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Sueoka, Shigeru; Iwano, Hideki*; Danhara, Toru*; Niwa, Masakazu; Kanno, Mizuho; Kohn, B. P.*; Kawamura, Makoto; Yokoyama, Tatsunori; Kagami, Saya; Ogita, Yasuhiro; et al.
Earth, Planets and Space (Internet), 75(1), p.177_1 - 177_24, 2023/12
Times Cited Count：0 Percentile：0.00(Geosciences, Multidisciplinary)Fluid-inclusion and thermochronometric analyses have been applied to hydrothermal alteration zones and their host rocks outcropping in the Hongu area of the Kii Peninsula, southwestern Japan in an attempt to detect thermal anomalies related to hydrothermal events and quantify the thermal effects on the host rocks. Hydrothermal events at ca 150 deg. C and ca 200 deg. C were identified by fluid-inclusion microthermometry of quartz veins in the alteration zones. For the host rocks and alteration zones, in the youngest population zircon yielded U-Pb dates ranging between ca 74.7-59.2 Ma, fission-track dates of ca 27.2-16.6 Ma, and (U-Th)/He single-grain dates of ca 23.6-8.7 Ma. Apatite yielded pooled fission-track ages of ca 14.9-9.0 Ma. The zircon U-Pb dates constrain the maximum depositional ages of the sedimentary samples. However, the fission-track and (U-Th)/He dates show no clear trend as a function of distance from the alteration zones. Hence, no thermal anomaly was detected in the surrounding host rocks based on the thermochronometric data patterns. The fission-track and (U-Th)/He dates are rather thought to record regional thermal and exhumation histories rather than a direct thermal imprint of fluid flow, probably because the duration of such activity was too short or because fluid flow occurred before regional cooling events and were later thermally overprinted. Apatite fission-track ages of ca 10 Ma may reflect regional mountain uplift and exhumation related to the obduction of the SW Japan lithospheric sliver onto the Shikoku Basin, or the rapid subduction of the Philippine Sea slab associated with the clockwise rotation of the Southwest Japan Arc.
Yanagisawa, Kayo; Matsueda, Makoto; Furukawa, Makoto*; Ishiniwa, Hiroko*; Wada, Toshihiro*; Hirata, Takafumi*; Takagai, Yoshitaka*
Analyst, 148(18), p.4291 - 4299, 2023/09
Times Cited Count：2 Percentile：18.58(Chemistry, Analytical)Quantitative imaging of trace elements was successfully performed by online isotope dilution laser ablation inductively coupled plasma mass spectrometry (online LA-ICP-IDMS). The sample aerosols produced by LA are mixed online with the mist created from an isotopically enriched spike solution via an in-house cyclonic spray chamber, which has a gas port on the top. Quantification was continuously achieved in each spot; subsequently, quantitative imaging was realized. Fe and Sr were selected as the model elements, and their spot quantifications based on online-isotope dilution. The method was applied to actual biological hard tissues, and the results were compared with electron probe microanalyzer data.
Sawada, Hikaru*; Niki, Sota*; Nagata, Mitsuhiro; Hirata, Takafumi*
Minerals (Internet), 12(1), p.107_1 - 107_15, 2022/01
Times Cited Count：4 Percentile：50.13(Geochemistry & Geophysics)The Oeyama ophiolite is one of the oldest components in Japanese Islands and important to reveal the initiation of plate subduction along proto-Japan. This study performed U-Pb-Hf isotopic and trace element analyses of zircon in gabbroic rocks. The weight mean of 
Pb/
U dates from zircons of the Oeyama ophiolite is 544 
4 Ma (2 sigma). Trace element analysis of the zircons exhibit that the host rock was derived from the mantle depleted of incompatible elements like mid-oceanic ridge basalt. The present igneous age and geochemical feature of the zircons is consistent with previous work for other part of the Oeyama ophiolite. Zircon Lu-Hf isotopic analysis also indicate that the gabbroic rock was derived from the depleted mantle domain. The Hf isotopic signature is more depleted than those of the zircons in jadeitite associated with the Oeyama ophiolite. This result implies that the older crustal material was involved into the initial oceanic plate subduction along the proto-Japan arc.
Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Takahashi, Yoshio*; Hirata, Takafumi*
Geostandards and Geoanalytical Research, 45(1), p.189 - 205, 2021/03
Times Cited Count：6 Percentile：34.66(Geochemistry & Geophysics)Uncertainty for elemental and isotopic analyses of calcite by LA-ICP-MS is largely controlled by the homogeneity of the reference materials (RMs) used for normalization and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb, and rare earth elements into calcite through heat- and pressure-induced crystallization from amorphous calcium carbonate that was precipitated from element-doped reagent solution. X-ray absorption spectra showed that U was present as U(VI) in the synthesized calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison to synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The 
Pb/Pb ratio in the calcite showed 
1% variations, while the U/Pb ratio showed 3-24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC-1, with analytical uncertainty as low as 3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions, and is a promising alternative to natural calcite RMs for U-Pb geochronology.
Sueoka, Shigeru; Shimada, Koji; Terusawa, Shuji*; Iwano, Hideki*; Danhara, Toru*; Ogita, Yasuhiro; Hirata, Takafumi*
Chishitsugaku Zasshi, 127(1), p.25 - 39, 2021/01
no abstracts in English
Takahashi, Hiroshi*; Mikoshiba, Masumi*; Shimura, Toshiaki*; Nagata, Mitsuhiro; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Island Arc, 30(1), p.e12393_1 - e12393_15, 2021/01
Times Cited Count：3 Percentile：18.64(Geosciences, Multidisciplinary)The Hidaka metamorphic belt is an excellent example of island-arc-type crust, and in this belt the metamorphic grade increases westwards from unmetamorphosed sediment up to the granulite facies. The metamorphic age of the belt had previously been considered to be ca. 55 Ma. However, zircons from the granulites in the lower sequence have given U-Pb ages of ca. 21-19 Ma and a preliminary report on zircons from pelitic gneiss in the upper sequence gave a U-Pb age of ca. 40 Ma. In this paper we provide new U-Pb ages for zircons from the pelitic gneisses in the upper sequence in order to assess the metamorphic age and also the maximum depositional age of the sedimentary protolith. The weighted mean Pb/U ages and 2 sigma errors for zircons from biotite gneiss in the central area of the belt are 39.6 0.9 Ma for metamorphic overgrowth rims and 53.1 0.9 Ma for the youngest inherited detrital cores. The ages of zircons from cordierite-biotite gneiss in the southern area are 35.9 0.7 Ma for overgrowth rims and 46.5 2.8 Ma for the youngest detrital cores. These results indicate that the metamorphism of the upper sequence took place at ca. 40-36 Ma, and that the sedimentary protolith was deposited after ca. 53-47 Ma. These metamorphic ages are consistent with the reported ages of ca. 37-36 Ma plutonic rocks in the upper sequence, but contrast with the ca. 21-19 Ma ages of metamorphic and plutonic rocks in the lower sequence. Therefore, we conclude, that the upper and lower metamorphic sequences developed independently but became coupled before ca. 19 Ma as a result of dextral reverse tectonic movements, as indicated by the intrusion of ca. 19-18 Ma magmas, possibly generated in the lower sequence, into the upper sequence.
Niwa, Masakazu; Amamiya, Hiroki*; Yonaga, Yusuke; Ogita, Yasuhiro; Yasue, Kenichi*; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Chishitsugaku Zasshi, 126(5), p.267 - 283, 2020/05
U-Pb and fission-track (FT) ages from single zircon grain were measured for three tephra samples (TKB3, TKB6, and TKB7) intercalated in Neogene to Quaternary in Horonobe area, Hokkaido, to understand their depositional ages. In TKB3 and TKB6, weighed average U-Pb and FT ages for zircon grains within the youngest age range are coincident within a range of error 2 
each other, which suggest that their ages correspond to the eruption ages. In TKB7, FT ages for most zircons are reset to their U-Pb ages or younger. The weighed average FT age for all analyzed zircons and weighed average U-Pb age for zircon grains within the youngest age range are coincident within a range of error 2 each other. Thus, their ages could also show the eruption age.
