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論文

A Colossal barocaloric effect induced by the creation of a high-pressure phase

Zhang, Z.*; Jiang, X.*; 服部 高典; Xu, X.*; Li, M.*; Yu, C.*; Zhang, Z.*; Yu, D.*; Mole, R.*; 矢野 真一郎*; et al.

Materials Horizons, 10(3), p.977 - 982, 2023/03

https://doi.org/10.1039/d2mh00905f
 被引用回数：0 パーセンタイル：0(Chemistry, Multidisciplinary)

現在の蒸気圧縮式冷凍機に代わる環境に優しい冷凍機として、バロカロリック効果に基づく固体冷凍機が世界的に注目されている。一般に、バロカロリック効果が発現する相はいずれも常圧でも存在する。ここでは、それらの物質と違って、KPF$$_{6}$$が高圧の菱面体晶相を生成することにより、巨大なバロカロリック効果を示すことを実証した。相図は、圧力依存の熱量測定、ラマン散乱測定、中性子回折測定に基づいて構築されたものである。本研究は、巨大バロカロリー効果に、高圧相の生成という新たな手法をもたらすと期待される。

論文

Radiation chemistry provides nanoscopic insights into the role of intermediate phases in CeO$$_{2}$$ mesocrystal formation

Li, Z.*; Piankova, D.*; Yang, Y.*; 熊谷 友多; Zschiesche, H.*; Jonsson, M.*; Tarakina, N. V.*; Soroka, I. L.*

Angewandte Chemie; International Edition, 61(6), p.e202112204_1 - e202112204_9, 2022/02

https://doi.org/10.1002/anie.202112204
 被引用回数：3 パーセンタイル：36.41(Chemistry, Multidisciplinary)

Ce(III)水溶液の放射線誘起酸化反応によるCeO$$_{2}$$形成過程を研究した。Ce(III)はガンマ線照射による水の放射線分解で生じるOHラジカルによりCe(IV)に酸化され、水に対する溶解度が減少するため析出し、最終的にはCeO$$_{2}$$が生成する。この反応過程を透過型電子顕微鏡観察とX線結晶構造解析を用いて調べた。その結果、ガンマ線照射によって生成するCeO$$_{2}$$は、いくつかの中間的な状態を経てメソ結晶体を形成することを明らかにした。水溶液中でCe(III)が酸化されると、CeO$$_{2}$$析出の前駆体としてアモルファスなCe(IV)水酸化物が生成する。その後、Ce(IV)水酸化物中でCeO$$_{2}$$のナノ粒子が成長する。このCeO$$_{2}$$ナノ粒子はアモルファス組織の中でゆっくりと配向性を有するようになり、ナノ粒子間の相互作用により規則的な構造を形成したメソ結晶体となる。さらに、このメソ結晶体を徐々に乾燥させることでメソ結晶体がさらに構造化した超結晶(supracrystal)となり、複雑な階層化アーキテクチャが形成されることを明らかにした。

論文

Optical selection rules of the magnetic excitation in the $$S$$ = $$frac{1}{2}$$ one-dimensional Ising-like antiferromagnet BaCo$$_{2}$$V$$_{2}$$O$$_{8}$$

木村 尚次郎*; 大西 弘明; 奥谷 顕*; 赤木 暢*; 鳴海 康雄*; 萩原 政幸*; 奥西 巧一*; 金道 浩一*; He, Z.*; 谷山 智康*; et al.

