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Sawada, Hikaru*; Niki, Sota*; Nagata, Mitsuhiro; Hirata, Takafumi*
Minerals (Internet), 12(1), p.107_1 - 107_15, 2022/01
Times Cited Count：1 Percentile：53.59(Geochemistry & Geophysics)The Oeyama ophiolite is one of the oldest components in Japanese Islands and important to reveal the initiation of plate subduction along proto-Japan. This study performed U-Pb-Hf isotopic and trace element analyses of zircon in gabbroic rocks. The weight mean of 
Pb/
U dates from zircons of the Oeyama ophiolite is 544 
4 Ma (2 sigma). Trace element analysis of the zircons exhibit that the host rock was derived from the mantle depleted of incompatible elements like mid-oceanic ridge basalt. The present igneous age and geochemical feature of the zircons is consistent with previous work for other part of the Oeyama ophiolite. Zircon Lu-Hf isotopic analysis also indicate that the gabbroic rock was derived from the depleted mantle domain. The Hf isotopic signature is more depleted than those of the zircons in jadeitite associated with the Oeyama ophiolite. This result implies that the older crustal material was involved into the initial oceanic plate subduction along the proto-Japan arc.
Miyajima, Yusuke*; Saito, Ayaka*; Kagi, Hiroyuki*; Yokoyama, Tatsunori; Takahashi, Yoshio*; Hirata, Takafumi*
Geostandards and Geoanalytical Research, 45(1), p.189 - 205, 2021/03
Times Cited Count：3 Percentile：28.5(Geochemistry & Geophysics)Uncertainty for elemental and isotopic analyses of calcite by LA-ICP-MS is largely controlled by the homogeneity of the reference materials (RMs) used for normalization and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb, and rare earth elements into calcite through heat- and pressure-induced crystallization from amorphous calcium carbonate that was precipitated from element-doped reagent solution. X-ray absorption spectra showed that U was present as U(VI) in the synthesized calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison to synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The 
Pb/Pb ratio in the calcite showed 
1% variations, while the U/Pb ratio showed 3-24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC-1, with analytical uncertainty as low as 3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions, and is a promising alternative to natural calcite RMs for U-Pb geochronology.
Sueoka, Shigeru; Shimada, Koji; Terusawa, Shuji*; Iwano, Hideki*; Danhara, Toru*; Ogita, Yasuhiro; Hirata, Takafumi*
Chishitsugaku Zasshi, 127(1), p.25 - 39, 2021/01
no abstracts in English
Takahashi, Yutaka*; Mikoshiba, Masumi*; Shimura, Toshiaki*; Nagata, Mitsuhiro; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Island Arc, 30(1), p.e12393_1 - e12393_15, 2021/01
Times Cited Count：2 Percentile：29.34(Geosciences, Multidisciplinary)The Hidaka metamorphic belt is an excellent example of island-arc-type crust, and in this belt the metamorphic grade increases westwards from unmetamorphosed sediment up to the granulite facies. The metamorphic age of the belt had previously been considered to be ca. 55 Ma. However, zircons from the granulites in the lower sequence have given U-Pb ages of ca. 21-19 Ma and a preliminary report on zircons from pelitic gneiss in the upper sequence gave a U-Pb age of ca. 40 Ma. In this paper we provide new U-Pb ages for zircons from the pelitic gneisses in the upper sequence in order to assess the metamorphic age and also the maximum depositional age of the sedimentary protolith. The weighted mean Pb/U ages and 2 sigma errors for zircons from biotite gneiss in the central area of the belt are 39.6 0.9 Ma for metamorphic overgrowth rims and 53.1 0.9 Ma for the youngest inherited detrital cores. The ages of zircons from cordierite-biotite gneiss in the southern area are 35.9 0.7 Ma for overgrowth rims and 46.5 2.8 Ma for the youngest detrital cores. These results indicate that the metamorphism of the upper sequence took place at ca. 40-36 Ma, and that the sedimentary protolith was deposited after ca. 53-47 Ma. These metamorphic ages are consistent with the reported ages of ca. 37-36 Ma plutonic rocks in the upper sequence, but contrast with the ca. 21-19 Ma ages of metamorphic and plutonic rocks in the lower sequence. Therefore, we conclude, that the upper and lower metamorphic sequences developed independently but became coupled before ca. 19 Ma as a result of dextral reverse tectonic movements, as indicated by the intrusion of ca. 19-18 Ma magmas, possibly generated in the lower sequence, into the upper sequence.
Niwa, Masakazu; Amamiya, Hiroki*; Yonaga, Yusuke; Ogita, Yasuhiro; Yasue, Kenichi*; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Chishitsugaku Zasshi, 126(5), p.267 - 283, 2020/05
U-Pb and fission-track (FT) ages from single zircon grain were measured for three tephra samples (TKB3, TKB6, and TKB7) intercalated in Neogene to Quaternary in Horonobe area, Hokkaido, to understand their depositional ages. In TKB3 and TKB6, weighed average U-Pb and FT ages for zircon grains within the youngest age range are coincident within a range of error 2 
each other, which suggest that their ages correspond to the eruption ages. In TKB7, FT ages for most zircons are reset to their U-Pb ages or younger. The weighed average FT age for all analyzed zircons and weighed average U-Pb age for zircon grains within the youngest age range are coincident within a range of error 2 each other. Thus, their ages could also show the eruption age.
