Chiera, N. M.*; Sato, Tetsuya; Eichler, R.*; Tomitsuka, Tomohiro; Asai, Masato; Adachi, Sadia*; Dressler, R.*; Hirose, Kentaro; Inoue, Hiroki*; Ito, Yuta; et al.
Angewandte Chemie; International Edition, 60(33), p.17871 - 17874, 2021/08
The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on-line gas phase chromatography technique, in the temperature range 350 - 600 C. Under the exact same chemical conditions, comparative studies with the lighter homologs of group-5 in the Periodic Table clearly indicate the volatility sequence being NbOCl TaOCl DbOCl. From the obtained experimental results, thermochemical data for DbOCl were derived. The present study delivers reliable experimental information for theoretical calculations on the chemical properties of transactinides.
Koyama, Shinichi; Nakagiri, Toshio; Osaka, Masahiko; Yoshida, Hiroyuki; Kurata, Masaki; Ikeuchi, Hirotomo; Maeda, Koji; Sasaki, Shinji; Onishi, Takashi; Takano, Masahide; et al.
Hairo, Osensui Taisaku jigyo jimukyoku Homu Peji (Internet), 144 Pages, 2021/08
JAEA performed the subsidy program for the "Project of Decommissioning and Contaminated Water Management (Development of Analysis and Estimation Technology for Characterization of Fuel Debris (Development of Technologies for Enhanced Analysis Accuracy and Thermal Behavior Estimation of Fuel Debris))" in 2020JFY. This presentation summarized briefly the results of the project, which will be available shortly on the website of Management Office for the Project of Decommissioning and Contaminated Water Management.
Sato, Tomonori; Hata, Kuniki; Kaji, Yoshiyuki; Ueno, Fumiyoshi; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; Abe, Hiroshi*; Akiyama, Eiji*; et al.
JAEA-Review 2021-001, 123 Pages, 2021/06
In the implement of the decommissioning of Fukushima Daiichi Nuclear Power Station (1F), there are many problems to be solved. Specially, the mitigation of the aging degradation by the corrosion of the structural materials is important to implement the decommissioning safely and continuously. However, there are limited data for the environmental factors of corrosion in 1F, and the condition of 1F is continuously changing. So, the literature data for the water radiolysis and the corrosion under irradiation are listed as the database of corrosion under irradiation in this report. And the new obtained radiolysis and corrosion data, which have not been reported in the literature and will be required in the decommissioning of 1F, are reported.
Omori, Atsushi*; Akiyama, Eiji*; Abe, Hiroshi*; Hata, Kuniki; Sato, Tomonori; Kaji, Yoshiyuki; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; et al.
Zairyo To Kankyo, 69(4), p.107 - 111, 2020/04
To evaluate the effect of oxidants, which are formed by radiolysis of water under gamma ray irradiation, on the corrosion of a carbon steel in humid environment, ozone was introduced as a model oxidant in to humidity-controlled air at 50C in a thermo-hygrostat chamber. Corrosion monitoring was performed by using an Atmospheric Corrosion Monitor-type (ACM) sensor consisting of a carbon steel anode and an Ag cathode. The output current of the ACM sensor was increased with the increase in relative humidity and it was obviously increased with the increase in the introduced ozone concentration at each relative humidity. The results indicate that ozone accelerates the corrosion of the carbon steel. The effect of ozone on the corrosion acceleration is attributed to the fast reduction reaction and fast dissolution reaction in to water compared to that of oxygen.
