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Ikeda, Kazutaka*; Sashida, Sho*; Otomo, Toshiya*; Oshita, Hidetoshi*; Honda, Takashi*; Hawai, Takafumi*; Saito, Hiraku*; Ito, Shinichi*; Yokoo, Tetsuya*; Sakaki, Koji*; et al.
International Journal of Hydrogen Energy, 51(Part A), p.79 - 87, 2024/01
Times Cited Count:0 Percentile:0.01(Chemistry, Physical)Sakaki, Koji*; Kim, H.*; Majzoub, E. H.*; Machida, Akihiko*; Watanuki, Tetsu*; Ikeda, Kazutaka*; Otomo, Toshiya*; Mizuno, Masataka*; Matsumura, Daiju; Nakamura, Yumiko*
Acta Materialia, 234, p.118055_1 - 118055_10, 2022/08
Times Cited Count:10 Percentile:83.19(Materials Science, Multidisciplinary)Wang, X.*; Tang, X.*; Zhang, P.*; Wang, Y.*; Gao, D.*; Liu, J.*; Hui, K.*; Wang, Y.*; Dong, X.*; Hattori, Takanori; et al.
Journal of Physical Chemistry Letters (Internet), 12(50), p.12055 - 12061, 2021/12
Times Cited Count:6 Percentile:49.65(Chemistry, Physical)Substituted polyacetylene is expected to improve the chemical stability, physical properties, and additional functions of the polyacetylene backbones, but its diversity is very limited. Here, by applying external pressure on solid acetylenedicarboxylic acid, we report the first crystalline poly-dicarboxylacetylene with every carbon on the trans-polyacetylene backbone bonded to a carboxyl group, which is very hard to synthesize by traditional methods. This unique structure combines the extremely high content of carbonyl groups and high conductivity of a polyacetylene backbone, which exhibits a high specific capacity and excellent cycling/rate performance as a Li-ion battery (LIB) anode. We present a completely functionalized crystalline polyacetylene and provide a high-pressure solution for the synthesis of polymeric LIB materials and other polymeric materials with a high content of active groups.
Ikeda, Reiji*; Ho, H. Q.; Nagasumi, Satoru; Ishii, Toshiaki; Hamamoto, Shimpei; Nakano, Yumi*; Ishitsuka, Etsuo; Fujimoto, Nozomu*
JAEA-Technology 2021-015, 32 Pages, 2021/09
Burnup calculation of the HTTR considering temperature distribution and detailed burning regions was carried out using MVP-BURN code. The results show that the difference in k, as well as the difference in average density of some main isotopes, is insignificant between the cases of uniform temperature and detailed temperature distribution. However, the difference in local density is noticeable, being 6% and 8% for U and Pu, respectively, and even 30% for the burnable poison B. Regarding the division of burning regions to more detail, the change of k is also small of 0.6%k/k or less. The small burning region gives a detailed distribution of isotopes such as U, Pu, and B. As a result, the effect of graphite reflector and the burnup behavior could be evaluated more clearly compared with the previous study.
Zhang, P.*; Tang, X.*; Wang, Y.*; Wang, X.*; Gao, D.*; Li, Y.*; Zheng, H.*; Wang, Y.*; Wang, X.*; Fu, R.*; et al.
Journal of the American Chemical Society, 142(41), p.17662 - 17669, 2020/10
Times Cited Count:21 Percentile:73.26(Chemistry, Multidisciplinary)Solid-state topochemical polymerization (SSTP) is a promising method to construct functional crystalline polymeric materials, but in contrast to various reactions that happen in solution, only very limited types of SSTP reactions are reported. Diels-Alder (DA) and dehydro-DA (DDA) reactions are textbook reactions for preparing six-membered rings in solution but are scarcely seen in solid-state synthesis. Here, using multiple cutting-edge techniques, we demonstrate that the solid 1,4-diphenylbutadiyne (DPB) undergoes a DDA reaction under 10-20 GPa with the phenyl as the dienophile. The crystal structure at the critical pressure shows that this reaction is "distance-selected". The distance of 3.2 between the phenyl and the phenylethynyl facilitates the DDA reaction, while the distances for other DDA and 1,4-addition reactions are too large to allow the bonding. The obtained products are crystalline armchair graphitic nanoribbons, and hence our studies open a new route to construct the crystalline carbon materials with atomic-scale control.
