Valence control of charge and orbital frustrated system YbFeO with electrochemical Li intercalation

Murase, Satoshi*; Yoshikawa, Yumi*; Fujiwara, Kosuke*; Fukada, Yukimasa*; Teranishi, Takashi*; Kano, Jun*; Fujii, Tatsuo*; Inada, Yasuhiro*; Katayama, Misaki*; Yoshii, Kenji; et al.

Journal of Physics and Chemistry of Solids, 162, p.110468_1 - 110468_6, 2022/03

https://doi.org/10.1016/j.jpcs.2021.110468

We report a trial of the valence control for mixed valence iron triangular oxide YbFeO in order to develop an effective technique to control the frustration of charges in strongly correlated electron systems. The electro-chemical doping of Li into YbFeO was examined on the cell type sample similar to the Li-ion secondary battery cell. Systematic change of the lattice constant, Fe-Fe and Fe-Yb distance were observed with Li doping. Maximum value of the doping was over 300 mAh/g. An EXAFS experiment indicated that Li positioned between Yb octahedron layer (U-layer) and Fe-bipyramidal layer (W-layer). However, detailed change of iron valence state of YbFeO was not clearly observed because of the superimpose of the signal from iron metal nano particles in XANES observation. The results indicate that the electrochemical method might be one of the potential technique to control the frustration of charges in YbFeO.

Study on the free corrosion potential at an interface between an Al electrode and an acidic aqueous NaCl solution through density functional theory combined with the reference interaction site model

Kano, Koichi*; Hagiwara, Satoshi*; Igarashi, Takahiro; Otani, Minoru*

Electrochimica Acta, 377, p.138121_1 - 138121_10, 2021/05

https://doi.org/10.1016/j.electacta.2021.138121

We investigated the free corrosion potential at an interface between an Al electrode and an aqueous NaCl solution under acidic conditions via density functional theory combined with the effective screening medium and reference interaction site model (ESM-RISM). The electrode potentials for the anodic and cathodic corrosion reactions were obtained from the grand potential profile as a function of the electron chemical potential at the interface. Thereafter, we determined the free corrosion potential using the Tafel extrapolation method. The results of the free corrosion potential were consistent with previous experimental data. By controlling the pH, we determined the pH dependence of the free corrosion potential, and the results agreed well with the experimental results. Our results indicated that the ESM-RISM method duly described the environmental effect of an acidic solution and precisely determined the free corrosion potential.

Annual report on the environmental radiation monitoring around the Tokai Reprocessing Plant FY2019

Nakano, Masanao; Fujii, Tomoko; Nemoto, Masashi; Tobita, Keiji; Seya, Natsumi; Nishimura, Shusaku; Hosomi, Kenji; Nagaoka, Mika; Yokoyama, Hiroya; Matsubara, Natsumi; et al.

JAEA-Review 2020-069, 163 Pages, 2021/02

JAEA-Review-2020-069.pdf:4.78MB

Environmental radiation monitoring around the Tokai Reprocessing Plant has been performed by the Nuclear Fuel Cycle Engineering Laboratories, based on "Safety Regulations for the Reprocessing Plant of Japan Atomic Energy Agency, Chapter IV - Environmental Monitoring". This annual report presents the results of the environmental monitoring and the dose estimation to the hypothetical inhabitant due to the radioactivity discharged from the plant to the atmosphere and the sea during April 2019 to March 2020. In this report, some data include the influence of the accidental release from the Fukushima Daiichi Nuclear Power Station of Tokyo Electric Power Co., Inc. (the trade name was changed to Tokyo Electric Power Company Holdings, Inc. on April 1, 2016) in March 2011. Appendices present comprehensive information, such as monitoring programs, monitoring methods, monitoring results and their trends, meteorological data and discharged radioactive wastes. In addition, the data which were influenced by the accidental release and exceeded the normal range of fluctuation in the monitoring, were evaluated.

Spallation and fragmentation cross sections for 168 MeV/nucleon Xe ions on proton, deuteron, and carbon targets

Sun, X. H.*; Wang, H.*; Otsu, Hideaki*; Sakurai, Hiroyoshi*; Ahn, D. S.*; Aikawa, Masayuki*; Fukuda, Naoki*; Isobe, Tadaaki*; Kawakami, Shunsuke*; Koyama, Shumpei*; et al.

Physical Review C, 101(6), p.064623_1 - 064623_12, 2020/06

https://doi.org/10.1103/PhysRevC.101.064623

The spallation and fragmentation reactions of Xe induced by proton, deuteron and carbon at 168 MeV/nucleon were studied at RIKEN Radioactive Isotope Beam Factory via the inverse kinematics technique. The cross sections of the lighter products are larger in the carbon-induced reactions due to the higher total kinetic energy of carbon. The energy dependence was investigated by comparing the newly obtained data with previous results obtained at higher reaction energies. The experimental data were compared with the results of SPACS, EPAX, PHITS and DEURACS calculations. These data serve as benchmarks for the model calculations.

Developments of nano-polycrystalline diamond anvil cells for neutron diffraction experiments

Komatsu, Kazuki*; Klotz, S.*; Nakano, Satoshi*; Machida, Shinichi*; Hattori, Takanori; Sano, Asami; Yamashita, Keishiro*; Irifune, Tetsuo*

High Pressure Research, 40(1), p.184 - 193, 2020/02

https://doi.org/10.1080/08957959.2020.1727465

A new high pressure cells for neutron diffraction experiments using nano-polycrystalline anvil is presented. The cell design, off-line pressure generation tests and a gas-loading procedure for this cell are described. The performance is illustrated by powder neutron diffraction patterns of ice VII to 82 GPa. We also demonstrate the feasibility of single crystal neutron diffraction experiments of FeO at ambient conditions using this cell and discuss the current limitation and future developments.

