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Yoshida, Kenta*; Toyama, Takeshi*; Inoue, Koji*; Nagai, Yasuyoshi*; Shimodaira, Masaki
Materia, 62(3), p.154 - 158, 2023/03
no abstracts in English
Chong, Y.*; Gholizadeh, R.*; Tsuru, Tomohito; Zhang, R.*; Inoue, Koji*; Gao, W.*; Godfrey, A.*; Mitsuhara, Masatoshi*; Morris, J. W. Jr.*; Minor, A. M.*; et al.
Nature Communications (Internet), 14, p.404_1 - 404_11, 2023/02
Times Cited Count:1 Percentile:70.95Interstitial oxygen embrittles titanium, particularly at cryogenic temperatures, which necessitates a stringent control of oxygen content in fabricating titanium and its alloys. Here, we propose a structural strategy, via grain refinement, to alleviate this problem. Compared to a coarse-grained counterpart that is extremely brittle at 77K, the uniform elongation of an ultrafine-grained (UFG) microstructure (grain size 2.0
m) in Ti-0.3wt.%O was successfully increased by an order of magnitude, maintaining an ultrahigh yield strength inherent to the UFG microstructure. This unique strength-ductility synergy in UFG Ti-0.3wt.%O was achieved via the combined effects of diluted grain boundary segregation of oxygen that helps to improve the grain boundary cohesive energy and enhanced
dislocation activities that contribute to the excellent strain hardening ability. The present strategy could not only boost the potential applications of high strength Ti-O alloys at low temperatures, but could also be applied to other alloy systems, where interstitial solution hardening results into an undesirable loss of ductility.
Chong, Y.*; Tsuru, Tomohito; Guo, B.*; Gholizadeh, R.*; Inoue, Koji*; Tsuji, Nobuhiro*
Acta Materialia, 240, p.118356_1 - 118356_15, 2022/11
Times Cited Count:5 Percentile:78.21(Materials Science, Multidisciplinary)In this study, we systematically investigated the influences of nitrogen content and grain size on the tensile properties and deformation behaviors of titanium at room temperature. By high-pressure torsion and annealing, we obtained ultrafine-grained (UFG) Ti-0.3wt.%N alloy with a fully recrystallized microstructure, which combined an unprecedented synergy of ultrahigh yield strength (1.04 GPa) and large uniform elongation (10%). The hardening and strain-hardening mechanisms of Ti-0.3wt.%N alloy were comprehensively studied via deformation substructure observation and first-principles calculations. It is revealed that the contributions of nitrogen to the excellent strength/ductility balance in UFG Ti-0.3wt.%N were twofold. On one hand, nitrogen atoms inside the grains strongly impeded the motion of dislocations on prismatic plane due the shuffling of nitrogen from octahedral to hexahedral site, giving rise to a six-fold increase in the friction stress than pure Ti. Moreover, the greatly reduced stacking fault energy difference between prismatic and pyramidal planes in Ti-0.3wt.%N alloy facilitated an easier activation of
dislocations, which contributed to an enhanced strain-hardening rate. On the other hand, some nitrogen atoms segregated near the grain boundaries, a phenomenon discovered in
-titanium for the first time. These segregated nitrogen atoms served as an additional contributor to the yield strength of UFG Ti-0.3wt.%N, by raising the barrier against dislocation slip transfer between grains. Our experimental and theoretical calculation work provide insights for the design of affordable high strength titanium without a large sacrifice of ductility, shedding lights on a more widespread use of this high strength to weight material.
