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Teraoka, Yuden; Yoshigoe, Akitaka; Moritani, Kosuke; Takakuwa, Yuji*; Ogawa, Shuichi*; Ishizuka, Shinji*; Okada, Michio*; Fukuyama, Tetsuya*; Kasai, Toshio*
Hoshako, 18(5), p.298 - 309, 2005/09
Representative research results in surface reaction dynamics, performed at a surface chemistry experimental station installed in the JAEA soft X-ray beamline in the SPring-8, were reviewed. As a research result in JAEA, SiO desorption mechanisms in the Si(001) oxidation at high temperature were introduced. As a collaboration with Osaka University on oxidation reaction dynamics of Cu, collision-induced atom absorption process was introduced. As a collaboration with Tohoku University on Ti(0001) oxidation reaction dynamics, it was introduced that two peaks, found in an incident energy dependence of initial sticking probability, were corresponding to potential energy barriers of dissociative adsorption of O molecules.
Terasaki, Hidenori*; Kato, Takumi*; Urakawa, Satoru*; Funakoshi, Kenichi*; Suzuki, Akio*; Okada, Taku; Maeda, Makoto*; Sato, Jin*; Kubo, Tomoaki*; Kasai, Shizu*
Earth and Planetary Science Letters, 190(1-2), p.93 - 101, 2001/07
Times Cited Count:52 Percentile:68.57(Geochemistry & Geophysics)The Fe-FeS melt is thought to be the major candidate of the outer core material. Its viscosity is one of the most important physical properties to study the dynamics of the convection in the outer core. We performed the in situ viscosity measurement of the Fe-FeS melt under high pressure using X-ray radiography falling sphere method with a novel sample assembly. Viscosity was measures in the temperature, pressure, and compositional conditions of 1233-1923 K, 1.5-6.9 GPa, and Fe-Fe S (wt %), respectively. The viscosity coefficients obtained by 17 measurements change systematically in the range of 0.008-0.036 Pa s. An activation energy of the viscous flow, 30 kJ/mol, and the activation volume, 1.5 cm /mol, are determined as the temperature and pressure dependence, and the viscosity of the Fe S melt is found to be smaller than that of the Fe melt by 15 %. These tendencies can be well correlated with the structural variation of the Fe-FeS melt.