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Nagai, Takayuki; Hasegawa, Takehiko*
JAEA-Research 2023-008, 41 Pages, 2023/12
JAEA-Research-2023-008.pdf:7.52MB
To reduce the risks posed by stored the high-level radioactive liquid waste (HAW), Tokai Vitrification Facility (TVF) is working to produce the HAW into vitrified bodies. With the aim of steady vitrification of HAW in TVF, the vitrification technology section has manufactured a new 3rd melter with an improved bottom structure and is working to verify the performance of this melter. In this study, solidified glass samples were taken from simulated vitrified bodies produced by flowing molten glass during the bottom drain-out test in the operation confirmation of the TVF 3rd melter. And the properties of the surface layer and fracture surface of the vitrified bodies were evaluated by using Raman spectroscopy, synchrotron radiation XAFS measurement, and laser ablation inductively coupled plasma atomic emission spectroscopy (LA ICP-AES) analysis. As a result of measuring the surface layer and fracture surface of the solidified samples produced on an actual scale, a slight difference was confirmed between the properties of the surface layer and those of the fracture surface. Since the chemical composition of these simulated vitrified bodies does not contain platinum group elements, it is expected that the glass structure of solidified glass samples is different from that of the actual vitrified body. However, this sample measuring was a valuable opportunity to evaluate samples produced by using the direct energized joule heating method. The properties of cullet used the operation confirmation of the TVF 3rd melter and the cullet of another production lot were measured and analyzed in the same manner under the measuring conditions of solidified glass samples. As a result, it was confirmed that cullet with different producing histories have different glass structures even with the same chemical composition, and that differences in glass structures remain in the glass samples after melting these cullet.
Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*
JAEA-Research 2023-004, 45 Pages, 2023/09
JAEA-Research-2023-004.pdf:6.07MB
The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, simulated waste glass samples were prepared and the chemical state regarding boron (B), silicon (Si) and waste elements of iron (Fe), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. To understand the chemical stability of simulated waste glasses, XANES spectra of B K-edge, Fe L
, L
-edge, and Cs M
, M
-edge were measured on the glass surface exposed to the leachate. As a result, it was found that the glass surface exposed to the leachate was changed and it was difficult to obtain a clear XANES spectrum. From the B K-edge XANES spectra on glass surfaces exposed to the leachate, an increase in three-coordination of B-O (BO) and a decrease in four-coordination of B-O (BO) were observed compared to the glass surfaces before immersion. The XANES spectra of Fe L, L-edge, and Cs M, M-edge show that as the exposure time in the leachate increases, the Cs present on the glass surface dissolves into the leachate. The XANES spectra of Si K-edge were measured on simulated waste glass surfaces before immersion, and it was confirmed that the change in XANES spectra given by NaO concentration had a larger effect than the waste component concentration.
Arai, Yoichi; Watanabe, So; Hasegawa, Kenta; Okamura, Nobuo; Watanabe, Masayuki; Takeda, Keisuke*; Fukumoto, Hiroki*; Ago, Tomohiro*; Hagura, Naoto*; Tsukahara, Takehiko*
Nuclear Instruments and Methods in Physics Research B, 542, p.206 - 213, 2023/09
Times Cited Count：1 Percentile：0.02(Instruments & Instrumentation)Sako, Hiroyuki; Harada, Hiroyuki; Sakaguchi, Takao*; Chujo, Tatsuya*; Esumi, Shinichi*; Gunji, Taku*; Hasegawa, Shoichi; Hwang, S.; Ichikawa, Yudai; Imai, Kenichi; et al.
Nuclear Physics A, 956, p.850 - 853, 2016/12
Times Cited Count：13 Percentile：65.38(Physics, Nuclear)Harada, Kosaku*; Nonaka, Tetsuo*; Hamada, Nobuyuki*; Sakurai, Hideyuki*; Hasegawa, Masatoshi*; Funayama, Tomoo; Kakizaki, Takehiko*; Kobayashi, Yasuhiko; Nakano, Takashi*
Cancer Science, 100(4), p.684 - 688, 2009/04
Times Cited Count：56 Percentile：75.54(Oncology)Mukaiyama, Takehiko; Takizuka, Takakazu; Mizumoto, Motoharu; Ikeda, Yujiro; Ogawa, Toru; Hasegawa, Akira; Takada, Hiroshi; Takano, Hideki
Progress in Nuclear Energy, 38(1-2), p.107 - 134, 2001/02
Times Cited Count：68 Percentile：96.8(Nuclear Science & Technology)no abstracts in English
Harada, Kosaku*; Nonaka, Tetsuo*; Sakurai, Hideyuki*; Kawamura, Hidemasa*; Hasegawa, Masatoshi*; Nakano, Takashi*; Hamada, Nobuyuki*; Wada, Seiichi*; Kobayashi, Yasuhiko; Funayama, Tomoo; et al.
no journal, ,
no abstracts in English
Wakai, Eiichi; Kogawara, Takafumi; Kikuchi, Takayuki; Yamamoto, Michiyoshi; Molla, J.*; Kimura, Akihiko*; Kasada, Ryuta*; Kim, B.*; Nogami, Shuhei*; Hasegawa, Akira*; et al.
no journal, ,
no abstracts in English
Wakai, Eiichi; Kondo, Hiroo; Kanemura, Takuji; Hirakawa, Yasushi; Furukawa, Tomohiro; Kikuchi, Takayuki; Ito, Yuzuru*; Hoashi, Eiji*; Yoshihashi, Sachiko*; Horiike, Hiroshi*; et al.
no journal, ,
no abstracts in English
Arai, Yoichi; Watanabe, So; Hasegawa, Kenta; Okamura, Nobuo; Watanabe, Masayuki; Takeda, Keisuke*; Fukumoto, Hiroki*; Ago, Tomohiro*; Hagura, Naoto*; Tsukahara, Takehiko*
no journal, ,
