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Journal Articles

Nature of structural instabilities in superconducting Sr$$_3$$Ir$$_4$$Sn$$_{13}$$

Kaneko, Koji; Cheung, Y. W.*; Hu, Y.*; Imai, Masaki*; Tanioku, Yasuaki*; Kanagawa, Hibiki*; Murakawa, Joichi*; Moriyama, Kodai*; Zhang, W.*; Lai, K. T.*; et al.

JPS Conference Proceedings (Internet), 30, p.011032_1 - 011032_6, 2020/03

Journal Articles

Zr separation from high-level liquid waste with a novel hydroxyacetoamide type extractant

Morita, Keisuke; Suzuki, Hideya; Matsumura, Tatsuro; Takahashi, Yuya*; Omori, Takashi*; Kaneko, Masaaki*; Asano, Kazuhito*

Proceedings of International Nuclear Fuel Cycle Conference / Light Water Reactor Fuel Performance Conference (Global/Top Fuel 2019) (USB Flash Drive), p.464 - 468, 2019/09

High level liquid waste (HLLW) contains several radionuclides with half-lives longer than 10$$^{6}$$ year. For reduce environmental burden of waste disposal, minor actinoids and long-lived fission products will to be partitioned and transmuted. JAEA and Toshiba developed process for recovering Se, Zr, Pd and Cs from HLLW. Solvent extraction for Zr with novel extractant, ${it N,N}$-didodecyl-2-hydroxyacetoamide (HAA) was detailed. The HAA system showed high selectivity for Zr, as indicated by the extraction order of Zr $$>$$ Mo $$>$$ Pd $$>$$ Ag $$approx$$ Sb $$>$$ Sn $$>$$ Lns $$>$$ Fe. The extracted species was determined as Zr(HAA)$$_{3}$$(NO$$_{3}$$)$$_{4}$$(HNO$$_{3}$$)$$_{x}$$. A continuous countercurrent extraction with HAA was applied to a simulated, concentrated HLLW after Pd, Se, and Cs removal, where the quantitative extraction of Zr and Mo was effectively demonstrated.

Journal Articles

Unique helical magnetic order and field-induced phase in trillium lattice antiferromagnet EuPtSi

Kaneko, Koji; Frontzek, M. D.*; Matsuda, Masaaki*; Nakao, Akiko*; Munakata, Koji*; Ohara, Takashi; Kakihana, Masashi*; Haga, Yoshinori; Hedo, Masato*; Nakama, Takao*; et al.

Journal of the Physical Society of Japan, 88, p.013702_1 - 013702_5, 2019/01

 Times Cited Count:60 Percentile:95.02(Physics, Multidisciplinary)

Journal Articles

Reduction and resource recycling of high-level radioactive wastes through nuclear transmutation; Isolation techniques of Pd, Zr, Se and Cs in simulated high level radioactive waste using solvent extraction

Sasaki, Yuji; Morita, Keisuke; Ito, Keisuke; Suzuki, Shinichi; Shiwaku, Hideaki; Takahashi, Yuya*; Kaneko, Masaaki*; Omori, Takashi*; Asano, Kazuhito*

Proceedings of International Nuclear Fuel Cycle Conference (GLOBAL 2017) (USB Flash Drive), 4 Pages, 2017/09

no abstracts in English

Journal Articles

Extraction and separation of Se, Zr, Pd, and Cs including long-lived radionuclides

Sasaki, Yuji; Morita, Keisuke; Suzuki, Shinichi; Shiwaku, Hideaki; Ito, Keisuke; Takahashi, Yuya*; Kaneko, Masaaki*

Solvent Extraction Research and Development, Japan, 24(2), p.113 - 122, 2017/06

The solvent extraction of Se, Zr, Pd, and Cs from nitric acid into 1-octanol (OC) and dodecane has been performed. These elements include long-lived radionuclides in spent nuclear fuels, so a simple separation method is indispensable for the development of the treatment of high-level liquid radioactive waste. It was found that Se can be extracted using phenylenediamine, Zr can be extracted using tetraoctyl diglycolamide and di-2-ethylhexyl phosphoric acid, and Pd can be extracted using (methylimino)bis(dioctylacetamide) and hexaoctylnitrilotriacetamide. These elements can be recovered in over 90% yield by these extractants from nitric acid into OC. A distribution ratio of Cs of greater than 1 can be obtained using di-t-butyldibenzo-18-crown-6. It is clear that 90% recovery of Cs can be achieved using an extraction solvent with ten times the volume of the aqueous phase.

