomposition maps of tetrahedral-mesh objects at the initial process so that the computational time for transport process can be reduced. Owing to this function, transport calculation in tetrahedral-mesh geometry can be as fast as that for the geometry in voxel-mesh with the same number of meshes. Due to adaptability of tetrahedrons in size and shape, dosimetrically equivalent objects can be represented by tetrahedrons with much fewer number of meshes compared with the voxels. For dosimetric calculation using computational human phantom, significant acceleration of the computational speed, about 4 times, was confirmed by adopting the tetrahedral mesh instead of the voxel.

Neutron spectroscopic factors of Ni hole-states from (p,d) transfer reactions

Sanetullaev, A.*; Tsang, M. B.*; Lynch, W. G.*; Lee, J.*; Bazin, D.*; Chan, K. P.*; Coupland, D.*; Hanzl, V.*; Hanzlova, D.*; Kilburn, M.*; et al.

Physics Letters B, 736, p.137 - 141, 2014/09

https://doi.org/10.1016/j.physletb.2014.07.003

no abstracts in English

Development of high voltage power supply for the KSTAR 170 GHz ECH and CD system

Jeong, J. H.*; Bae, Y. S.*; Joung, M.*; Kim, H. J.*; Park, S. I.*; Han, W. S.*; Kim, J. S.*; Yang, H. L.*; Kwak, J. G.*; Sakamoto, Keishi; et al.

Fusion Engineering and Design, 88(5), p.380 - 387, 2013/06

https://doi.org/10.1016/j.fusengdes.2013.03.078

ITER magnet systems; From qualification to full scale construction

Nakajima, Hideo; Hemmi, Tsutomu; Iguchi, Masahide; Nabara, Yoshihiro; Matsui, Kunihiro; Chida, Yutaka; Kajitani, Hideki; Takano, Katsutoshi; Isono, Takaaki; Koizumi, Norikiyo; et al.

Proceedings of 24th IAEA Fusion Energy Conference (FEC 2012) (CD-ROM), 8 Pages, 2013/03

http://www-naweb.iaea.org/napc/physics/FEC/FEC2012/papers/578_ITR24.pdf

The ITER organization and 6 Domestic Agencies (DA) have been implementing the construction of ITER superconducting magnet systems. Four DAs have already started full scale construction of Toroidal Field (TF) coil conductors. The qualification of the radial plate manufacture has been completed, and JA and EU are ready for full scale construction. JA has qualified full manufacturing processes of the winding pack with a 1/3 prototype and made 2 full scale mock-ups of the basic segments of TF coil structure to optimize and industrialize the manufacturing process. Preparation and qualification of the full scale construction of the TF coil winding is underway by EU. Procurement of the manufacturing equipment is near completion and qualification of manufacturing processes has already started. The constructions of other components of the ITER magnet systems are also going well towards the main goal of the first plasma in 2020.

Event structure and double helicity asymmetry in jet production from polarized collisions at = 200 GeV

Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Y.*; Al-Bataineh, H.*; Alexander, J.*; Aoki, K.*; Aphecetche, L.*; Armendariz, R.*; et al.

Physical Review D, 84(1), p.012006_1 - 012006_18, 2011/07

https://doi.org/10.1103/PhysRevD.84.012006

We report on the event structure and double helicity asymmetry () of jet production in longitudinally polarized collisions at = 200 GeV. Photons and charged particles were measured by the PHENIX experiment. Event structure was compared with the results from PYTHIA event generator. The production rate of reconstructed jets is satisfactorily reproduced with the next-to-leading-order perturbative QCD calculation. We measured = -0.0014 0.0037 at the lowest bin and -0.0181 0.0282 at the highest bin. The measured is compared with the predictions that assume various distributions.

Azimuthal correlations of electrons from heavy-flavor decay with hadrons in and Au+Au collisions at = 200 GeV

Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Aramaki, Y.*; et al.

Physical Review C, 83(4), p.044912_1 - 044912_16, 2011/04

https://doi.org/10.1103/PhysRevC.83.044912

Measurements of electrons from the decay of open-heavy-flavor mesons have shown that the yields are suppressed in Au+Au collisions compared to expectations from binary-scaled collisions. Here we extend these studies to two particle correlations where one particle is an electron from the decay of a heavy flavor meson and the other is a charged hadron from either the decay of the heavy meson or from jet fragmentation. These measurements provide more detailed information about the interaction between heavy quarks and the quark-gluon matter. We find the away-side-jet shape and yield to be modified in Au+Au collisions compared to collisions.

Commissioning results of the KSTAR neutral beam system

Bae, Y. S.*; Park, Y. M.*; Kim, J. S.*; Han, W. S.*; Kwak, S. W.*; Chang, Y. B.*; Park, H. T.*; Song, N. H.*; Chang, D. H.*; Jeong, S. H.*; et al.

Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 9 Pages, 2011/03

http://www-naweb.iaea.org/napc/physics/FEC/FEC2010/html/node443.htm#86774

The neutral beam injection (NBI) system is designed to provide the ion heating and current drive for the high performance operation and long pulse operation of the Korean Superconducting Tokamak Advanced Research (KSTAR). The KSTAR NBI consists of two beam lines. Each beam line contains three ion sources of which one ion source has been designed to deliver more than 2.5 MW of deuterium neutral beam power with maximum 120-keV beam energy. Consequently, the final goal of the KSTAR NBI system aims to inject more than 14 MW of deuterium beam power with the two beam lines. According to the planned NBI system, the first NBI system is to demonstrate the beam injection from one ion source into the KSTAR tokamak plasma in 2010 campaign including the system commissioning of each components and subsystems. In this paper, the construction and the commissioning of the first NBI system with one ion source is presented.