Li, X.*; Liu, P.-F.*; Zhao, E.*; Zhang, Z.*; Guide, T.*; Le, M. D.*; Avdeev, M.*; Ikeda, Kazutaka*; Otomo, Toshiya*; Kofu, Maiko; et al.
Nature Communications (Internet), 11, p.942_1 - 942_9, 2020/02
Times Cited Count:37 Percentile:90.10(Multidisciplinary Sciences)In high-performance thermoelectric materials, there are two main low thermal conductivity mechanisms: the phonon anharmonic and phonon scattering resulting from the dynamic disorder, which have been successfully revealed by inelastic neutron scattering. Using neutron scattering and ab initio calculations, we report here a mechanism of static local structure distortion combined with phonon-anharmonic-induced ultralow lattice thermal conductivity in -MgAgSb. Since the transverse acoustic phonons are almost fully scattered by the intrinsic distorted rocksalt sublattice in this compound, the heat is mainly transported by the longitudinal acoustic phonons. The ultralow thermal conductivity in -MgAgSb is attributed to its atomic dynamics being altered by the structure distortion, which presents a possible microscopic route to enhance the performance of similar thermoelectric materials.
Wu, H.*; Wang, Y.*; Ikeda, Atsushi; Miller, C. J.*; Waite, T. D.*
Environmental Science; Water Research & Technology, 5(8), p.1400 - 1411, 2019/08
Times Cited Count:7 Percentile:36.83(Engineering, Environmental)In this study, the distributions of iron and phosphorus species in a 1.25 m pilot scale submerged membrane bioreactor dosed with Fe(II) salts to either the membrane chamber or the 1st anoxic chamber were determined using X-ray absorption spectroscopy (XAS) at the iron and phosphorus K-edges. Significant differences in the distribution of Fe species were evident at the commencement of dosing depending on the chamber to which Fe(II) was dosed though these differences were much less distinct by the time steady state conditions were achieved. Both the co-precipitation of P with Fe and adsorption of phosphorus to iron oxides play important roles with regard to the removal of phosphorus from the MBR supernatant with the results of this work suggesting that P removal via formation of Fe(III)-phosphate mineral species is preferred if Fe(II) is dosed to the membrane chamber rather than the 1st anoxic chamber.
Kobayashi, Kazuhiro; Torikai, Yuji*; Saito, Makiko; Alimov, V. Kh.*; Miya, Naoyuki; Ikeda, Yoshitaka
Fusion Science and Technology, 67(2), p.428 - 431, 2015/03
Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)Disassembly of the JT-60U torus was started in 2010 after 18 years deuterium operations. In the disassembly of the JT-60U torus, tritium retention in the vacuum vessel of the JT-60U is one of the most important safety issues for the fusion reactor. It was very important to study the tritium behavior in Inconel 625 from viewpoint of the clearance procedure in the future plan. After the tritium release for about 1 year at 298 K, the residual tritium in the specimen was released by heating up to 1073 K, and then the residual tritium in the specimen was measured by chemical etching method. Most of the chemical form of the released tritium was HTO. The contaminated specimen by tritium was released continuously the diffusible tritium under the ambient condition. In the tritium release experiment, most of tritium in the specimen was released during 1 year.