Journal Articles

U-RANS simulation of elbow flow with a 1/7 scale experimental loop simulating JSFR cold-leg piping

Yamano, Hidemasa; Kaneko, Tetsuya*; Aizawa, Kosuke; Tanaka, Masaaki; Ebara, Shinji*; Hashizume, Hidetoshi*

Proceedings of 9th Korea-Japan Symposium on Nuclear Thermal Hydraulics and Safety (NTHAS-9) (CD-ROM), 10 Pages, 2014/11

In this study, Unsteady Reynolds Averaged Navier-Stokes equations (U-RANS) approach with the Reynolds Stress Model using a commercial computational fluid dynamics code has been applied to the flow through single and double short-elbows under a high Reynolds number condition (1.0$$times$$10$$^{6}$$). This numerical simulation has utilized a 1/7 scaled water experiment simulating the JSFR cold-leg piping in order to investigate the flow pattern in a three-dimensionally connected double elbow. As a result, validity and applicability of the U-RANS numerical simulation method were confirmed by comparison between the numerical and experimental results. The simulation has also shown that unsteady flow fields including vortex structures in the 1st elbow were very different from that in the 2nd elbow. This is because horseshoe vortexes generated in the 1st elbow downstream enter sideways the 2nd elbow. In addition, the simulation has indicated that the influence of distance between two elbows in the double elbow flow addressed in this paper was small.

Journal Articles

Influence of electron doping on magnetic order in CeRu$$_2$$Al$$_{10}$$

Kobayashi, Riki*; Kaneko, Koji; Saito, Kotaro*; Mignot, J.-M.*; Andr$'e$, G.*; Robert, J.*; Wakimoto, Shuichi; Matsuda, Masaaki*; Chi, S.*; Haga, Yoshinori; et al.

Journal of the Physical Society of Japan, 83(10), p.104707_1 - 104707_5, 2014/10

 Times Cited Count:17 Percentile:68.53(Physics, Multidisciplinary)

Journal Articles

Isotope dilution inductively coupled plasma mass spectrometry for determination of $$^{126}$$Sn content in spent nuclear fuel sample

Asai, Shiho; Toshimitsu, Masaaki; Hanzawa, Yukiko; Suzuki, Hideya; Shinohara, Nobuo; Inagawa, Jun; Okumura, Keisuke; Hotoku, Shinobu; Kimura, Takaumi; Suzuki, Kensuke*; et al.

Journal of Nuclear Science and Technology, 50(6), p.556 - 562, 2013/06

 Times Cited Count:11 Percentile:64.2(Nuclear Science & Technology)

The $$^{126}$$Sn content in a spent nuclear fuel solution was determined by ICP-MS for its inventory estimation in high-level radioactive waste. An irradiated UO$$_{2}$$ fuel was used as a sample to evaluate the reliability of the methodology. Prior to the measurement, Sn was separated from $$^{126}$$Te, which causes major isobaric interference in the determination of $$^{126}$$Sn content, along with highly radioactive coexisting elements using an anion-exchange column. The absence of counts attributed to Te in the Sn-containing effluent indicates that Te was completely removed. After washing, Sn retained on the column was readily eluted with 1 M HNO$$_{3}$$. The isotope ratios of Sn were successfully determined and showed good agreement with those obtained through ORIGEN2 calculations. The results reported in this paper are the first experimental values of $$^{126}$$Sn content in the spent nuclear fuel solution originating in spent nuclear fuel irradiated at a nuclear power plant in Japan.

Journal Articles

Development of proposed guideline of flow-induced vibration evaluation for hot-leg piping in a sodium-cooled fast reactor

Sakai, Takaaki; Yamano, Hidemasa; Tanaka, Masaaki; Ono, Ayako; Ohshima, Hiroyuki; Kaneko, Tetsuya*; Hirota, Kazuo*; Sago, Hiromi*; Xu, Y.*; Iwamoto, Yukiharu*; et al.