Hata, Kuniki; Inoue, Hiroyuki*
Journal of Nuclear Science and Technology, 56(9-10), p.842 - 850, 2019/09
To investigate the effect of dissolved species from steels on the radiolysis processes of Cl, radiolysis simulations of solutions containing both Cl and Fe were carried out. The results showed that the generation of radiolytic products (HO, O and H) increased mainly by the addition of Fe, and a drop in the pH was caused by the hydrolysis of Fe. This pH drop enhanced the reactivity of Cl with OH, which induced additional generation of HO and O. These results show that low concentrations of Cl (1 10 mol/dm = 35ppm) in the presence of Fe could influence the generation of HO and O during water radiolysis. However, it is considered that these effects of Fe and low concentration of Cl on water radiolysis are less important for corrosion of steels due to the low concentrations of HO and O generated. The other process, such as dissolution of iron enhanced by FeOOH, might predominantly induce corrosion under the conditions of solutions with low concentrations of HO and O.
Saha, P. K.; Harada, Hiroyuki; Kinsho, Michikazu; Miura, Akihiko; Yoshimoto, Masahiro; Okabe, Kota; Suganuma, Kazuaki; Yamane, Isao*; Irie, Yoshiro*; Liu, Y.*; et al.
Proceedings of 15th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.806 - 810, 2018/08
Harada, Hiroyuki; Saha, P. K.; Yoneda, Hitoki*; Michine, Yurina*; Inoue, Shunsuke*; Sato, Atsushi*; Suganuma, Kazuaki; Yamane, Isao*; Kinsho, Michikazu; Irie, Yoshiro*
Proceedings of 15th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.811 - 815, 2018/08
The high-intensity proton accelerator adopts a charge exchange injection scheme, which injects with exchanging from negative Hydrogen ion to proton by using carbon foil. This scheme can realize high intensity proton beam but the uncontrolled beam losses occur by scattering at the foil. Additionally, the beam collision at the foil may cause the break itself. Therefore, a new injection scheme for higher intensity is needed as an alternative to the foil. We newly propose and develop a laser stripping injection scheme. At the first step, we propose a proof-of-principle (POP) experiment of the scheme in J-PARC and develop a laser system. In this presentation, we will introduce the laser stripping injection scheme and describe an overview of a POP experiment. We will report a current status of the laser system.
Hata, Kuniki; Inoue, Hiroyuki*; Kojima, Takao*; Kasahara, Shigeki; Hanawa, Satoshi; Ueno, Fumiyoshi; Tsukada, Takashi; Iwase, Akihiro*
Proceedings of Symposium on Water Chemistry and Corrosion in Nuclear Power Plants in Asia 2017 (AWC 2017) (USB Flash Drive), p.304 - 314, 2017/09
A model simulation of radiolysis of mixed solutions of NaCl and NaBr was carried out. The simulation result agreed well with the experimental result, and Br played an important role in determining the amounts of products from water radiolysis. The simulation result also showed that, in highly pure NaCl solutions, the steady-state concentration of a radolytic product, HO, was mainly controlled by three reactions (Cl + OH ClOH, ClOH Cl + OH, and ClOH + H Cl + HO), which indicated that accurate evaluation of the rate constants of these reactions was very important in improving the radiolysis simulation of solutions containing Cl. An immersion test using a low-alloy steel, SQV2A, in the mixed solutions was also carried out under irradiation. The corrosion rate increased or decreased depending on the pH or the concentrations of the halide ions in a similar way to the change in concentration of HO produced from water radiolysis, which is affected by the presence of Cl and Br. However, at high pH values (12), the corrosion rate was almost zero even though the concentration of HO was high. This could be attributed to enhancement of the passivity of test specimens at higher pH values.
Yukawa, Takuji*; Inoue, Hiroyuki*; Kojima, Takao*; Iwase, Akihiro*; Taniguchi, Naoki; Tachikawa, Hirokazu*
Zairyo To Kankyo 2016 Koenshu (CD-ROM), p.359 - 362, 2016/05
The immersion tests of pure titanium were carried out in aqueous solution containing carbonate/bicarbonate with 50 mM-chloride ion under gamma irradiation. The effect of pH on general corrosion rate of titanium were studied. The experimental results showed that the concentration of hydrogen preoxide was increased with pH, and the corrosion rate increased with the hydrogen preoxide concentration. The corrosion rate in pH12 and 13 were 5 to10 times larger than those under unirradiated conditions.