Physical Review B, 105(1), p.014417_1 - 014417_9, 2022/01

https://doi.org/10.1103/PhysRevB.105.014417
 被引用回数：0 パーセンタイル：0(Materials Science, Multidisciplinary)

In this study, we clarify the selection rules of optical transitions from the ground state to the magnetic excited states in the quasi-one-dimensional quantum Ising-like antiferromagnet BaCo$$_{2}$$V$$_{2}$$O$$_{8}$$ with spin $$S$$ = $$frac{1}{2}$$ using the high-field electron spin resonance measurement with illuminating polarized electromagnetic waves. We demonstrate that the unconventional magnetic excitation via the pair creation of quasipaticles at wave numbers $$q_{z}=pi/2$$ and $$pi$$ in the field-induced quantum critical state can couple with both oscillating magnetic and electric fields. Our density matrix renormalization group calculations indicate that the observed selection rules can be explained by two- and four-fold periodical spin interactions, originating from the screw chain structure in BaCo$$_{2}$$V$$_{2}$$O$$_{8}$$, in addition to the magnetoelectric coupling between spins and electric dipoles.

論文

Temperature-dependent hardening contributions in CrFeCoNi high-entropy alloy

Naeem, M.*; He, H.*; Harjo S.; 川崎 卓郎; Lin, W.*; Kai, J.-J.*; Wu, Z.*; Lan, S.*; Wang, X.-L.*

Acta Materialia, 221, p.117371_1 - 117371_18, 2021/12

https://doi.org/10.1016/j.actamat.2021.117371
 被引用回数：17 パーセンタイル：93.02(Materials Science, Multidisciplinary)

We studied the deformation behavior of CrFeCoNi high-entropy alloy by in situ neutron diffraction at room temperature, intermediate low temperature of 140 K, low temperatures of 40 K (no serrated deformation) and 25 K (with massive serrations). The contributions from different deformation mechanisms to the yield strength and strain hardening have been estimated. The athermal contributions to the yield strength were $$sim$$183 MPa at all temperatures, while the Peierls stress increased significantly at low temperatures (from 148 MPa at room temperature to 493 MPa at 25 K). Dislocations contributed to $$sim$$94% strain hardening at room temperature. Although the dislocation strengthening remained the major hardening mechanism at very low temperatures, the planar faults contribution increased steadily from 6% at room temperature to 28% at 25 K.

論文

Martensitic transformation in CrCoNi medium-entropy alloy at cryogenic temperature

Naeem, M.*; Zhou, H.*; He, H.*; Harjo S.; 川崎 卓郎; Lan, S.*; Wu, Z.*; Zhu, Y.*; Wang, X.-L.*

Applied Physics Letters, 119(13), p.131901_1 - 131901_7, 2021/09

https://doi.org/10.1063/5.0067268
 被引用回数：7 パーセンタイル：72.26(Physics, Applied)

We investigated the in situ deformation behavior of the CrCoNi medium-entropy alloy at a cryogenic temperature of 140 K and compared it with deformation at room temperature. The sample exhibited higher strength and larger ductility at the cryogenic temperature. The CrCoNi alloy remained single-phase face-centered cubic at room temperature, while deformation at 140 K resulted in a martensitic transformation to the hexagonal close-packed structure. The phase transformation, an additional deformation mechanism to stacking faults, twinning, and dis- location slip, resulted in a higher work hardening at cryogenic temperature. The study addresses the structure metastability in the CrCoNi alloy, which led to the formation of epsilon-martensite from the intrinsic stacking faults.

論文

Stacking fault driven phase transformation in CrCoNi medium entropy alloy

He, H.*; Naeem, M.*; Zhang, F.*; Zhao, Y.*; Harjo S.; 川崎 卓郎; Wang, B.*; Wu, X.*; Lan, S.*; Wu, Z.*; et al.

Nano Letters, 21(3), p.1419 - 1426, 2021/02

https://doi.org/10.1021/acs.nanolett.0c04244
 被引用回数：24 パーセンタイル：94.49(Chemistry, Multidisciplinary)

In CrCoNi, a so-called medium-entropy alloy, an fcc-to-hcp phase transformation has long been anticipated. Here, we report an in situ loading study with neutron diffraction, which revealed a bulk fcc-to-hcp phase transformation in CrCoNi at 15 K under tensile loading. By correlating deformation characteristics of the fcc phase with the development of the hcp phase, it is shown that the nucleation of the hcp phase was triggered by intrinsic stacking faults. The confirmation of a bulk phase transformation adds to the myriads of deformation mechanisms available in CrCoNi, which together underpin the unusually large ductility at low temperatures.