Proceedings of 15th International Topical Meeting on Nuclear Reactor Thermal Hydraulics (NURETH-15) (USB Flash Drive), 13 Pages, 2013/05

The development of flow-induced vibration evaluation methodology has reached a milestone that separate-effect experimental data under a high Reynolds number regime including swirl and deflected inflow conditions are available for the validation of the methodology. On the other hand, technical standards are desirable to be documented for designers of sodium-cooled fast reactors. From such a background, the documentation of a flow-induced vibration design guideline has been made for the hot-leg piping of Japan sodium-cooled fast reactor. This paper describes the design guideline of the flow-induced vibration evaluation methodology, which has been informed from main separate-effect experiments, as well as supplemental interpretation for the guideline.

Journal Articles

Development of flow-induced vibration evaluation methodology based on unsteady fluid flow analysis for large diameter pipe with elbow in JSFR

Hayakawa, Satoshi*; Ishikura, Shuichi*; Watanabe, Osamu*; Kaneko, Tetsuya*; Yamano, Hidemasa; Tanaka, Masaaki

Proceedings of 8th Japan-Korea Symposium on Nuclear Thermal Hydraulics and Safety (NTHAS-8) (USB Flash Drive), 10 Pages, 2012/12

The present methodology was applied to the analysis for the 1/3-scale experiment of the hot-leg pipe of JSFR, and the predicted stress values were compared with the measured stress values. The predicted stress values were underestimated in the case of using the intact pressure fluctuations obtained by the unsteady fluid flow analysis. Therefore, the improvement of the prediction accuracy of the pressure fluctuations on the pipe wall was attempted.

Journal Articles

Neutron scattering studies of the spin-5/2 antiferromagnetic linear trimer substance SrMn$$_3$$P$$_4$$O$$_{14}$$

Hase, Masashi*; D$"o$nni, A.*; Ozawa, Kiyoshi*; Kitazawa, Hideaki*; Sakai, Osamu*; Pomjakushin, V. Y.*; Keller, L.*; Kaneko, Koji; Metoki, Naoto; Kakurai, Kazuhisa; et al.

Journal of Physics; Conference Series, 340, p.012066_1 - 012066_7, 2012/00

 Times Cited Count:1 Percentile:44.95(Physics, Condensed Matter)

We determined the magnetic structure below $$T_{rm N1}=2.2(1)$$ K of the spin-5/2 antiferromagnetic (AF) trimer substance SrMn$$_3$$P$$_4$$O$$_{14}$$ using neutron powder diffraction experiments. The incommensurate propagation vector is expressed as [0, $$k_y$$, 0], due to competition between the nearest-neighbor and next-nearest-neighbor interactions in trimerized chains. The value of $$k_y$$ is 0.316 to 0.331, changing rapidly at $$T_{rm N2}= 1.75(5)$$ K. We confirmed that the intra-trimer $$J_1$$ interaction is AF. The magnetic excitation peaks were obsereved at 0.46, 0.68, and 1.02 meV. The weak Q dependence indicates the discrete energy levels, which do not contradict the AF trimer model with the intra-trimer interaction value of 0.29 meV (3.4 K).

Journal Articles

Magnetic excitations in the spin-5/2 antiferromagnetic trimer substance SrMn$$_3$$P$$_4$$O$$_{14}$$

Hase, Masashi*; Matsuda, Masaaki*; Kaneko, Koji; Metoki, Naoto; Kakurai, Kazuhisa; Yang, T.*; Cong, R.*; Lin, J.*; Ozawa, Kiyoshi*; Kitazawa, Hideaki*

Physical Review B, 84(21), p.214402_1 - 214402_6, 2011/12

 Times Cited Count:10 Percentile:42.01(Materials Science, Multidisciplinary)

Journal Articles

Simple cation-exchange separation for ICP-MS measurement of $$^{79}$$Se in spent nuclear fuel sample

Asai, Shiho; Hanzawa, Yukiko; Suzuki, Hideya; Toshimitsu, Masaaki; Okumura, Keisuke; Shinohara, Nobuo; Kimura, Takaumi; Inagawa, Jun; Suzuki, Kensuke*; Kaneko, Satoru*