Ueki, Tadamasa; Niwa, Masakazu; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*
Chishitsugaku Zasshi, 125(3), p.227 - 236, 2019/03
no abstracts in English
Yuguchi, Takashi*; Sueoka, Shigeru; Iwano, Hideki*; Izumino, Yuya*; Ishibashi, Masayuki; Danhara, Toru*; Sasao, Eiji; Hirata, Takafumi*; Nishiyama, Tadao*
Journal of Asian Earth Sciences, 169, p.47 - 66, 2019/01
Times Cited Count：14 Percentile：69.07(Geosciences, Multidisciplinary)This study presents position-by-position 
paths within a granitic pluton based on thermochronological data, and describes their constraints and their relationship with fracture frequency, as an example from the Toki granite, central Japan. The cooling paths have position-specific characteristics; a single path does not represent the cooling behavior of the entire pluton. Such position-specific paths enable us to evaluate three-dimensional thermal evolution within the granitic pluton, and thus can clarify the detailed formation history of the entire pluton after the incipient intrusion of the granitic magma into the shallow crust. This study reveals the relationship between position-specific paths and fracture frequency, and thus provides a criterion for evaluating the fracture population in terms of thermal stress.
Yokoyama, Tatsunori; Kimura, Junichi*; Mitsuguchi, Takehiro; Danhara, Toru*; Hirata, Takafumi*; Sakata, Shuhei*; Iwano, Hideki*; Maruyama, Seiji*; Chang, Q.*; Miyazaki, Takashi*; et al.
Geochemical Journal, 52(6), p.531 - 540, 2018/12
Times Cited Count：16 Percentile：69.06(Geochemistry & Geophysics)Sasao, Eiji; Danhara, Toru*; Iwano, Hideki*; Hirata, Takafumi*
Chishitsugaku Zasshi, 124(2), p.141 - 150, 2018/02
Here U-Pb and reassessed fission track (FT) ages are presented for samples from the Miocene Mizunami and Iwamura groups in the southeastern Gifu Prefecture, central Japan. The U-Pb ages of three tuff samples coincide with the reassessed FT ages within the error range. These new U-Pb and reassessed FT ages are consistent with those reported in previous microfossil and paleomagnetic studies, which indicate the following depositional history: The Hongo and Akeyo formations of the Mizunami Group were deposited at ~19-18 Ma and ca. 18 Ma, respectively, and the lower part of the Toyama Formation of the Iwamura Group was deposited ca. 18 Ma.
Ikuta, Masafumi*; Niwa, Masakazu; Danhara, Toru*; Yamashita, Toru*; Maruyama, Seiji*; Kamataki, Takanobu*; Kobayashi, Tetsuo*; Kurosawa, Hideki*; Kokubu, Yoko; Hirata, Takafumi*
Chishitsugaku Zasshi, 122(3), p.89 - 107, 2016/03
We carried out mineral composition analysis, morphological classification of volcanic glass shards and refractive index measurements of the glass shards and orthopyroxene from the eruption products from Sakurajima volcano. In this study, refractive indexes of hydrated and non-hydrated parts within each individual glass shard were measured separately. This measurements in consideration of hydration in glass shards made possible distinct discrimination of the pumice samples from the three eruption events of Bunmei, An-ei, and Taisho. Pumice layers in the core samples obtained from the southern part of the Miyazaki Plain were also identified as the Sakurajima-Bunmei tephra by the above mentioned analyses, and also by the data of radiocarbon dating for coaly materials included in the pumice layers. Occurrences of the pumice layers suggest that the Sakurajima-Bunmei tephra could have reached the southern part of Miyazaki Plain as pumice falls.
Suzuki, Yohei*; Mukai, Hiroki*; Ishimura, Toyoho*; Yokoyama, Takatomi*; Sakata, Shuhei*; Hirata, Takafumi*; Iwatsuki, Teruki; Mizuno, Takashi
Scientific Reports (Internet), 6, p.22701_1 - 22701_6, 2016/03
Times Cited Count：11 Percentile：38.59(Multidisciplinary Sciences)The stimulation of bacterial activities that convert hexavalent uranium to tetravalent uranium appears to be feasible for cost-effective remediation of contaminated aquifers. However, U(VI) reduction typically results in the precipitation of U(IV) particles less than 5 nanometers in diameter. Here we show that U(IV) nanoparticles of coffinite formed in fracture-filling calcium carbonate in a granitic aquifer. As the microbiologically induced precipitation of calcium carbonate in aquifer systems worldwide is extremely common, we anticipate simultaneous stimulation of microbial activities for precipitation reactions of calcium carbonate and U(IV) nanoparticles, which leads to long-term sequestration of uranium and other radionuclides in contaminated aquifers and deep geological repositories.