Hata, Kuniki; Inoue, Hiroyuki*; Kojima, Takao*; Iwase, Akihiro*; Kasahara, Shigeki; Hanawa, Satoshi; Ueno, Fumiyoshi; Tsukada, Takashi
Nuclear Technology, 193(3), p.434 - 443, 2016/03
Hattori, Takanori; Sano, Asami; Arima, Hiroshi*; Komatsu, Kazuki*; Yamada, Akihiro*; Inamura, Yasuhiro; Nakatani, Takeshi; Seto, Yusuke*; Nagai, Takaya*; Utsumi, Wataru; et al.
Nuclear Instruments and Methods in Physics Research A, 780, p.55 - 67, 2015/04
PLANET is a time-of-flight (ToF) neutron beamline dedicated to high-pressure and high-temperature experiments. The large six-axis multi-anvil high-pressure press designed for ToF neutron diffraction experiments enables routine data collection at high pressures and high temperatures up to 10 GPa and 2000 K, respectively. To obtain clean data, the beamline is equipped with the incident slits and receiving collimators to eliminate parasitic scattering from the high-pressure cell assembly. The high performance of the diffractometer for the resolution ( / 0.6%) and the accessible -spacing range (0.2-8.4 ) together with low-parasitic scattering characteristics enables precise structure determination of crystals and liquids under high pressure and temperature conditions.
Umeda, Naotaka; Kashiwagi, Mieko; Taniguchi, Masaki; Tobari, Hiroyuki; Watanabe, Kazuhiro; Dairaku, Masayuki; Yamanaka, Haruhiko; Inoue, Takashi; Kojima, Atsushi; Hanada, Masaya
Review of Scientific Instruments, 85(2), p.02B304_1 - 02B304_3, 2014/02
In order to realize neutral beam systems in ITER whose target is to produce D ion beam of 1 MeV, 200 A/m during 3600s, the electrostatic five-stages negative ion accelerator has been developed at JAEA. To extend pulse length, heat load of the acceleration grids was reduced by controlling the ion beam trajectory. Namely, the beam deflection due to the residual magnetic filter in the accelerator was suppressed with the newly developed extractor with a 0.5 mm off-set aperture displacement. The use of new extractor improved the deflection angle from 6 mrad to 1 mrad, resulting in the reduction of direct interception of negative ions from 23% to 15% of the total acceleration power, respectively. As a result, the pulse length of 130 A/m, 881 keV H ion beam has been successfully extended from a previous value of 0.4s to 8.7s.
Kashiwagi, Mieko; Umeda, Naotaka; Tobari, Hiroyuki; Kojima, Atsushi; Yoshida, Masafumi; Taniguchi, Masaki; Dairaku, Masayuki; Maejima, Tetsuya; Yamanaka, Haruhiko; Watanabe, Kazuhiro; et al.
Review of Scientific Instruments, 85(2), p.02B320_1 - 02B320_3, 2014/02
The negative ion extractor for high power and long-pulse operations is newly developed toward the neutral beam injector (NBI) for heating & current drive of future fusion machines such as ITER, JT-60 Super Advanced (SA) and DEMO reactor. The satisfactory cooling capability is designed in the thermal analysis. A negative ion production and a suppression of electrons are experimentally validated for this new extractor. As the results, the negative ion current shows increases by a factor of 1.3 with suppressing the electron current. The beam divergence angle is also maintained small enough, 4 mrad.
Tobari, Hiroyuki; Inoue, Takashi; Taniguchi, Masaki; Kashiwagi, Mieko; Umeda, Naotaka; Dairaku, Masayuki; Yamanaka, Haruhiko; Watanabe, Kazuhiro; Sakamoto, Keishi; Kuriyama, Masaaki*; et al.
