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Journal Articles

Hydrogen adsorption on single-walled carbon nanotubes studied by core-level photoelectron spectroscopy and Raman spectroscopy

Tokura, Akio*; Maeda, Fumihiko*; Teraoka, Yuden; Yoshigoe, Akitaka; Takagi, Daisuke*; Homma, Yoshikazu*; Watanabe, Yoshio*; Kobayashi, Yoshihiro*

Carbon, 46(14), p.1903 - 1908, 2008/11

 Times Cited Count:18 Percentile:51.99(Chemistry, Physical)

We have investigated the adsorption of atomic hydrogen on vertically aligned carbon nanotube using ${it in situ}$ synchrotron-radiation-based core-level photoelectron spectroscopy and Raman spectroscopy. From C1s spectra, we identified a peak component due to CH bonds of carbon atoms in single-walled carbon nanotubes. We also found the suppression of $$pi$$-plasmon excitation, indicating that the hydrogen adsorption deforms the bonding structure. Raman spectra of the single-walled carbon nanotubes indicated that the radial-breathing-mode intensities decreased due to the adsorption-induced bonding-structure deformation. Moreover, the decrease for single-walled carbon nanotubes with small-diameter was more severe than that for large-diameter. Our results strongly suggest that the hydrogen adsorption, which induces the structure deformation from sp$$^{2}$$ to sp$$^{3}$$ bonding, depends on the diameter of SWCNTs.

Oral presentation

Soft X-ray photoelectron spectroscopy study of atomic hydrogen exposure on carbon nanotubes

Tokura, Akio*; Maeda, Fumihiko*; Takagi, Daisuke*; Homma, Yoshikazu*; Yoshigoe, Akitaka; Teraoka, Yuden; Watanabe, Yoshio*; Kobayashi, Yoshihiro*

no journal, , 

no abstracts in English

Oral presentation

Diameter dependence of hydrogen adsorption on single-walled carbon nanotubes

Tokura, Akio*; Maeda, Fumihiko*; Teraoka, Yuden; Yoshigoe, Akitaka; Takagi, Daisuke*; Homma, Yoshikazu*; Watanabe, Yoshio*; Kobayashi, Yoshihiro*

no journal, , 

We have investigated the adsorption of atomic hydrogen on vertically aligned SWNT film. The effects of hydrogen adsorption were investigated by photoelectron spectroscopy and Raman spectroscopy. By fitting C 1s core level spectrum, we found the component attributed to hydrogenation of carbon. The suppression of $$pi$$ plasmons was also found. These results indicate that hydrogen adsorption induced bonding structure deformation. Raman spectra demonstrate that the radial-breathing-mode intensity of small-diameter SWNTs is more severely decreased than that of large-diameter SWNTs. The G-band/D-band ratio also decreased after the irradiation. These results indicate the disordering of graphene on small-diameter SWNTs is induced more easily. Our results indicate that the adsorption coefficient of hydrogen atoms for SWNTs with small diameter is higher than that for SWNTs with large diameter.

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