Ueki, Tadamasa; Niwa, Masakazu; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Chishitsugaku Zasshi, 125(3), p.227 - 236, 2019/03
no abstracts in English
Yuguchi, Takashi*; Sueoka, Shigeru; Iwano, Hideki*; Izumino, Yuya*; Ishibashi, Masayuki; Danhara, Toru*; Sasao, Eiji; Hirata, Takafumi*; Nishiyama, Tadao*
Journal of Asian Earth Sciences, 169, p.47 - 66, 2019/01
Times Cited Count：17 Percentile：62.62(Geosciences, Multidisciplinary)This study presents position-by-position 
paths within a granitic pluton based on thermochronological data, and describes their constraints and their relationship with fracture frequency, as an example from the Toki granite, central Japan. The cooling paths have position-specific characteristics; a single path does not represent the cooling behavior of the entire pluton. Such position-specific paths enable us to evaluate three-dimensional thermal evolution within the granitic pluton, and thus can clarify the detailed formation history of the entire pluton after the incipient intrusion of the granitic magma into the shallow crust. This study reveals the relationship between position-specific paths and fracture frequency, and thus provides a criterion for evaluating the fracture population in terms of thermal stress.
Yokoyama, Tatsunori; Kimura, Junichi*; Mitsuguchi, Takehiro; Danhara, Toru*; Hirata, Takafumi*; Sakata, Shuhei*; Iwano, Hideki*; Maruyama, Seiji*; Chang, Q.*; Miyazaki, Takashi*; et al.
Geochemical Journal, 52(6), p.531 - 540, 2018/12
Times Cited Count：17 Percentile：61.25(Geochemistry & Geophysics)Sasao, Eiji; Danhara, Toru*; Iwano, Hideki*; Hirata, Takafumi*
Chishitsugaku Zasshi, 124(2), p.141 - 150, 2018/02
Here U-Pb and reassessed fission track (FT) ages are presented for samples from the Miocene Mizunami and Iwamura groups in the southeastern Gifu Prefecture, central Japan. The U-Pb ages of three tuff samples coincide with the reassessed FT ages within the error range. These new U-Pb and reassessed FT ages are consistent with those reported in previous microfossil and paleomagnetic studies, which indicate the following depositional history: The Hongo and Akeyo formations of the Mizunami Group were deposited at ~19-18 Ma and ca. 18 Ma, respectively, and the lower part of the Toyama Formation of the Iwamura Group was deposited ca. 18 Ma.
Ikuta, Masafumi*; Niwa, Masakazu; Danhara, Toru*; Yamashita, Toru*; Maruyama, Seiji*; Kamataki, Takanobu*; Kobayashi, Tetsuo*; Kurosawa, Hideki*; Kokubu, Yoko; Hirata, Takafumi*
Chishitsugaku Zasshi, 122(3), p.89 - 107, 2016/03
We carried out mineral composition analysis, morphological classification of volcanic glass shards and refractive index measurements of the glass shards and orthopyroxene from the eruption products from Sakurajima volcano. In this study, refractive indexes of hydrated and non-hydrated parts within each individual glass shard were measured separately. This measurements in consideration of hydration in glass shards made possible distinct discrimination of the pumice samples from the three eruption events of Bunmei, An-ei, and Taisho. Pumice layers in the core samples obtained from the southern part of the Miyazaki Plain were also identified as the Sakurajima-Bunmei tephra by the above mentioned analyses, and also by the data of radiocarbon dating for coaly materials included in the pumice layers. Occurrences of the pumice layers suggest that the Sakurajima-Bunmei tephra could have reached the southern part of Miyazaki Plain as pumice falls.
Suzuki, Yohei*; Mukai, Hiroki*; Ishimura, Toyoho*; Yokoyama, Takatomi*; Sakata, Shuhei*; Hirata, Takafumi*; Iwatsuki, Teruki; Mizuno, Takashi
Scientific Reports (Internet), 6, p.22701_1 - 22701_6, 2016/03
Times Cited Count：14 Percentile：46.81(Multidisciplinary Sciences)The stimulation of bacterial activities that convert hexavalent uranium to tetravalent uranium appears to be feasible for cost-effective remediation of contaminated aquifers. However, U(VI) reduction typically results in the precipitation of U(IV) particles less than 5 nanometers in diameter. Here we show that U(IV) nanoparticles of coffinite formed in fracture-filling calcium carbonate in a granitic aquifer. As the microbiologically induced precipitation of calcium carbonate in aquifer systems worldwide is extremely common, we anticipate simultaneous stimulation of microbial activities for precipitation reactions of calcium carbonate and U(IV) nanoparticles, which leads to long-term sequestration of uranium and other radionuclides in contaminated aquifers and deep geological repositories.
Yuguchi, Takashi*; Iwano, Hideki*; Kato, Takenori*; Sakata, Shuhei*; Hattori, Kentaro*; Hirata, Takafumi*; Sueoka, Shigeru; Danhara, Toru*; Ishibashi, Masayuki; Sasao, Eiji; et al.