論文

Extremely high dislocation density and deformation pathway of CrMnFeCoNi high entropy alloy at ultralow temperature

Naeem, M.*; He, H.*; Harjo S.; 川崎 卓郎; Zhang, F.*; Wang, B.*; Lan, S.*; Wu, Z.*; Wu, Y.*; Lu, Z.*; et al.

Scripta Materialia, 188, p.21 - 25, 2020/11

https://doi.org/10.1016/j.scriptamat.2020.07.004
 被引用回数：43 パーセンタイル：97.2(Nanoscience & Nanotechnology)

The deformation behavior of CrMnFeCoNi high entropy alloy was investigated by in situ neutron diffraction at an ultralow temperature of 15 K. Analysis of the diffraction peak widths showed an extremely high dislocation density at 15 K, reaching $$sim$$10$$^{16}$$ m$$^{-2}$$. In addition, the dislocation density was found to closely follow the development of texture caused by deformation. In contrast to deformation by dislocation slip at room temperature, the ultralow-temperature deformation also involved stacking faults, twinning and serrations. The deformation pathway at ultralow temperature is outlined which is responsible for the extraordinary strength-ductility combination.

論文

Magnetic-field and composition tuned antiferromagnetic instability in the quantum spin-liquid candidate NaYbO$$_2$$

Guo, J.*; Zhao, X.*; 河村 聖子; Ling, L.*; Wang, J.*; He, L.*; 中島 健次; Li, B.*; Zhang, Z.*

Physical Review Materials (Internet), 4(6), p.064410_1 - 064410_7, 2020/06

https://doi.org/10.1103/PhysRevMaterials.4.064410
 被引用回数：9 パーセンタイル：49.67(Materials Science, Multidisciplinary)

NaYbO$$_2$$ has been reported as a possible host for the quantum spin-liquid state. Here, the composition-dependent polycrystalline Na$$_{1-x}$$YbO$$_2$$ ($$x = 0$$, 0.03, and 0.07) has been investigated by combining high-field magnetizations and inelastic neutron scattering techniques. For the $$x = 0$$ sample, no signature of a magnetic order is observed down to 0.3 K. Inelastic neutron scattering measurement suggests a continuous low-energy excitation spectrum centered at momentum transfer $$(Q) sim 1.25$$~$AA$^{-1}$$ and extending up to energy transfer $$(E) sim 2.0$$~meV. In contrast, $$x = 0.03$$ and 0.07 samples exhibit magnetic transitions at 1.1 and 2.3 K, respectively. High-field magnetization measurements indicate similar behaviors for $$x = 0$$ and 0.03 samples including plateau-like features at the 1/3 saturated magnetization, which implies that the spin disorder in the $$x = 0$$ sample might be suppressed preceding the emergence of the up-up-down phase. This composition- and field-dependent study allows us to construct complete phase diagrams indicating that NaYbO$$_2$$ is a promising candidate for the quantum spin-liquid state in close proximity to the antiferromagnetic instability tuned by the application of magnetic fields as well as controlling the concentration of Na$$^+$$ ion vacancies.

論文

Cooperative deformation in high-entropy alloys at ultralow temperatures

Naeem, M.*; He, H.*; Zhang, F.*; Huang, H.*; Harjo S.; 川崎 卓郎; Wang, B.*; Lan, S.*; Wu, Z.*; Wang, F.*; et al.

