Investigation of hydrogen superoxide adsorption during ORR on Pt/C catalyst in acidic solution for PEFC by high energy resolution XAFS

Yamamoto, Naoki*; Matsumura, Daiju; Hagihara, Yuto*; Tanaka, Kei*; Hasegawa, Yuta*; Ishii, Kenji*; Tanaka, Hirohisa*

Journal of Power Sources, 557, p.232508_1 - 232508_10, 2023/02

https://doi.org/10.1016/j.jpowsour.2022.232508

Feasibility study of magnetic-domain observation by means of non-resonant magnetic X-ray diffraction

Inami, Toshiya*; Shobu, Takahisa; Ishii, Kenji*

IEEE Transactions on Magnetics, 57(3, Part2), p.6400105_1 - 6400105_5, 2021/03

https://doi.org/10.1109/TMAG.2020.3046006

Synthesis report on the R&D for the Horonobe Underground Research Laboratory; Project carried out during fiscal years 2015-2019

Nakayama, Masashi; Saiga, Atsushi; Kimura, Shun; Mochizuki, Akihito; Aoyagi, Kazuhei; Ono, Hirokazu; Miyakawa, Kazuya; Takeda, Masaki; Hayano, Akira; Matsuoka, Toshiyuki; et al.

JAEA-Research 2019-013, 276 Pages, 2020/03

JAEA-Research-2019-013.pdf:18.72MB

The Horonobe Underground Research Laboratory (URL) Project is being pursued by the Japan Atomic Energy Agency (JAEA) to enhance the reliability of relevant disposal technologies for geological disposal of High-level Radioactive Waste through investigations of the deep geological environment within the host sedimentary rock at Horonobe Town in Hokkaido, north Japan. The investigations will be conducted in three phases, namely "Phase 1: Surface based investigations", "Phase 2: Construction phase" (investigations during construction of the underground facilities) and "Phase 3: Operation phase" (research in the underground facilities). According to the research plan described in the 3rd Mid- and Long- term Plan of JAEA, "Near-field performance study", "Demonstration of repository design option", and "Verification of crustal-movement buffering capacity of sedimentary rocks" are important issues of the Horonobe URL Project, and schedule of future research and backfill plans of the project will be decided by the end of 2019 Fiscal Year. The present report summarizes the research and development activities of these 3 important issues carried out during 3rd Medium to Long-term Research Phase.

Numerical evaluation on fluctuation absorption characteristics based on nuclear heat supply fluctuation test using HTTR

Takada, Shoji; Honda, Yuki*; Inaba, Yoshitomo; Sekita, Kenji; Nemoto, Takahiro; Tochio, Daisuke; Ishii, Toshiaki; Sato, Hiroyuki; Nakagawa, Shigeaki; Sawa, Kazuhiro*

Proceedings of 9th International Topical Meeting on High Temperature Reactor Technology (HTR 2018) (USB Flash Drive), 7 Pages, 2018/10

Nuclear heat utilization systems connected to HTGRs will be designed on the basis of non-nuclear grade standards for easy entry of chemical plant companies, requiring reactor operations to continue even if abnormal events occur in the systems. The inventory control is considered as one of candidate methods to control reactor power for load following operation for siting close to demand area, in which the primary gas pressure is varied while keeping the reactor inlet and outlet coolant temperatures constant. Numerical investigation was carried out based on the results of nuclear heat supply fluctuation tests using HTTR by non-nuclear heating operation to focus on the temperature transient of the reactor core bottom structure by imposing stepwise fluctuation on the reactor inlet temperature under different primary gas pressures below 120C. As a result, it was emerged that the fluctuation absorption characteristics are not deteriorated by lowering pressure. It was also emerged that the reactor outlet temperature did not reach the scram level by increasing the reactor inlet temperature 10 C stepwise at 80% of the rated power as same with the full power case.

