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Journal Articles

Protonic conduction, crystal and electronic structures of La$$_{0.9}$$Ba$$_{1.1}$$Ga$$_{0.95}$$Mg$$_{0.05}$$O$$_{4-delta}$$

Hamao, Naoki*; Kitamura, Naoto*; Ito, Takanori*; Igawa, Naoki; Idemoto, Yasushi*; Daido, Hiroyuki; Kaku, Masanori*; Kubodera, Masakazu*

Solid State Ionics, 253, p.123 - 129, 2013/12

 Times Cited Count:3 Percentile:15.44(Chemistry, Physical)

La$$_{0.9}$$Ba$$_{1.1}$$Ga$$_{0.95}$$Mg$$_{0.05}$$O$$_{4-delta}$$ which is one of the candidates for solid electrolyte of solid oxide fuel cell was synthesized by means of a conventional solid-state reaction, and investigated by conductivity measurements, the Rietveld and maximum entropy method analyses using neutron and synchrotron X-ray diffraction data. Conductivity measurements indicated that simultaneous Ba and Mg substitutions for LaBaGaO$$_{4}$$ were effective way to improve the protonic conductivity. From the Rietveld and maximum entropy method analyses, it was confirmed that La$$_{0.9}$$Ba$$_{1.1}$$Ga$$_{0.95}$$Mg$$_{0.05}$$O$$_{4-delta}$$ kept the same crystal structure as LaBaGaO$$_{4}$$ even at elevated temperature, i.e. 1000 K, and that protons existed around the O3 site and formed hydrogen bonds. It is also found that oxygens in LaBaGaO$$_{4}$$-based samples formed Ga-O$$_{4}$$ tetrahedra, and the bonding strength was varied by the partial substitutions.

Journal Articles

Demonstration of partially transparent thick metallic sodium in the vacuum ultraviolet spectral range

Daido, Hiroyuki; Suzuki, Yoji; Kawachi, Tetsuya; Fukuda, Takeshi*; Nakagiri, Toshio; Kaku, Masanori*; Kubodera, Masakazu*

Optics Express (Internet), 21(23), p.28182 - 28188, 2013/11

 Times Cited Count:1 Percentile:7.09(Optics)

We describe the direct measurement of actual transmittance of sodium samples with thickness of a 2 mm and 3 mm in a spectral range $$>$$115 nm, resulting in $$>$$50% transmittance of 3 mm thick solid and liquid sodium samples including transmission of a pair of the windows at the wavelength of 120 nm, giving an extinction coefficient of $$sim$$10$$^{-6}$$ to $$sim$$10$$^{-7}$$ which represents the sodium with a few cm thickness to be partially transparent for this wavelength. To confirm the measurement, we perform simple imaging experiments by the ultra-violet light passing through a 8 mm-thick sodium sample to illuminate a mesh as an object, resulting in obtaining a clear image.

Journal Articles

Transmission imaging of sodium in the vacuum ultra-violet spectral range; New application for an intense VUV Source

Daido, Hiroyuki; Suzuki, Yoji; Kawachi, Tetsuya; Fukuda, Takeshi*; Nakagiri, Toshio; Kaku, Masanori*; Kubodera, Masakazu*; Pirozhkov, A. S.

Proceedings of SPIE, Vol.8849, p.884908_1 - 884908_11, 2013/09

no abstracts in English

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