Proceedings of International Conference on Toward and Over the Fukushima Daiichi Accident (GLOBAL 2011) (CD-ROM), 5 Pages, 2011/12

Journal Articles

New ORIGEN2 libraries based on JENDL-4.0 and their validation for long-lived fission products by post irradiation examination analyses of LWR spent fuels

Kojima, Kensuke; Okumura, Keisuke; Asai, Shiho; Hanzawa, Yukiko; Okamoto, Tsutomu; Toshimitsu, Masaaki; Inagawa, Jun; Kimura, Takaumi; Kaneko, Satoru*; Suzuki, Kensuke*

Proceedings of International Conference on Toward and Over the Fukushima Daiichi Accident (GLOBAL 2011) (CD-ROM), 5 Pages, 2011/12

Accurate inventory estimation of long-lived fission products (LLFPs) in LWR spent fuels is important for the quality management and for long-term safety assessment of high-level radioactive vitrified wastes. In Japan, ORIGEN2 has been widely used to estimate the fuel compositions. However, equipped library data in the original ORIGEN2 are old and are not validated enough for LLFPs, such as $$^{79}$$Se, $$^{99}$$Tc, $$^{126}$$Sn and $$^{135}$$Cs, because available post irradiation examination (PIE) data are limited for these nuclides, which have difficulties in radiochemical analyses. For more accurate the estimation, new ORIGEN2 libraries are developed from the latest nuclear data library JENDL-4.0 for cross sections and fission yields, and from other libraries for half-lives, and so on. The new libraries are validated by PIE analyses of the sample fuels irradiated in Cooper, Calvert-Cliffs-1, H. B. Robinson-2, and Ohi-1. As a result, it was found that the new library gives good results for the estimation.

Journal Articles

Analyses of assay data of LWR spent nuclear fuels with a continuous-energy Monte Carlo code MVP and JENDL-4.0 for inventory estimation of $$^{79}$$Se, $$^{99}$$Tc, $$^{126}$$Sn and $$^{135}$$Cs

Okumura, Keisuke; Asai, Shiho; Hanzawa, Yukiko; Suzuki, Hideya; Toshimitsu, Masaaki; Inagawa, Jun; Okamoto, Tsutomu; Shinohara, Nobuo; Kaneko, Satoru*; Suzuki, Kensuke*

Progress in Nuclear Science and Technology (Internet), 2, p.369 - 374, 2011/10

For accurate inventory estimation of long-lived fission products in LWR spent fuels, a new burn-up chain model and decay data based on the latest nuclear data such as JENDL-4.0 was developed. MVP-BURN with the latest nuclear data was applied to several post irradiation examinations including inventory measurements of $$^{79}$$Se, $$^{99}$$Tc, $$^{126}$$Sn and $$^{135}$$Cs. One of them is a new measurement by JAEA. From the PIE analyses, it is found that the new PIE data obtained by JAEA is consistent with the other PIE data by different laboratory with different techniques. It is also confirmed that the present calculation results show good agreements with experimental ones within about 10% for productions of $$^{79}$$Se and $$^{135}$$Cs. In contrast, amounts of $$^{99}$$Tc and $$^{126}$$Sn are overestimated by about 50%. These discrepancies are likely due to the effect of insoluble residue produced during sample dissolution and/or errors of fission yields in the analyses.

Journal Articles

Validation of correlations between Nd isotopes and difficult-to-measure nuclides predicted with burn-up calculation code by post irradiation examination

Asai, Shiho; Okumura, Keisuke; Hanzawa, Yukiko; Suzuki, Hideya; Toshimitsu, Masaaki; Inagawa, Jun; Kimura, Takaumi; Kaneko, Satoru*; Suzuki, Kensuke*

Proceedings of 14th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2011) (CD-ROM), p.1437 - 1442, 2011/09

Journal Articles

Computational study for inventory estimation of Se-79, Tc-99, Sn-126, and Cs-135 in high-level radioactive wastes from spent nuclear fuels of light water reactors