Effect of water for the oxygen adsorption on surface of PtCo catalysts

Cui, Y.-T.*; Harada, Yoshihisa*; Niwa, Hideharu*; Oshima, Masaharu*; Hatanaka, Tatsuya*; Nakamura, Naoki*; Ando, Masaki*; Yoshida, Toshihiko*; Ishii, Kenji*; Matsumura, Daiju

NanotechJapan Bulletin (Internet), 11(4), 6 Pages, 2018/08

no abstracts in English

Observation of momentum-dependent charge excitations in hole-doped cuprates using resonant inelastic X-ray scattering at the oxygen edge

Ishii, Kenji*; Toyama, Takami*; Asano, Shun*; Sato, Kentaro*; Fujita, Masaki*; Wakimoto, Shuichi; Tsutsui, Kenji*; Sota, Shigetoshi*; Miyawaki, Jun*; Niwa, Hideharu*; et al.

Physical Review B, 96(11), p.115148_1 - 115148_8, 2017/09

AA2017-0402.pdf:0.81MB

https://doi.org/10.1103/PhysRevB.96.115148

Absence of a polar phase in perovskite chromite CrO (=La and Pr)

Yoshii, Kenji; Ikeda, Naoshi*; Shimojo, Yutaka; Ishii, Yoshinobu*

Materials Chemistry and Physics, 190, p.96 - 101, 2017/04

https://doi.org/10.1016/j.matchemphys.2016.12.074

Magnetic and dielectric properties have been studied for LaCrO, PrCrO, and their solid solution LaPrCrO, belonging to a family of ferroelectricorthochromite series CrO (: rare earths). The magnetic measurements confirm that the material shows canted antiferromagnetic ordering at 240-288 K. Neutron diffraction patterns could be fitted with the centrosymmetric , which is different from the non-centrosymmetric structure proposed for the ferroelectric phase of NdCrO. The large dielectric constants are likely due to the hopping of charge carriers as proposed previously for other chromites.

Electronic structure of Pt and Pt-Co nanoparticles with O and O/HO adsorption revealed by in situ XAFS and hard X-ray photoelectron spectroscopy

Cui, Y.*; Harada, Yoshihisa*; Hatanaka, Tatsuya*; Nakamura, Naoki*; Ando, Masaki*; Yoshida, Toshihiko*; Ikenaga, Eiji*; Ishii, Kenji*; Matsumura, Daiju; Li, R.*; et al.

ECS Transactions, 72(8), p.131 - 136, 2016/10

https://doi.org/10.1149/07208.0131ecst

Observation of momentum-resolved charge fluctuations proximate to the charge-order phase using resonant inelastic X-ray scattering

Yoshida, Masahiro*; Ishii, Kenji; Naka, Makoto*; Ishihara, Sumio*; Jarrige, I.*; Ikeuchi, Kazuhiko*; Murakami, Yoichi*; Kudo, Kazutaka*; Koike, Yoji*; Nagata, Tomoko*; et al.

Scientific Reports (Internet), 6, p.23611_1 - 23611_8, 2016/03

https://doi.org/10.1038/srep23611

Clay-based modeling approach to diffusion and sorption in the argillaceous rock from the Horonobe URL; Application to Ni(II), Am(III), and Se(IV)

Tachi, Yukio; Suyama, Tadahiro; Yotsuji, Kenji; Ishii, Yasuo; Takahashi, Hiroaki*

CMS Workshop Lectures, Vol.21, p.241 - 250, 2016/00

https://www.clays.org/other-cms-publications-wrksh21/

Sorption and diffusion of radionuclides in argillaceous rocks are key processes in the safe geological disposal. The diffusion and sorption behavior of Ni(II), Am(III) and Se(IV) in mudstone from the Horonobe URL were investigated by experimental and modeling approaches. Effective diffusivities obtained by the through-diffusion experiments were in the sequence of Cs, Ni, HTO, I, Se(SeO), Am(Am(CO)) by comparison with the previous study. The distribution coefficient values were consistent with those obtained by batch sorption tests. These results were interpreted by the clay-based modeling approach coupling the thermodynamic sorption model assuming key contributions of clays (smectite and illite) and the diffusion model assuming the electrical double layer theory and the simplified pore model with size distribution. This clay-based model could provide reasonable account of observed trends and could be basically applicable for various radionuclides.