Fusion Engineering and Design, 88(6-8), p.975 - 979, 2013/10
The HV bushing, one of the ITER NB components, which is to be procured by JADA, is a multi-conductor feed through composed of five-stage double-layered insulator columns with large brazed ceramic ring and fiber reinforced plastic (FRP) ring. The HV bushing is a bulk head between insulation gas at 0.6 MPa and vacuum. The FRP ring is required to sustain the pressure load, seismic load and dead weight. Brazing area of the ceramic ring with Kovar is required to maintain vacuum leak tightness and pressure tightness against the air filled at 0.6 MPa. To design the HV bushing satisfying the safety factor of 3.5, mechanical analyses were carried out. As for the FRP ring, it was confirmed that isotropic fiber cloth FRP rings should be used for sufficient strength against shear stress. Also, shape and fixation area of the Kovar sleeve were modified to lower the stress at the joint area. As a result, a design of the insulator for the HV bushing was established satisfying the requirement.
Kojima, Atsushi; Hanada, Masaya; Yoshida, Masafumi; Inoue, Takashi; Watanabe, Kazuhiro; Taniguchi, Masaki; Kashiwagi, Mieko; Umeda, Naotaka; Tobari, Hiroyuki; Grisham, L. R.*; et al.
Fusion Engineering and Design, 88(6-8), p.918 - 921, 2013/10
In this paper, the recent activities are reported toward demonstration of the long pulse production. As for the improvement of uniform beam current profile, a symmetric magnetic field configuration for the source plasma production, a so-called tent-shaped filter, was found to be effective to improve the uniformity of the beam current profile. A similar configuration is applied to the JT-60 negative ion source whose plasma size is 1220 mm 564 mm. An estimation from trajectory calculations of primary electrons with the symmetric magnetic field configuration showed that the primary electrons were distributed uniformly in a longitudinal direction. As for the temperature control of the plasma grid, a prototype of the grid with cooling/heating by circulating a high-temperature fluorinated fluid has been developed. This grid was found to have a capability to control the temperature with a time constant of 10 s by considering the physical properties of the fluid.
Kashiwagi, Mieko; Taniguchi, Masaki; Umeda, Naotaka; Dairaku, Masayuki; Tobari, Hiroyuki; Yamanaka, Haruhiko; Watanabe, Kazuhiro; Inoue, Takashi; DeEsch, H. P. L.*; Grisham, L. R.*; et al.
AIP Conference Proceedings 1515, p.227 - 236, 2013/02
In a five stage multi-aperture multi-grid (MAMuG) accelerator for the ITER neutral beam injector (NBI), 1 MeV, 40 A D ion beam is required for 1 hour. However, beamlets are deflected due to (1) magnetic field for electron suppression and (2) space charge repulsion between beamlets, and consequently, cause excess grid heat load. A three dimensional beam analysis has been carried out to compensate the beamlet deflections. This paper shows that the beamlet deflections due to (1) and (2) are compensated by an aperture offset of only 0.6 mm applied to the aperture of 17 mm in diameter in the extractor and by a metal bar attached around aperture area beneath the extractor, respectively. When the metal bar is increased to 3 mm in thickness and installed 30 mm away from the aperture area, the beamlet is steered gently by the weaker electric field distortion. The beam optics was confirmed not deteriorated by those compensations. The presentation also discusses application of these compensation techniques to the ITER design.
Shibata, Takanori; Terasaki, Ryo*; Kashiwagi, Mieko; Inoue, Takashi; Dairaku, Masayuki; Taniguchi, Masaki; Tobari, Hiroyuki; Umeda, Naotaka; Watanabe, Kazuhiro; Sakamoto, Keishi; et al.
