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Ba
Ga
Mg
O
Hamao, Naoki*; Kitamura, Naoto*; Ito, Takanori*; Igawa, Naoki; Idemoto, Yasushi*; Daido, Hiroyuki; Kaku, Masanori*; Kubodera, Masakazu*
Solid State Ionics, 253, p.123 - 129, 2013/12
Times Cited Count:3 Percentile:13.76(Chemistry, Physical)La
Ba
Ga
Mg
O
which is one of the candidates for solid electrolyte of solid oxide fuel cell was synthesized by means of a conventional solid-state reaction, and investigated by conductivity measurements, the Rietveld and maximum entropy method analyses using neutron and synchrotron X-ray diffraction data. Conductivity measurements indicated that simultaneous Ba and Mg substitutions for LaBaGaO
were effective way to improve the protonic conductivity. From the Rietveld and maximum entropy method analyses, it was confirmed that La
Ba
Ga
Mg
O
kept the same crystal structure as LaBaGaO
even at elevated temperature, i.e. 1000 K, and that protons existed around the O3 site and formed hydrogen bonds. It is also found that oxygens in LaBaGaO
-based samples formed Ga-O
tetrahedra, and the bonding strength was varied by the partial substitutions.
Daido, Hiroyuki; Suzuki, Yoji; Kawachi, Tetsuya; Fukuda, Takeshi*; Nakagiri, Toshio; Kaku, Masanori*; Kubodera, Masakazu*
Optics Express (Internet), 21(23), p.28182 - 28188, 2013/11
Times Cited Count:2 Percentile:12.16(Optics)We describe the direct measurement of actual transmittance of sodium samples with thickness of a 2 mm and 3 mm in a spectral range
115 nm, resulting in
50% transmittance of 3 mm thick solid and liquid sodium samples including transmission of a pair of the windows at the wavelength of 120 nm, giving an extinction coefficient of
10
to
10
which represents the sodium with a few cm thickness to be partially transparent for this wavelength. To confirm the measurement, we perform simple imaging experiments by the ultra-violet light passing through a 8 mm-thick sodium sample to illuminate a mesh as an object, resulting in obtaining a clear image.
Daido, Hiroyuki; Suzuki, Yoji; Kawachi, Tetsuya; Fukuda, Takeshi*; Nakagiri, Toshio; Kaku, Masanori*; Kubodera, Masakazu*; Pirozhkov, A. S.
Proceedings of SPIE, Vol.8849, p.884908_1 - 884908_11, 2013/09
no abstracts in English