Kim, H.*; Sakaki, Koji*; Asano, Kota*; Ikeda, Kazutaka*; Otomo, Toshiya*; Machida, Akihiko; Watanuki, Tetsu; Nakamura, Yumiko*
Nihon Kinzoku Gakkai-Shi, 79(3), p.131 - 136, 2015/03
Times Cited Count:0 Percentile:0.01(Metallurgy & Metallurgical Engineering)no abstracts in English
Makino, Risa; Swinhoe, M. T.*; Suzuki, Hisanori; Ikeda, Atsushi*; Menlove, H. O.*; Shimizu, Yasuyuki; Nakamura, Hironobu
Kaku Busshitsu Kanri Gakkai (INMM) Nihon Shibu Dai-35-Kai Nenji Taikai Rombunshu (Internet), 9 Pages, 2015/01
The Inventory Verification Sample system (INVS) is a non-destructive assay system for samples to quantify the Pu amount in Pu nitrate solutions and MOX with 31.3% of counting efficiency. It has been used for IAEA verification measurement for many years at the Plutonium Conversion Development Facility for the samples taken at the timing of PIV etc. as a partial defects verification system (uncertainty: about 3-5%). If the measurement uncertainty can be improved (to 1%), it is expected that the usage can be extended to the operator's own measurements in MC&A to reduce the number of destructive analyses. In order to improve the measurement uncertainty for solution samples, after optimization of detector parameter and sample position, we conducted 3 different types of calibration method that is passive calibration curve, known- and multiplicity method to achieve the target uncertainty. To perform calibration and control the measurement quality, MOX fuel pellets with known Pu amount are fabricated and used. In the range of concentration of typical solution samples, we could confirm good correlations between measured doubles and Pu effective mass in the three methods. Especially, it was confirmed that the conventional calibration curve method could meet our target uncertainty (1%).
Tonegawa, Sho*; Hashimoto, Kenichiro*; Ikada, Kisuke*; Tsuruhara, Yugo*; Lin, Y.-H.*; Shishido, Hiroaki*; Haga, Yoshinori; Matsuda, Tatsuma; Yamamoto, Etsuji; Onuki, Yoshichika; et al.
Physical Review B, 88(24), p.245131_1 - 245131_13, 2013/12
Times Cited Count:12 Percentile:48.54(Materials Science, Multidisciplinary)Tonegawa, Sho*; Hashimoto, Kenichiro*; Ikada, Kisuke*; Lin, Y.-H.*; Shishido, Hiroaki*; Haga, Yoshinori; Matsuda, Tatsuma; Yamamoto, Etsuji; Onuki, Yoshichika; Ikeda, Hiroaki*; et al.
Physical Review Letters, 109(3), p.036401_1 - 036401_5, 2012/07
Times Cited Count:53 Percentile:87.38(Physics, Multidisciplinary)Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Armendariz, R.*; et al.
Physical Review C, 83(6), p.064903_1 - 064903_29, 2011/06
Times Cited Count:184 Percentile:99.42(Physics, Nuclear)Transverse momentum distributions and yields for , and in collisions at = 200 and 62.4 GeV at midrapidity are measured by the PHENIX experiment at the RHIC. We present the inverse slope parameter, mean transverse momentum, and yield per unit rapidity at each energy, and compare them to other measurements at different collisions. We also present the scaling properties such as and scaling and discuss the mechanism of the particle production in collisions. The measured spectra are compared to next-to-leading order perturbative QCD calculations.
Ikeda, Makoto; Munakata, Masahiro; Sakai, Ryutaro; Kimura, Hideo; Jia, H.*; Matsuba, Hisashi*
Nihon Chikasui Gakkai 2011-Nen Shunki Koenkai Koen Yoshi, p.86 - 91, 2011/05
no abstracts in English
Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Aramaki, Y.*; et al.
Physical Review C, 83(4), p.044912_1 - 044912_16, 2011/04
Times Cited Count:9 Percentile:52.86(Physics, Nuclear)Measurements of electrons from the decay of open-heavy-flavor mesons have shown that the yields are suppressed in Au+Au collisions compared to expectations from binary-scaled collisions. Here we extend these studies to two particle correlations where one particle is an electron from the decay of a heavy flavor meson and the other is a charged hadron from either the decay of the heavy meson or from jet fragmentation. These measurements provide more detailed information about the interaction between heavy quarks and the quark-gluon matter. We find the away-side-jet shape and yield to be modified in Au+Au collisions compared to collisions.
Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Y.*; Al-Bataineh, H.*; Alexander, J.*; Aoki, K.*; Aphecetche, L.*; Armendariz, R.*; et al.
Physical Review D, 83(5), p.052004_1 - 052004_26, 2011/03
Times Cited Count:177 Percentile:98.48(Astronomy & Astrophysics)The PHENIX experiment at RHIC has measured the invariant differential cross section for production of , , and mesons in collisions at = 200 GeV. The spectral shapes of all hadron transverse momentum distributions are well described by a Tsallis distribution functional form with only two parameters, and , determining the high and characterizing the low regions for the spectra, respectively. The integrated invariant cross sections calculated from the fitted distributions are found to be consistent with existing measurements and with statistical model predictions.
Okazaki, Ryuji*; Shibauchi, Takasada*; Shi, H. J.*; Haga, Yoshinori; Matsuda, Tatsuma; Yamamoto, Etsuji; Onuki, Yoshichika; Ikeda, Hiroaki*; Matsuda, Yuji*
Science, 331(6016), p.439 - 442, 2011/01
Times Cited Count:215 Percentile:98.04(Multidisciplinary Sciences)Ikeda, Atsushi; Tsushima, Satoru*; Takao, Koichiro*; Rossberg, A.*; Funke, H.*; Scheinost, A. C.*; Bernhard, G.*; Yaita, Tsuyoshi; Hennig, C.*
Inorganic Chemistry, 48(24), p.11779 - 11787, 2009/12
Times Cited Count:34 Percentile:79.53(Chemistry, Inorganic & Nuclear)The electrochemical behavior and complex structure of Np carbonato complexes have been investigated in aqueous NaCO and NaCO/NaOH solutions at different oxidation states by using cyclic voltammetry, X-ray absorption spectroscopy, and density functional theory calculations. The end-member complexes of penta- and hexavalent Np in 1.5 M NaCO with pH = 11.7 have been determined as a transdioxo neptunyl tricarbonato complex, [NpO(CO)] ( = 5 for Np, and 4 for Np). In contrast, the electrochemical oxidation of Np in a highly basic carbonate solution of 2.0M NaCO/1.0M NaOH (pH 13) yielded a stable heptavalent Np complex of [Np O(OH)], indicating that the oxidation reaction from Np to Np in the carbonate solution involves a drastic structural rearrangement from the transdioxo configuration to a square-planar-tetraoxo configuration, as well as exchanging the coordinating anions from carbonate ions (CO) to hydroxide ions (OH).
Ikeda, Atsushi; Hennig, C.*; Rossberg, A.*; Funke, H.*; Scheinost, A. C.*; Bernhard, G.*; Yaita, Tsuyoshi
ESRF Highlights 2008, p.99 - 100, 2009/02
Structural arrangement of Np species has been investigated in various aqueous solutions by synchrotron-based X-ray absorption fine structure (XAFS) spectroscopy. The obtained results revealed that Np(IV) dominantly forms a spherically coordinated decahydrate complex, [Np(HO)], while Np(V) and -(VI) form a pentahydrate neptunyl complex, [NpO(HO)].
Matsukawa, Makoto; Kikuchi, Mitsuru; Fujii, Tsuneyuki; Fujita, Takaaki; Hayashi, Takao; Higashijima, Satoru; Hosogane, Nobuyuki; Ikeda, Yoshitaka; Ide, Shunsuke; Ishida, Shinichi; et al.
Fusion Engineering and Design, 83(7-9), p.795 - 803, 2008/12
Times Cited Count:17 Percentile:72.53(Nuclear Science & Technology)no abstracts in English