Okumura, Keisuke; Asai, Shiho; Hanzawa, Yukiko; Okamoto, Tsutomu; Suzuki, Hideya; Toshimitsu, Masaaki; Inagawa, Jun; Kimura, Takaumi; Suzuki, Kensuke*; Kaneko, Satoru*

Proceedings of 14th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2011) (CD-ROM), p.1443 - 1450, 2011/09

Inventory estimation of long-lived fission products (LLFPs) in high-level radioactive wastes (HLW) from spent nuclear fuels of light water reactors is important for a safety assessment of their disposal. In order to develop an inventory estimation method of difficult-to-measure LLFPs (Se-79, Tc-99, Sn-126, and Cs-135), a parametric study was carried out by using a sophisticated burnup calculation code and data. In the parametric study, fuel specifications and irradiation conditions are changed in the conceivable range. The considered parameters are fuel assembly types (PWR / BWR), U-235 enrichment, moderator temperature, void fraction, power density, and so on. From the calculated results, we clarify the burnup characteristics of the target LLFPs and their possible ranges of generations. Finally, candidates of the key nuclide are proposed for the scaling factor method of HLW.

Journal Articles

Comparison of post-irradiation experimental data and theoretical calculations for inventory estimation of long-lived fission products in spent nuclear fuel

Asai, Shiho; Hanzawa, Yukiko; Okumura, Keisuke; Suzuki, Hideya; Toshimitsu, Masaaki; Shinohara, Nobuo; Kaneko, Satoru*; Suzuki, Kensuke*

Proceedings of 13th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2010) (CD-ROM), p.261 - 264, 2010/10

Journal Articles

Post irradiation examination analyses with a continuous-energy Monte Carlo code MVP for long-lived fission products in LWR spent fuels

Okumura, Keisuke; Asai, Shiho; Hanzawa, Yukiko; Suzuki, Hideya; Toshimitsu, Masaaki; Inagawa, Jun; Katakura, Junichi; Shinohara, Nobuo; Kaneko, Satoru*; Suzuki, Kensuke*

Proceedings of Joint International Conference of 7th Supercomputing in Nuclear Application and 3rd Monte Carlo (SNA + MC 2010) (USB Flash Drive), 5 Pages, 2010/10

For accurate inventory estimation of long-lived fission products in LWR spent fuels, a new burn-up chain model and decay data based on the latest nuclear data were developed for MVP-BURN. They were applied to three post irradiation examinations including inventory measurements of $$^{79}$$Se, $$^{99}$$Tc, $$^{126}$$Sn and $$^{135}$$Cs. One of them is new measurements performed by JAEA. From the PIE analyses, it is found that the new measurements by JAEA are consistent with the other PIE data obtained by different laboratory with different techniques. It is also confirmed that the present calculation results show good agreements with experimental ones for $$^{79}$$Se and $$^{135}$$Cs within about 10%. In contrast, amounts of $$^{99}$$Tc and $$^{126}$$Sn are overestimated by about up to 50%. These discrepancies are likely due to the effect of insoluble residue in the measurements and/or errors of fission yields in the analyses.

Journal Articles

Longitudinal spin density wave order in a quasi-1D Ising-like quantum antiferromagnet

Kimura, Shojiro*; Matsuda, Masaaki; Masuda, Takatsugu*; Hondo, Suguru*; Kaneko, Koji; Metoki, Naoto; Hagiwara, Masayuki*; Takeuchi, Tetsuya*; Okunishi, Koichi*; He, Z.*; et al.

Physical Review Letters, 101(20), p.207201_1 - 207201_4, 2008/11

 Times Cited Count:51 Percentile:86.19(Physics, Multidisciplinary)

From neutron diffraction measurements on a quasi-1D Ising-like Co$$^{2+}$$ spin compound BaCo$$_2$$V$$_2$$O$$_8$$, we observed an appearance of a novel type of incommensurate ordering in magnetic fields. This ordering is essentially different from the N$'e$el-type ordering, which is expected for the classical system, and the peculiar spin structure is caused by quantum fluctuation inherent in the quantum spin chain. A Tomonaga-Luttinger liquid (TLL) nature characteristic of the gapless quantum 1D system is responsible for the realization of the incommensurate ordering.

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