Science Advances (Internet), 6(13), p.eaax4002_1 - eaax4002_8, 2020/03

https://doi.org/10.1126/sciadv.aax4002
 被引用回数：109 パーセンタイル：98.93(Multidisciplinary Sciences)

High-entropy alloys exhibit exceptional mechanical properties at cryogenic temperatures, due to the activation of twinning in addition to dislocation slip. The coexistence of multiple deformation pathways raises an important question regarding how individual deformation mechanisms compete or synergize during plastic deformation. Using in situ neutron diffraction, we demonstrate the interaction of a rich variety of deformation mechanisms in high-entropy alloys at 15 K, which began with dislocation slip, followed by stacking faults and twinning, before transitioning to inhomogeneous deformation by serrations. Quantitative analysis showed that the cooperation of these different deformation mechanisms led to extreme work hardening. The low stacking fault energy plus the stable face-centered cubic structure at ultralow temperatures, enabled by the high-entropy alloying, played a pivotal role bridging dislocation slip and serration.

論文

Ultralow thermal conductivity from transverse acoustic phonon suppression in distorted crystalline $$alpha$$-MgAgSb

Li, X.*; Liu, P.-F.*; Zhao, E.*; Zhang, Z.*; Guide, T.*; Le, M. D.*; Avdeev, M.*; 池田 一貴*; 大友 季哉*; 古府 麻衣子; et al.

Nature Communications (Internet), 11, p.942_1 - 942_9, 2020/02

https://doi.org/10.1038/s41467-020-14772-5
 被引用回数：27 パーセンタイル：90.23(Multidisciplinary Sciences)

高性能の熱電材料実現には低熱伝導率が必要であり、その機構としてはフォノンの非調和によるもの、あるいは、結晶構造の動的な乱れによるフォノンの散乱によるものがあげられ、どちらも中性子散乱でその現象が明らかにされている。我々は中性子散乱と第一原理計算を組み合わせ、$$alpha$$-MgAgSbにおいて、静的な結晶構造の乱れとフォノンの非調和性が組み合わされて極端に低い熱伝導率が実現されているということを見いだしたので、これを報告する。

論文

Fine structure in the $$alpha$$ decay of $$^{218}$$At

Cubiss, J. G.*; Andreyev, A. N.; Barzakh, A. E.*; Andel, B.*; Antalic, S.*; Cocolios, T. E.*; Day Goodacre, T.*; Fedorov, D. V.*; Fedosseev, V. N.*; Ferrer, R.*; et al.

Physical Review C, 99(6), p.064317_1 - 064317_6, 2019/06

https://doi.org/10.1103/PhysRevC.99.064317
 被引用回数：6 パーセンタイル：60.44(Physics, Nuclear)

$$^{218}$$Atの$$alpha$$崩壊について、CERN-ISOLDE施設においてレーザーイオン化法を使うことで研究した。$$alpha$$-$$gamma$$同時計数データを初めて取得し、より精度の良い半減期の値として1.27(6)秒を得た。$$alpha$$崩壊の微細構造を基に新しい$$alpha$$崩壊図式を構築した。それらの結果から、$$^{218}$$Atの基底状態のスピン・パリティは(3$$^{-}$$)がより確からしいことが解ったが、(2)$$^{-}$$の可能性も完全には否定しきれない。

論文

Inverse odd-even staggering in nuclear charge radii and possible octupole collectivity in $$^{217,218,219}$$At revealed by in-source laser spectroscopy

Barzakh, A. E.*; Cubiss, J. G.*; Andreyev, A. N.; Seliverstov, M. D.*; Andel, B.*; Antalic, S.*; Ascher, P.*; Atanasov, D.*; Beck, D.*; Biero$'n$, J.*; et al.

Physical Review C, 99(5), p.054317_1 - 054317_9, 2019/05

https://doi.org/10.1103/PhysRevC.99.054317
 被引用回数：12 パーセンタイル：77.08(Physics, Nuclear)

Hyperfine-structure parameters and isotope shifts for the 795-nm atomic transitions in $$^{217,218,219}$$At have been measured at CERN-ISOLDE, using the in-source resonance-ionization spectroscopy technique. Magnetic dipole and electric quadrupole moments, and changes in the nuclear mean-square charge radii, have been deduced. A large inverse odd-even staggering in radii, which may be associated with the presence of octupole collectivity, has been observed. Namely, the radius of the odd-odd isotope $$^{218}$$At has been found to be larger than the average.