Yuguchi, Takashi*; Iwano, Hideki*; Kato, Takenori*; Sakata, Shuhei*; Hattori, Kentaro*; Hirata, Takafumi*; Sueoka, Shigeru; Danhara, Toru*; Ishibashi, Masayuki; Sasao, Eiji; et al.
Journal of Mineralogical and Petrological Sciences, 111(1), p.9 - 34, 2016/02
Times Cited Count：16 Percentile：56.02(Mineralogy)Zircon growth collected from a granitic pluton shows four (1st - 4th) events with specific mechanisms, crystallization temperatures and U-Pb ages, revealing the sequential formation process from intrusion through emplacement to crystallization / solidification. The events are recognized by: (1) internal structure of zircon based on the cathodoluminescence observation, (2) crystallization temperatures by the Ti-in-zircon thermometer in the internal structure and (3) U-Pb ages in the internal structure.
Irisawa, Keita; Hirata, Takafumi*; Tanimizu, Masaharu*
no journal, ,
Currently, the best chronometer for metal-silicate separation is 182Hf-182W systematics. In the previous studies, the Earth's core could have separated from the silicate mantle within the first 30 million years of accretion, if Earth's accretion was terminated by a giant impact and accompanied by complete metal-silicate equilibration. In order to constrain the age of the core-mantle differentiation and of the Moon-forming giant impact in the Earth, we should estimate W behavior between metal and a silicate phases through the planetary formation. To determine W isotopic fractionation for chondrites, achondrites, and iron meteorites have potential interpretation of planetary core-mantle differentiation. In this study, an external correction technique using 185Re/187Re ratio was applied in order to detect W isotopic fractionation for various meteoritic materials, and therefore, we will discuss about a new interpretation of the age of Moon-forming giant impact.
Yamada, Kunimi; Kogiso, Tetsu*; Uesugi, Kentaro*; Hirata, Takafumi*
no journal, ,
no abstracts in English
Yamada, Kunimi; Kogiso, Tetsu*; Uesugi, Kentaro*; Hirata, Takafumi*
no journal, ,
no abstracts in English
Yamada, Kunimi; Kogiso, Tetsu*; Uesugi, Kentaro*; Hirata, Takafumi*
no journal, ,
no abstracts in English
Yuguchi, Takashi; Iwano, Hideki*; Danhara, Toru*; Hirata, Takafumi*; Sueoka, Shigeru; Hattori, Kentaro*; Sakata, Shuhei*; Ishibashi, Masayuki; Kunimaru, Takanori; Nishiyama, Tadao*
no journal, ,
no abstracts in English
Yuguchi, Takashi; Iwano, Hideki*; Hattori, Kentaro*; Sakata, Shuhei*; Sueoka, Shigeru; Danhara, Toru*; Hirata, Takafumi*; Ishibashi, Masayuki; Kunimaru, Takanori; Nishiyama, Tadao*
no journal, ,
no abstracts in English
Yuguchi, Takashi*; Iwano, Hideki*; Kato, Takenori*; Sakata, Shuhei*; Hattori, Kentaro*; Hirata, Takafumi*; Sueoka, Shigeru; Danhara, Toru*; Ishibashi, Masayuki; Sasao, Eiji; et al.
no journal, ,
Zircon growth collected from a granitic pluton shows four (1st - 4th) events with specific mechanisms, crystallization temperatures and U-Pb ages, revealing the sequential formation process from intrusion through emplacement to crystallization / solidification. The events are recognized by: (1) internal structure of zircon based on the cathodoluminescence observation, (2) crystallization temperatures by the Ti-in-zircon thermometer in the internal structure and (3) U-Pb ages in the internal structure.
Yokoyama, Tatsunori; Kokubu, Yoko; Murakami, Hiroaki; Hirata, Takafumi*; Sakata, Shuhei*; Danhara, Toru*; Iwano, Hideki*; Chang, Q.*; Kimura, Junichi*
no journal, ,
The chronological information about carbonates is useful for modeling and enables forecast of geological and geochemical environmental changes by simulating. The U-Th-Pb dating method for carbonates which were formed at reducing environment remain to be established. The final goal of our study is to establish in situ U-Th-Pb dating method for carbonates which are filling cracks in pervious rock like fault rocks. In this study, the U-Th-Pb elemental and isotopic two-dimension distribution for an ammonite fossil were visualized by "Imaging" method using Laser-ablation ICP Mass Spectrometry. In U-Pb isotope analysis for carbonates in cracks of granites, we could not obtain significant U-Pb age data by the lack of uranium and influence of non-radiogenic common lead. When the concentration of lead is sufficiently high for the measurement, we obtained reliable isotopic data from carbonates and their lead isotopic composition reflected characteristic composition of their origin water.