Journal of Mineralogical and Petrological Sciences, 111(1), p.9 - 34, 2016/02
Times Cited Count：17 Percentile：50.39(Mineralogy)Zircon growth collected from a granitic pluton shows four (1st - 4th) events with specific mechanisms, crystallization temperatures and U-Pb ages, revealing the sequential formation process from intrusion through emplacement to crystallization / solidification. The events are recognized by: (1) internal structure of zircon based on the cathodoluminescence observation, (2) crystallization temperatures by the Ti-in-zircon thermometer in the internal structure and (3) U-Pb ages in the internal structure.
Cs
Fe
Se
Hawai, Takafumi*; Nambu, Yusuke*; Ogushi, Kenya*; Du, F.*; Hirata, Yasuyuki*; Avdeev, M.*; Uwatoko, Yoshiya; Sekine, Yurina; Fukazawa, Hiroshi; Ma, J.*; et al.
Physical Review B, 91(18), p.184416_1 - 184416_11, 2015/05
Times Cited Count：17 Percentile：56.79(Materials Science, Multidisciplinary)We investigated the iron-based ladder compounds (Ba, Cs)FeSe, whose parent compounds, BaFeSe and CsFeSe, have different space groups, formal valences of Fe and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, X-ray diffraction and powder neutron diffraction measurements were conducted to obtain the temperature and composition phase diagram of this system. Block magnetism seen in BaFeSe is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFeSe more resilient to Ba doping. Novel magnetic structure appears in intermediate compositions, which is similar to the stripe magnetism of CsFeSe but with different inter-ladder spin configuration. Intermediate compounds show insulating behavior, nevertheless finite T-linear contribution in specific heat was obtained at low temperature.
Yokoyama, Tatsunori; Kokubu, Yoko; Mitsuguchi, Takehiro*; Murakami, Hiroaki; Hirata, Takafumi*; Sakata, Shuhei*; Danhara, Toru*; Iwano, Hideki*; Maruyama, Seiji*; Chang, Q.*; et al.
no journal, ,
no abstracts in English
Yuguchi, Takashi; Iwano, Hideki*; Hattori, Kentaro*; Sakata, Shuhei*; Sueoka, Shigeru; Danhara, Toru*; Hirata, Takafumi*; Ishibashi, Masayuki; Kunimaru, Takanori; Nishiyama, Tadao*
no journal, ,
no abstracts in English
Yokoyama, Tatsunori; Kokubu, Yoko; Mitsuguchi, Takehiro; Murakami, Hiroaki; Hirata, Takafumi*; Sakata, Shuhei*; Danhara, Toru*; Iwano, Hideki*; Maruyama, Seiji*; Chang, Q.*; et al.
no journal, ,
no abstracts in English
Yamada, Kunimi; Kogiso, Tetsu*; Uesugi, Kentaro*; Hirata, Takafumi*
no journal, ,
no abstracts in English
Yokoyama, Tatsunori; Kokubu, Yoko; Murakami, Hiroaki; Watanabe, Takahiro; Hirata, Takafumi*; Sakata, Shuhei*; Danhara, Toru*; Iwano, Hideki*; Maruyama, Seiji*; Miyazaki, Takashi*; et al.
no journal, ,
Chronological and geochemical studies of carbonates, which are commonly found as fracture filling minerals in rocks, can provide information about geochemical conditions present during formation including in deep subsurface environments. A dating technique for the carbonates using laser ablation-multiple collector-inductively coupled plasma mass spectrometry (LA-MC-ICPMS) is still immature partly because of a lack of a consensus international carbonate standard for the in-situ dating technique. In this study, we performed a survey on the carbonate standard materials that may be suitable for high precision U-Th-Pb dating using LA-MC-ICPMS. We examined carbonate standard materials JCp-1 and JCt-1 issued by the Geological Survey of Japan (GSJ). Based on solution-based bulk analysis using MC-ICP-MS, heterogeneities in Pb isotope compositions were confirmed. Nevertheless, the 206Pb-based isotopic compositions were all within 1.2 per mill variations acceptable for a standard used for age determination using LA-MC-ICPMS. Additional tests on the heterogenities in U-Th-Pb compositions of the carbonate standards along with determinations of other trace elements using a 2D imaging LA-ICP-MS are ongoing. Examinations on both natural standards and synthetic standards are ongoing for further efforts in determination of the standard suitable for U-Th-Pb dating of carbonates.