論文

Coexistence of ferromagnetic and stripe-type antiferromagnetic spin fluctuations in YFe$$_{2}$$Ge$$_{2}$$

Wo, H.*; Wang, Q.*; Shen, Y.*; Zhang, X.*; Hao, Y.*; Feng, Y.*; Shen, S.*; He, Z.*; Pan, B.*; Wang, W.*; et al.

Physical Review Letters, 122(21), p.217003_1 - 217003_5, 2019/05

https://doi.org/10.1103/PhysRevLett.122.217003
 被引用回数：3 パーセンタイル：33.41(Physics, Multidisciplinary)

We report neutron scattering measurements of single-crystalline YFe$$_{2}$$Ge$$_{2}$$ in the normal state, which has the same crystal structure as the 122 family of iron pnictide superconductors. YFe$$_{2}$$Ge$$_{2}$$ does not exhibit long-range magnetic order but exhibits strong spin fluctuations. Like the iron pnictides, YFe$$_{2}$$Ge$$_{2}$$ displays anisotropic stripe-type antiferromagnetic spin fluctuations at ($$pi, 0, pi$$). More interesting, however, is the observation of strong spin fluctuations at the in-plane ferromagnetic wave vector ($$0, 0, pi$$). These ferromagnetic spin fluctuations are isotropic in the ($$H, K$$) plane, whose intensity exceeds that of stripe spin fluctuations. Both the ferromagnetic and stripe spin fluctuations remain gapless down to the lowest measured energies. Our results naturally explain the absence of magnetic order in YFe$$_{2}$$Ge$$_{2}$$ and also imply that the ferromagnetic correlations may be a key ingredient for iron-based materials.

論文

EXILL; A High-efficiency, high-resolution setup for $$gamma$$-spectroscopy at an intense cold neutron beam facility

Jentschel, M.*; Blanc, A.*; de France, G.*; K$"o$ster, U.*; Leoni, S.*; Mutti, P.*; Simpson, G.*; Soldner, T.*; Ur, C.*; Urban, W.*; et al.

Journal of Instrumentation (Internet), 12(11), p.P11003_1 - P11003_33, 2017/11

https://doi.org/10.1088/1748-0221/12/11/P11003
 被引用回数：33 パーセンタイル：84.86(Instruments & Instrumentation)

A highly efficient array of high-purity germanium (HPGe) detectors was developed and operated at the cold neutron beam facility PF1B of the Institut Laue-Langevin (ILL) to carry out nuclear structure studies, via measurements of $$gamma$$-rays following neutron-induced capture and fission reactions. The setup consisted of a collimation system producing a pencil beam with a thermal capture equivalent flux of about 10$$^8$$ns$$^{-1}$$cm$$^{-2}$$ at the target position and negligible neutron halo. The target was surrounded by an array of eight to ten anti-Compton shielded EXOGAM Clover detectors, four to six anti-Compton shielded large coaxial GASP detectors and two standard Clover detectors. For a part of the campaign the array was combined with 16 LaBr$$_{3}$$:(Ce) detectors from the FATIMA collaboration.

