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Journal Articles

Direct and indirect processes in photon-stimulated ion desorption from condensed formamide

Ikeura, Hiromi*; Sekiguchi, Tetsuhiro; Baba, Yuji; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*

Surface Science, 593(1-3), p.303 - 309, 2005/11

 Times Cited Count:5 Percentile:26.14(Chemistry, Physical)

no abstracts in English

Journal Articles

Characterization of air-exposed surface $$beta$$-FeSi$$_{2}$$ fabricated by ion beam sputter deposition method

Saito, Takeru; Yamamoto, Hiroyuki; Yamaguchi, Kenji; Nakanoya, Takamitsu; Hojo, Kiichi; Haraguchi, Masaharu*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Tanaka, Tomoaki*; Shimada, Hiromichi*

Nuclear Instruments and Methods in Physics Research B, 206, p.321 - 325, 2003/05

 Times Cited Count:7 Percentile:46.83(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Fabrication of $$beta$$-FeSi$$_{2}$$ thin films on Si(III) surface by solid phase epitaxy (SPE) analyzed by means of synchrotron radiation XPS (SR-XPS)

Saito, Takeru; Yamamoto, Hiroyuki; Asaoka, Hidehito; Haraguchi, Masaharu*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Tanaka, Tomoaki*; Shimada, Hiromichi*; Hojo, Kiichi

Analytical Sciences (CD-ROM), 17(Suppl.), p.1073 - 1076, 2002/03

no abstracts in English

Journal Articles

XAS and XPS combined analysis using high-resolution and high-flux soft X-ray from synchrotron radiation

Matsubayashi, Nobuyuki*; Tanaka, Tomoaki*; Imamura, Motoyasu*; Shimada, Hiromichi*; Saito, Takeru

Analytical Sciences (CD-ROM), 17(Suppl.), p.119 - 121, 2002/03

no abstracts in English

Journal Articles

In-situ XAFS analysis of Y zeolite-supported Rh catalysts during high-pressure hydrogenation of CO$$_{2}$$

Bando, Kyoko*; Saito, Takeru; Sato, Koichi*; Tanaka, Tomoaki*; Dumeignil, F.*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*

Topics in Catalysis, 18(1-2), p.59 - 65, 2002/01

no abstracts in English

Journal Articles

Orientation-selective excitation and dissociation in multilayer benzene

Sekiguchi, Tetsuhiro; Baba, Yuji; Sekiguchi, Hiromi*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*

Applied Surface Science, 169-170(1-4), p.287 - 291, 2001/06

no abstracts in English

Journal Articles

Fragmentation and charge-neutralization pathways depending on molecular orientation at surfaces

Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji

Surface Science, 482-485(Part.1), p.279 - 284, 2001/06

no abstracts in English

Journal Articles

Formation process of $$beta$$-FeSi$$_{2}$$ on Si(111) substrate studied by means of SR-XPS

Saito, Takeru; Yamamoto, Hiroyuki; Haraguchi, Masaharu*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Tanaka, Tomoaki*; Shimada, Hiromichi*; Hojo, Kiichi

Photon Factory Activity Report 2001, (19), P. 205, 2001/00

no abstracts in English

Journal Articles

Selective fragmentation of surface molecules excited by linearly polarized SR

Sekiguchi, Tetsuhiro; Sekiguchi, Hiromi*; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji

Photon Factory Activity Report 1999, Part B, P. 325, 2000/11

no abstracts in English

Journal Articles

Site-specific ion desorption from condensed C- and N-deuterated formamide near the caron and nitrogen K-edge

Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji

Surface Science, 454-456, p.407 - 411, 2000/05

 Times Cited Count:5 Percentile:32.8(Chemistry, Physical)

no abstracts in English

Journal Articles

Investigation on the $$beta$$-FeSi$$_{2}$$ formation mechanisms on Si(111) substrate by means of SR-XPS

Saito, Takeru; Yamamoto, Hiroyuki; Hojo, Kiichi; Matsubayashi, Nobuyuki*; Imamura, Motoyasu*; Shimada, Hiromichi*

Photon Factory Activity Report 2000, P. 82, 2000/00

no abstracts in English

Journal Articles

Photon-stimulated ion desorption in deuterated formamide adsorbates

Sekiguchi, Hiromi*; Sekiguchi, Tetsuhiro; Imamura, Motoyasu*; Matsubayashi, Nobuyuki*; Shimada, Hiromichi*; Baba, Yuji

Photon Factory Activity Report 1998, Part B, P. 37, 1999/11

no abstracts in English

Oral presentation

Structural characteristics of the active site of $$beta$$-Lactamase TOHO-1 determined by combined high-resolution neutron and X-ray crystallography

Kurihara, Kazuo; Sunami, Tomoko; Yamada, Mitsugu; Nitanai, Yasushi*; Okazaki, Nobuo; Adachi, Motoyasu; Tamada, Taro; Shimamura, Tatsuro*; Miyano, Masashi*; Ishii, Yoshikazu*; et al.

no journal, , 

To help resolve questions regarding the catalytic activity of $$beta$$-lactamase, the crystal structure of an unliganded form of the $$beta$$-lactamase Toho-1 with double mutation R274N/R276N (Toho-1/NN) has been determined by the use of high-resolution neutron and X-ray diffraction data. A large single crystal of Toho-1/NN with a dimension of 2.6 $$times$$ 2.5 $$times$$ 1.3 mm$$^{3}$$ was used to collect 100 K neutron diffraction data to 1.5 ${AA}$ resolution and X-ray diffraction data to 1.4 ${AA}$ resolution. The structural model of Toho-1/NN was refined to an R-factor of 19.7% using a program PHENIX. The structure showed that Glu166, a catalytic residue of Toho-1, was protonated even at pH 7 nonetheless for the close location to the positively charged side chain amino group (-NH3$$_{+}$$) of Lys73. It is also found that there is a hydration water network bridging between the protonated Glu166 and the oxyanion hole comprising two main chain nitrogen atoms of Ser70 and Ser237. The neutron structure analysis also revealed the clear configuration of the proposed catalytic water molecule bridging Glu166 and Ser70. These observations are important to understand the catalytic action of $$beta$$-lactamase Toho-1.

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