Enhancement of element production by incomplete fusion reaction with weakly bound deuteron

Wang, H.*; Otsu, Hideaki*; Chiga, Nobuyuki*; Kawase, Shoichiro*; Takeuchi, Satoshi*; Sumikama, Toshiyuki*; Koyama, Shumpei*; Sakurai, Hiroyoshi*; Watanabe, Yukinobu*; Nakayama, Shinsuke; et al.

Communications Physics (Internet), 2(1), p.78_1 - 78_6, 2019/07

https://doi.org/10.1038/s42005-019-0165-1

Searching for effective pathways for the production of proton- and neutron-rich isotopes through an optimal combination of reaction mechanism and energy is one of the main driving forces behind experimental and theoretical nuclear reaction studies as well as for practical applications in nuclear transmutation of radioactive waste. We report on a study on incomplete fusion induced by deuteron, which contains one proton and one neutron with a weak binding energy and is easily broken up. This reaction study was achieved by measuring directly the cross sections for both proton and deuteron for Pd at 50 MeV/u via inverse kinematics technique. The results provide direct experimental evidence for the onset of a cross-section enhancement at high energy, indicating the potential of incomplete fusion induced by loosely-bound nuclei for creating proton-rich isotopes and nuclear transmutation of radioactive waste.

Pressure-induced stacking disorder in boehmite

Ishii, Yusuke*; Komatsu, Kazuki*; Nakano, Satoshi*; Machida, Shinichi*; Hattori, Takanori; Sano, Asami; Kagi, Hiroyuki*

Physical Chemistry Chemical Physics, 20(24), p.16650 - 16656, 2018/06

https://doi.org/10.1039/C8CP02565G

The structure of an aluminum layered hydroxide, boehmite (-AlOOH), as a function of pressure was studied by using synchrotron X-ray and neutron diffraction. Peak broadening and subsequent splitting, which are only found for hkl (h 0) peaks in the X-ray diffraction patterns above 25 GPa, are explained by stacking disorder accompanied with a continuously increasing displacement of the AlO octahedral layer along a-axis. This finding could be the first experimental result for the pressure-induced stacking disorder driven by the continuous layer displacement. The magnitude of the layer displacement was estimated from the X-ray scattering profile calculation based on the stacking disordered structure model. Hydrogen bond geometries of boehmite, obtained by structure refinements on the observed neutron diffraction patterns for deuterated sample up to 10 GPa, show linearly approaching O-D covalent and DO hydrogen bond distances and they could merge below 26 GPa. The pressure-induced stacking disorder would make the electrostatic potential of hydrogen bonds asymmetric, yielding less chance for the proton-tunnelling.

Role of multichance fission in the description of fission-fragment mass distributions at high energies

Hirose, Kentaro; Nishio, Katsuhisa; Tanaka, Shoya*; Lguillon, R.*; Makii, Hiroyuki; Nishinaka, Ichiro*; Orlandi, R.; Tsukada, Kazuaki; Smallcombe, J.*; Vermeulen, M. J.; et al.

Physical Review Letters, 119(22), p.222501_1 - 222501_6, 2017/12

https://doi.org/10.1103/PhysRevLett.119.222501

Fission-fragment mass distributions were measured for U, Np and Pu populated in the excitation-energy range from 10 to 60 MeV by multi-nucleon transfer channels in the reaction O + U at the JAEA tandem facility. Among them, the data for U and Np were observed for the first time. It was found that the mass distributions for all the studied nuclides maintain a double-humped shape up to the highest measured energy in contrast to expectations of predominantly symmetric fission due to the washing out of nuclear shell effects. From a comparison with the dynamical calculation based on the fluctuation-dissipation model, this behavior of the mass distributions was unambiguously attributed to the effect of multi-chance fission.

Annual report on the environmental radiation monitoring around the Tokai Reprocessing Plant FY2015

Nakano, Masanao; Fujita, Hiroki; Mizutani, Tomoko; Hosomi, Kenji; Nagaoka, Mika; Hokama, Tomonori; Yokoyama, Hiroya; Nishimura, Tomohiro; Matsubara, Natsumi; Maehara, Yushi; et al.

JAEA-Review 2016-035, 179 Pages, 2017/03

JAEA-Review-2016-035.pdf:4.2MB

Environmental radiation monitoring around the Tokai Reprocessing Plant has been performed by the Nuclear Fuel Cycle Engineering Laboratories, based on "Safety Regulations for the Reprocessing Plant of Japan Atomic Energy Agency, Chapter IV - Environmental Monitoring". This annual report presents the results of the environmental monitoring and the dose estimation to the hypothetical inhabitant due to the radioactivity discharged from the plant to the atmosphere and the sea during April 2015 to March 2016. In this report, some data include the influence of the accidental release from the Fukushima Daiichi Nuclear Power Station of Electric Power Company Holdings, Inc. in March 2011. Appendices present comprehensive information, such as monitoring programs, monitoring methods, monitoring results and their trends, meteorological data and discharged radioactive wastes. In addition, the data which were influenced by the accidental release and were exceeded the normal range of fluctuation in the monitoring, were evaluated.

Simultaneous measurements of superradiance at multiple wavelength from helium excited states, 2; Analysis

Ohae, Chiaki*; Harries, J.; Iwayama, Hiroshi*; Kawaguchi, Kentaro*; Kuma, Susumu*; Miyamoto, Yuki*; Nagasono, Mitsuru*; Nakajima, Kyo*; Nakano, Itsuo*; Shigemasa, Eiji*; et al.

Journal of the Physical Society of Japan, 85(3), p.034301_1 - 034301_10, 2016/03

https://doi.org/10.7566/JPSJ.85.034301