論文

Atomically dispersed Pt on the surface of Ni particles; Synthesis and catalytic function in hydrogen generation from aqueous ammonia-borane

Li, Z.*; He, T.*; 松村 大樹; Miao, S.*; Wu, A.*; Liu, L.*; Wu, G.*; Chen, P.*

ACS Catalysis, 7(10), p.6762 - 6769, 2017/10

https://doi.org/10.1021/acscatal.7b01790
 被引用回数：137 パーセンタイル：96.38(Chemistry, Physical)

We report herein that the single-atom alloy (SAA) made of atomically dispersed Pt on the surface of Ni particles (Pt is surrounded by Ni atoms) exhibits improved catalytic activity on the hydrolytic dehydrogenation of ammonia-borane, a promising hydrogen storage method for onboard applications. Specifically, an addition of 160 ppm of Pt leads to ca. 3-fold activity improvement in comparison to that of pristine Ni/CNT catalyst. The turnover frequency based on the isolated Pt is 12000 mol$$_{rm{H}2}$$ mol$$_{rm{Pt}}$$$$^{-1}$$ min$$^{-1}$$, which is about 21 times the value of the best Pt-based catalyst ever reported. Our simulation results indicate that the high activity achieved stems from the synergistic effect between Pt and Ni, where the negatively charged Pt (Pt$$^{delta -}$$) and positively charged Ni (Ni$$^{delta +}$$) in the Pt-Ni alloy are prone to interact with H and OH of H$$_{2}$$O molecules, respectively, leading to an energetically favorable reaction pathway.

論文

Shape evolution in neutron-rich krypton isotopes beyond N=60; First spectroscopy of $$^{98,100}$$Kr

Flavigny, F.*; Doornenbal, P.*; Obertelli, A.*; Delaroche, J.-P.*; Girod, M.*; Libert, J.*; Rodriguez, T. R.*; Authelet, G.*; 馬場 秀忠*; Calvet, D.*; et al.

Physical Review Letters, 118(24), p.242501_1 - 242501_6, 2017/06

https://doi.org/10.1103/PhysRevLett.118.242501
 被引用回数：32 パーセンタイル：86.69(Physics, Multidisciplinary)

The first $$gamma$$-ray spectroscopy of very neutron rich $$^{98,100}$$Kr isotopes was carried out at the RIBF at RIKEN Nishina center. Excited states in these isotopes were populated via (p,2p) reactions using radioactive $$^{99,101}$$Rb beams accelerated to 220 MeV/nucleon. The new data show a significant increase in deformation beyond N=60, as well as competing configurations (shape-coexistence) at low energy. The data were compared with beyond-mean-field calculations which predict level energies in good agreement with observation, and suggest oblate-prolate shape coexistence.

論文

Are there signatures of harmonic oscillator shells far from stability?; First spectroscopy of $$^{110}$$Zr

Paul, N.*; Corsi, A.*; Obertelli, A.*; Doornenbal, P.*; Authelet, G.*; 馬場 秀忠*; Bally, B.*; Bender, M.*; Calvet, D.*; Ch$^a$teau, F.*; et al.

Physical Review Letters, 118(3), p.032501_1 - 032501_7, 2017/01

https://doi.org/10.1103/PhysRevLett.118.032501
 被引用回数：33 パーセンタイル：87.13(Physics, Multidisciplinary)

The first measurement of $$gamma$$ rays emitted by the very neutron rich nuclei $$^{112}$$Mo (Z=42) and $$^{110}$$Zr (Z=40) was carried out at the RIBF facility at RIKEN. These data shine light on the postulated N=70 harmonic oscillator shell. If the spin-orbit splitting which gives rise to the N=82 shell gap is reduced in very neutron-rich nuclei, the harmonic oscillator gap at N=70 should open instead. However, both the measured energy of the first excited state $$^{112}$$Mo and $$^{110}$$Zr, respectively 235(7) keV and 185(11) keV, and their E(4$$^+$$)/E(2$$^+$$) ratio, indicate that these nuclei are good rotors, and exclude the shell stabilization scenario at Z=40 and N=70. These results were compared to state-of-the-art density functional theoretical calculations using Gogny and Skyrme effective interactions.

論文

$$beta$$-delayed fission and $$alpha$$ decay of $$^{196}$$At

Truesdale, V. L.*; Andreyev, A. N.; Ghys, L.*; Huyse, M.*; Van Duppen, P.*; Sels, S.*; Andel, B.*; Antalic, S.*; Barzakh, A.*; Capponi, L.*; et al.