Chen, J.*; Yoshida, Kenta*; Suzudo, Tomoaki; Shimada, Yusuke*; Inoue, Koji*; Konno, Toyohiko*; Nagai, Yasuyoshi*
Materials Transactions, 63(4), p.468 - 474, 2022/04
Times Cited Count:1 Percentile:26.88(Materials Science, Multidisciplinary)In situ electron irradiation using high-resolution transmission electron microscopy (HRTEM) was performed to visualize the Frank loop evolution in aluminium-copper (Al-Cu) alloy with an atomic-scale spatial resolution of 0.12 nm. The HRTEM observation along the [110] direction of the FCC-Al lattice, Frank partial dislocation bounding an intrinsic stacking fault exhibited an asymmetrical climb along the
112
direction opposed to those in the reference pure Al under an electron irradiation, with a corresponding displacement-per-atom rate of 0.055-0.120 dpa/s. The asymmetrical climb of the partial dislocation was described as pinning effects due to Cu-Cu bonding in Guinier-Preston zones by a molecular dynamics simulation.
Koyama, Shinichi; Nakagiri, Toshio; Osaka, Masahiko; Yoshida, Hiroyuki; Kurata, Masaki; Ikeuchi, Hirotomo; Maeda, Koji; Sasaki, Shinji; Onishi, Takashi; Takano, Masahide; et al.
Hairo, Osensui Taisaku jigyo jimukyoku Homu Peji (Internet), 144 Pages, 2021/08
JAEA performed the subsidy program for the "Project of Decommissioning and Contaminated Water Management (Development of Analysis and Estimation Technology for Characterization of Fuel Debris (Development of Technologies for Enhanced Analysis Accuracy and Thermal Behavior Estimation of Fuel Debris))" in 2020JFY. This presentation summarized briefly the results of the project, which will be available shortly on the website of Management Office for the Project of Decommissioning and Contaminated Water Management.
Sekine, Megumi; Sukegawa, Hidetoshi; Ishikuro, Yasuhiro; Oyama, Koji; Obata, Takashi; Hayashi, Kazuhiko; Inoue, Naoko
Proceedings of INMM & ESARDA Joint Virtual Annual Meeting (Internet), 10 Pages, 2021/08
The Integrated Support Center for Nuclear Nonproliferation and Nuclear Security (ISCN) of the Japan Atomic Energy Agency (JAEA) developed the virtual tour of a reference nuclear facility. The developed virtual tour was applied to the Design Information Questionnaire (DIQ) workshop exercise for the online SSAC course held in November 2020 in connection with the IAEA safeguards-related regional training course. Also, it was applied to the Complementary Access (CA) exercise for the online workshop of the Nuclear Security and Safeguards Project under the Forum for Nuclear Cooperation in Asia (FNCA), held in February 2021. The workshop exercises have been implemented for in-person format however due to COVID-19 pandemic, a virtual tour was applied. The virtual tour was found to be a strong tool not only for online training as an alternative for a facility tour, but also considered to be more advantageous even for the in-person training. The developed virtual tour of a reference nuclear facility, going to shut down, can find potentially varied applications. The paper describes how to create a virtual tour of a reference research reactor facility for the DIQ and CA exercises respectively which have different learning objectives. It emphasizes how the features of the reference facility were captured and the challenges encountered to convey to the training participants the importance of providing the required design information while not being physically present at the facility. It also show the advantage of using the same virtual tour to describe the safeguards-related verification activities of a complementary access. Virtual tours can be applied to a variety of training.
Zhao, C.*; Suzudo, Tomoaki; Toyama, Takeshi*; Nishitani, Shigeto*; Inoue, Koji*; Nagai, Yasuyoshi*
Materials Transactions, 62(7), p.929 - 934, 2021/07
Times Cited Count:2 Percentile:21.22(Materials Science, Multidisciplinary)We succeeded in measuring the diffusion coefficient of Cu in Fe in a low temperature range that had not been measured so far. Since the diffusion couple, which is a general method for measuring the diffusion coefficient, can be applied only at high temperature, atom probe tomography and Cu precipitation rate theory were used in this study. The estimated diffusion coefficient was found to be more reliable than that obtained in previous studies. Therefore, it is considered that the estimation by the atom probe provided higher accuracy. Furthermore, the kinetic Monte Carlo simulation revealed that the diffusion coefficient estimated by this method tends to be slightly overestimated as the temperature decreases.
