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Journal Articles

Study of mechanism of mixed conduction due to electrons and oxygen ions in (La$$_{0.75}$$Sr$$_{0.25}$$)MnO$$_{3.00}$$ and (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$ through rietveld refinement and MEM analysis

Ito, Takanori*; Shirasaki, Saori*; Fujie, Yoshinori*; Kitamura, Naoto*; Idemoto, Yasushi*; Osaka, Keiichi*; Hirosawa, Ichiro*; Igawa, Naoki

Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 77(2), p.161 - 168, 2009/02

 Times Cited Count:3 Percentile:8.28(Electrochemistry)

We analyzed the mechanism of mixed conduction due to electrons and oxygen ions in (La$$_{0.75}$$Sr$$_{0.25}$$)MnO$$_{3.00}$$ and (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$ through the Rietveld refinement and maximum entropy method analyses of neutron and synchrotron X-ray diffractions. It was found that Mn-O plane in (La$$_{0.75}$$Sr$$_{0.25}$$)MnO$$_{3.00}$$ has a strong, isotropic covalent bond that enables conduction of electrons. The (Co, Fe)-O2 plane with a covalent bond and a low concentration of oxygen vacancies in (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$ can also conduct electrons. On the other hand, the (Ba, Sr)-O1 plane in (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$, which has a high concentration of oxygen vacancies, large isotropic displacement parameter, and a strong ionic bond, is responsible for the diffusion of oxygen ions.

Journal Articles

Determination of crystal structure and charge density of (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$ by Rietveld refinement and maximum entropy method analysis

Ito, Takanori*; Nishida, Yuki*; Tomita, Aya*; Fujie, Yoshinori*; Kitamura, Naoto*; Idemoto, Yasushi*; Osaka, Keiichi*; Hirosawa, Ichiro*; Igawa, Naoki

Solid State Communications, 149(1-2), p.41 - 44, 2009/01

 Times Cited Count:35 Percentile:77.13(Physics, Condensed Matter)

The crystal structure and charge density of (Ba$$_{0.5}$$Sr$$_{0.5}$$)(Co$$_{0.8}$$Fe$$_{0.2}$$)O$$_{2.33}$$ were investigated by the Rietveld refinement method and the maximum entropy method by using neutron and synchrotron X-ray diffraction. The crystal structure was refined by using the split atom model to cation sites with the space group, ${it Pnma}$. The site occupancies of O1(4${it c}$) and O2(8${it d}$) sites were 0.59 and 0.87, respectively. It was found that the (Co, Fe)-O2 plane in the sample has anisotropic covalent and ionic bands, and that the (Ba, Sr)-O1 bond was ionic with a low charge density.

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