AIP Conference Proceedings 1515, p.177 - 186, 2013/02
In the neutral beam injector in JT-60SA, one of issues is that negative ion beam is partially intercepted at acceleration grids due to a spatial non-uniformity of negative ion production on large extraction area (0.90.45m). Previous experiments showed that fast electrons emitted from filament cathodes are transported in a longitudinal direction by drift and the spatial distribution of electron temperature () strongly relates with the non-uniformity. In this study, a three-dimensional electron transport analysis has been developed. Electron temperature in the analysis agreed well with measurements in JAEA 10A ion source. This study clarified that the bias of distribution are caused by the following reasons; (1) fast electrons drifted in the longitudinal direction survives near the end wall with energy up to = 25-60 eV and (2) they produces thermal electrons by collision with plasma particles there.
Tobari, Hiroyuki; Taniguchi, Masaki; Kashiwagi, Mieko; Dairaku, Masayuki; Umeda, Naotaka; Yamanaka, Haruhiko; Tsuchida, Kazuki; Takemoto, Jumpei; Watanabe, Kazuhiro; Inoue, Takashi; et al.
Plasma Science and Technology, 15(2), p.179 - 183, 2013/02
Vacuum insulation is a common issue for the accelerator and the HV bushing for the ITER NBI. The HV bushing has five-stage structure and each stage consists of double-layered insulators. Hence, several triple points exist around the insulators. To reduce electric field at those points simultaneously, three types of stress ring were developed. In voltage holding test of a full-scale mockup equipped with those stress rings, 120% of rated voltage was sustained and the voltage holding capability required in ITER was verified. In the MeV accelerator, voltage holding capability was not sufficient due to breakdown triggered by electric field concentration at edge and corner on grid components. By extending gap length, 1 MV was sustained in vacuum. Furthermore, with new accelerator grids which compensates beam deflection due to magnetic field and space charge repulsion between beamlets, 980 keV, 185 A/m H ion beam acceleration was demonstrated, which was close to ITER requirement.
Kojima, Atsushi; Hanada, Masaya; Hilmi, A.*; Inoue, Takashi; Watanabe, Kazuhiro; Taniguchi, Masaki; Kashiwagi, Mieko; Umeda, Naotaka; Tobari, Hiroyuki; Kobayashi, Shinichi*; et al.
Review of Scientific Instruments, 83(2), p.02B117_1 - 02B117_5, 2012/02
Production of 500 keV, 3 A beams has been successfully achieved in the JT-60 negative by overcoming the low voltage holding of the accelerator. Toward the design of next ion source, database for the voltage holding capability based on experimental results is required and obtained. As a result, the voltage holding capability was found to vary with 67 N power of -0.15 and with 31.7 S power of -0.125 where N is the aperture number and S is the anode surface area. When N = 1100 and S = 2 m are applied to the design of JT-60SA ion source, the factors C are estimated to be 23 and 29, respectively. Therefore, the influence of the local electric field around the apertures is stronger than that of the surface area.
Taniguchi, Masaki; Kashiwagi, Mieko; Umeda, Naotaka; Dairaku, Masayuki; Takemoto, Jumpei; Tobari, Hiroyuki; Tsuchida, Kazuki; Yamanaka, Haruhiko; Watanabe, Kazuhiro; Kojima, Atsushi; et al.
Review of Scientific Instruments, 83(2), p.02B121_1 - 02B121_3, 2012/02
JAEA has developed the MeV accelerator to demonstrate 1 MeV, 200 A/m H ion beam acceleration required for ITER NBI. A key to realize such a high power accelerator is improvement of voltage holding capability. Based on detailed investigation of the voltage holding characteristics, MeV accelerator was modified to reduce electric field concentration by extending gaps between the grid supports and increasing curvature radiuses at the support corners. After the modifications, accelerator succeeded in sustaining -1 MV in vacuum without beam acceleration. Moreover, beam deflection due to the magnetic field for electron suppression and space charge repulsion was compensated by aperture displacement technique. As the result, beam deflection was compensated and voltage holding during the beam acceleration was improved. Beam parameter of the MeV accelerator was increased to 980 keV, 185 A/m, which is close to the requirement of ITER accelerator.