Oto, Tsutomu; Asano, Norikazu; Kawamata, Takanori; Yanai, Tomohiro; Nishimura, Arashi; Araki, Daisuke; Otsuka, Kaoru; Takabe, Yugo; Otsuka, Noriaki; Kojima, Keidai; et al.
JAEA-Review 2020-018, 66 Pages, 2020/11
A collapse event of the cooling tower of secondary cooling system in the JMTR (Japan Materials Testing Reactor) was caused by the strong wind of Typhoon No.15 on September 9, 2019. The cause of the collapse of the cooling tower was investigated and analyzed. As the result, it was identified that four causes occurred in combination. Thus, the soundness of the cooling tower of Utility Cooling Loop (UCL cooling tower), which is a wooden cooling tower installed at the same period as the cooling tower of secondary cooling system, was investigated. The items of soundness survey are to grasp the operation conditions of the UCL cooling tower, to confirm the degradation of structural materials, the inspection items and inspection status of the UCL cooling tower, and to investigate the past meteorological data. As the results of soundness survey of the UCL cooling tower, the improvement of inspection items of the UCL cooling tower was carried out and the replacement and repair of the structural materials of the UCL cooling tower were planned for safe maintenance and management of this facility. And the renewal plan of new cooling tower was created to replace the existing UCL cooling tower. This report is summarized the soundness survey of the UCL cooling tower.
Komura, Keitaro*; Kaneda, Heitaro*; Tanaka, Tomoki*; Kojima, Satoru*; Inoue, Tsutomu*; Nishio, Tomohiro
Geomorphology, 365, p.107214_1 - 107214_22, 2020/09
Times Cited Count:1 Percentile:11.12(Geography, Physical)On the basis of pit excavations and sediment cores at an off-fault deep-seated gravitational slope deformation (DGSD) site and a trench excavation across the active Neodani fault at a nearby site, we examined the records of DGSD and surface-rupturing paleoearthquakes of the Neodani fault. We found the four most recent DGSD events and the four most recent surface-rupturing earthquakes, respectively and conclude that the ages of events are overlapped each other. We infer that static crustal strain from repeated seismogenic faulting plays an important role in the occurrence of DGSD events, at least in the immediate vicinity of active faults, although coseismic severe shaking would have at least some effect on them. Our case study suggests that off-fault DGSDs can be used to reconstruct or refine the paleoseismic history of a nearby active fault.
Du, Y.*; Yoshida, Kenta*; Shimada, Yusuke*; Toyama, Takeshi*; Inoue, Koji*; Arakawa, Kazuto*; Suzudo, Tomoaki; Milan, K. J.*; Gerard, R.*; Onuki, Somei*; et al.
Materialia, 12, p.100778_1 - 100778_10, 2020/08
In order to ensure the integrity of the reactor pressure vessel in the long term, it is necessary to understand the effects of irradiation on the materials. In this study, irradiation-induced dislocation loops were observed in neutron-irradiated reactor pressure vessel specimens during annealing using our newly developed WB-STEM. It was confirmed that the proportion of loops increased with increasing annealing temperature. We also succeeded in observing the phenomenon that two
loops collide into a
loop. Moreover, a phenomenon in which dislocation loops decorate dislocations was also observed, and the mechanism was successfully explained by molecular dynamics simulation.
Yoshida, Koji*; Inoue, Takuya*; Torigoe, Motokatsu*; Yamada, Takeshi*; Shibata, Kaoru; Yamaguchi, Toshio*
Journal of Chemical Physics, 149(12), p.124502_1 - 124502_10, 2018/09
Times Cited Count:3 Percentile:13.55(Chemistry, Physical)Differential scanning calorimetry, X-ray diffraction, and quasi-elastic neutron scattering (QENS) measurements of aqueous glycine solutions confined in mesoporous silica (MCM-41) were performed at different glycine concentrations, pH, and loading ratio (= mass of glycine solution / mass of dry MCM-41) in the temperature range from 305 to 180 K to discuss the confinement effect on the thermal behavior, the structure, and the dynamic properties of the solutions.