Physical Review C, 94(3), p.034308_1 - 034308_11, 2016/09

https://doi.org/10.1103/PhysRevC.94.034308
 被引用回数：9 パーセンタイル：59.92(Physics, Nuclear)

A nuclear-decay spectroscopy study of the neutron-deficient isotope $$^{196}$$At is reported where an isotopically pure beam was produced using the selective Resonance Ionization Laser Ion Source and On-Line Isotope Mass Separator (CERN). The fine-structure $$alpha$$ decay of $$^{196}$$At allowed the low-energy excited states in the daughter nucleus $$^{192}$$Bi to be investigated. A $$beta$$-delayed fission study of $$^{196}$$At was also performed. A mixture of symmetric and asymmetric fission-fragment mass distributions of the daughter isotope $$^{196}$$Po (populated by $$beta$$ decay of $$^{196}$$At) was deduced based on the measured fission-fragment energies. A $$beta$$DF probability $$P_{rm beta DF}$$($$^{196}$$At) = 9(1)$$times$$10$$^{-5}$$ was determined.

論文

Decomposition studies of group 6 hexacarbonyl complexes, 1; Production and decomposition of Mo(CO)$$_6$$ and W(CO)$$_6$$

Usoltsev, I.*; Eichler, R.*; Wang, Y.*; Even, J.*; Yakushev, A.*; 羽場 宏光*; 浅井 雅人; Brand, H.*; Di Nitto, A.*; D$"u$llmann, Ch. E.*; et al.

Radiochimica Acta, 104(3), p.141 - 151, 2016/03

https://doi.org/10.1515/ract-2015-2445
 被引用回数：30 パーセンタイル：95.74(Chemistry, Inorganic & Nuclear)

周期表第6族元素で最も重いSgのヘキサカルボニル錯体の熱的安定性を調べることを目指して、短寿命MoおよびW同位体を用いてヘキサカルボニル錯体を合成し、その合成および解離条件を調べた。チューブ状の反応装置を用いてヘキサカルボニル錯体を解離させ、第1解離エネルギーを導出できるかテストした。第6族元素のヘキサカルボニル錯体の解離を調べるには、反応表面として銀が最適であることがわかった。Mo(CO)$$_6$$およびW(CO)$$_6$$の解離が起こる反応表面温度は、それらの第1解離エネルギーと相関があることがわかり、この方法を用いてSg(CO)$$_6$$の第1解離エネルギーを決定できる見通しを得た。

論文

In situ synthesis of volatile carbonyl complexes with short-lived nuclides

Even, J.*; Ackermann, D.*; 浅井 雅人; Block, M.*; Brand, H.*; Di Nitto, A.*; D$"u$llmann, Ch. E.*; Eichler, R.*; Fan, F.*; 羽場 宏光*; et al.

Journal of Radioanalytical and Nuclear Chemistry, 303(3), p.2457 - 2466, 2015/03

https://doi.org/10.1007/s10967-014-3793-7
 被引用回数：14 パーセンタイル：77.77(Chemistry, Analytical)

金属カルボニル錯体の迅速その場合成を、核分裂や核融合反応によって生成される短寿命同位体を用いた実験によって実証した。高い反跳エネルギーを持つ短寿命核反応生成物を一酸化炭素分子と直接反応させることでカルボニル錯体を合成し、高い揮発性を持つ錯体のみをガス気流によって迅速に搬送し、化学分析・測定装置にかけて検出した。この手法を用いることで、Mo, Tc, Ru, Rh, W, Re, Os, Irの短寿命同位体の揮発性カルボニル錯体の合成に成功した。一方、HfとTaの揮発性錯体は検出されなかった。この手法は超重元素シーボーギウム(原子番号106)の化学研究に既に適用されており、また短寿命遷移金属同位体を用いた核科学研究の様々な分野への応用が今後期待される。

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