Inoue, Rintaro*; Kanaya, Toshiji*; Yamada, Takeshi*; Shibata, Kaoru; Fukao, Koji*
Physical Review E, 97(1), p.012501_1 - 012501_6, 2018/01
Times Cited Count:9 Percentile:64.63(Physics, Fluids & Plasmas)In this study, we investigate the process of a polystyrene thin film using inelastic neutron scattering (INS), dielectric relaxation spectroscopy (DRS), and thermal expansion spectroscopy (TES). The DRS and TES measurements exhibited a decrease in glass transition temperature (
) with film thickness. On the other hand, an increase in
was observed in INS studies. In order to interpret this contradiction, we investigated the temperature dependence of the peak frequency (
) of the
process probed by DRS and TES. The experiments revealed an increase in the peak frequency (
) with decreasing film thickness in the frequency region. This observation is consistent with the observed decrease in
with thickness. The discrepancy between INS and DRS or TES descriptions of the
process is likely to be attributed to a decrease in the apparent activation energy with film thickness and reduced mobility, due to the impenetrable wall effect.
Hata, Kuniki; Inoue, Hiroyuki*; Kojima, Takao*; Kasahara, Shigeki; Hanawa, Satoshi; Ueno, Fumiyoshi; Tsukada, Takashi; Iwase, Akihiro*
Proceedings of Symposium on Water Chemistry and Corrosion in Nuclear Power Plants in Asia 2017 (AWC 2017) (USB Flash Drive), p.304 - 314, 2017/09
A model simulation of radiolysis of mixed solutions of NaCl and NaBr was carried out. The simulation result agreed well with the experimental result, and Br
played an important role in determining the amounts of products from water radiolysis. The simulation result also showed that, in highly pure NaCl solutions, the steady-state concentration of a radolytic product, H
O
, was mainly controlled by three reactions (Cl
+
OH
ClOH
, ClOH
Cl
+
OH, and ClOH
+ H
Cl
+ H
O), which indicated that accurate evaluation of the rate constants of these reactions was very important in improving the radiolysis simulation of solutions containing Cl
. An immersion test using a low-alloy steel, SQV2A, in the mixed solutions was also carried out under irradiation. The corrosion rate increased or decreased depending on the pH or the concentrations of the halide ions in a similar way to the change in concentration of H
O
produced from water radiolysis, which is affected by the presence of Cl
and Br
. However, at high pH values (
12), the corrosion rate was almost zero even though the concentration of H
O
was high. This could be attributed to enhancement of the passivity of test specimens at higher pH values.
Takamizawa, Hisashi; Shimizu, Yasuo*; Inoue, Koji*; Nozawa, Yasuko*; Toyama, Takeshi*; Yano, Fumiko*; Inoue, Masao*; Nishida, Akio*; Nagai, Yasuyoshi*
Applied Physics Express, 9(10), p.106601_1 - 106601_4, 2016/10
Times Cited Count:0 Percentile:0(Physics, Applied)Yukawa, Takuji*; Inoue, Hiroyuki*; Kojima, Takao*; Iwase, Akihiro*; Taniguchi, Naoki; Tachikawa, Hirokazu*
Zairyo To Kankyo 2016 Koenshu (CD-ROM), p.359 - 362, 2016/05
The immersion tests of pure titanium were carried out in aqueous solution containing carbonate/bicarbonate with 50 mM-chloride ion under gamma irradiation. The effect of pH on general corrosion rate of titanium were studied. The experimental results showed that the concentration of hydrogen preoxide was increased with pH, and the corrosion rate increased with the hydrogen preoxide concentration. The corrosion rate in pH12 and 13 were 5 to10 times larger than those under unirradiated conditions.
Hata, Kuniki; Inoue, Hiroyuki*; Kojima, Takao*; Iwase, Akihiro*; Kasahara, Shigeki; Hanawa, Satoshi; Ueno, Fumiyoshi; Tsukada, Takashi
Nuclear Technology, 193(3), p.434 - 443, 2016/03
Times Cited Count:12 Percentile:76.04(Nuclear Science & Technology)Yatsuka, Eiichi; Hatae, Takaki; Suito, Satoshi*; Ohara, Miyuki*; Hagita, Koji*; Inoue, Kazunori*; Bassan, M.*; Walsh, M.*; Itami, Kiyoshi
Journal of Instrumentation (Internet), 11(1), p.C01006_1 - C01006_12, 2016/01
Times Cited Count:6 Percentile:32.03(Instruments & Instrumentation)Sekio, Yoshihiro; Yamagata, Ichiro; Yamashita, Shinichiro; Inoue, Masaki; Maeda, Koji
Proceedings of 2014 Nuclear Plant Chemistry Conference (NPC 2014) (USB Flash Drive), 10 Pages, 2014/10
In the Fukushima Dai-ichi Nuclear Power Plant accident, seawater was temporarily injected into the spent fuel pools since water cooling and feeding functions were lost. For fuel assemblies which experienced seawater immersion, surface corrosion due to seawater constituents and the resultant degradation of mechanical property are of concern. Therefore, in order to assess the integrity of fuel assemblies (especially cladding tubes), the effects of seawater immersion on corrosion behavior and mechanical properties for as-recieved and irradiated Zircaloy-2 cladding tubes were investigated in the present study. As a result, no obvious surface corrosion and no significant degradation in the tensile strength property were observed after both artificial and natural seawater immersion tests for both steels. This suggests that the effects of seawater immersions on corrosion behavior and mechanical property (especially tensile property) for Zircaloy-2 cladding tubes are probably negligible.
Umeda, Naotaka; Kashiwagi, Mieko; Taniguchi, Masaki; Tobari, Hiroyuki; Watanabe, Kazuhiro; Dairaku, Masayuki; Yamanaka, Haruhiko; Inoue, Takashi; Kojima, Atsushi; Hanada, Masaya
Review of Scientific Instruments, 85(2), p.02B304_1 - 02B304_3, 2014/02
Times Cited Count:12 Percentile:49.3(Instruments & Instrumentation)In order to realize neutral beam systems in ITER whose target is to produce D ion beam of 1 MeV, 200 A/m
during 3600s, the electrostatic five-stages negative ion accelerator has been developed at JAEA. To extend pulse length, heat load of the acceleration grids was reduced by controlling the ion beam trajectory. Namely, the beam deflection due to the residual magnetic filter in the accelerator was suppressed with the newly developed extractor with a 0.5 mm off-set aperture displacement. The use of new extractor improved the deflection angle from 6 mrad to 1 mrad, resulting in the reduction of direct interception of negative ions from 23% to 15% of the total acceleration power, respectively. As a result, the pulse length of 130 A/m
, 881 keV H
ion beam has been successfully extended from a previous value of 0.4s to 8.7s.
Kashiwagi, Mieko; Umeda, Naotaka; Tobari, Hiroyuki; Kojima, Atsushi; Yoshida, Masafumi; Taniguchi, Masaki; Dairaku, Masayuki; Maejima, Tetsuya; Yamanaka, Haruhiko; Watanabe, Kazuhiro; et al.
Review of Scientific Instruments, 85(2), p.02B320_1 - 02B320_3, 2014/02
Times Cited Count:28 Percentile:75.12(Instruments & Instrumentation)The negative ion extractor for high power and long-pulse operations is newly developed toward the neutral beam injector (NBI) for heating & current drive of future fusion machines such as ITER, JT-60 Super Advanced (SA) and DEMO reactor. The satisfactory cooling capability is designed in the thermal analysis. A negative ion production and a suppression of electrons are experimentally validated for this new extractor. As the results, the negative ion current shows increases by a factor of 1.3 with suppressing the electron current. The beam divergence angle is also maintained small enough, 4 mrad.