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Journal Articles

An X-ray and neutron scattering study of aqueous MgCl$$_2$$ solution in the gigapascal pressure range

Yamaguchi, Toshio*; Fukuyama, Nami*; Yoshida, Koji*; Katayama, Yoshinori*; Machida, Shinichi*; Hattori, Takanori

Liquids, 3(3), p.288 - 302, 2023/09

We report the structure of an aqueous 2 mol/kg MgCl$$_2$$ solution at pressures from 0.1 MPa to 4 GPa and temperatures from 300 to 500 K revealed by X-ray and neutron scattering measurements. The scattering data are analyzed by empirical potential structure refinement (EPSR) modeling to derive the pair distribution functions, coordination number distributions, angle distributions, and spatial density functions as a function of pressure and temperature. Mg$$^{2+}$$ forms rigid solvation shells extended to the third shell; the first solvation shell of six-fold octahedral coordination with about six water molecules at 0 GPa transforms into about five water molecules and one Cl$$^-$$ due to the formation of the contact ion pairs in the GPa pressure range. The Cl$$^-$$ solvation shows a substantial pressure dependence; the coordination number of a water oxygen atom around Cl$$^-$$ increases from 8 at 0.1 MPa/300 K to 10 at 4 GPa/500 K. The solvent water transforms the tetrahedral network structure at 0.1 MPa/300 K to a densely packed structure in the GPa pressure range; the number of water oxygen atoms around a central water molecule gradually increases from 4.6 at 0.1 MPa/298 K to 8.4 at 4 GPa/500 K.

Journal Articles

Site occupancy of interstitial deuterium atoms in face-centred cubic iron

Machida, Akihiko; Saito, Hiroyuki; Sugimoto, Hidehiko*; Hattori, Takanori; Sano, Asami; Endo, Naruki*; Katayama, Yoshinori; Iizuka, Riko*; Sato, Toyoto*; Matsuo, Motoaki*; et al.

Nature Communications (Internet), 5, p.5063_1 - 5063_6, 2014/09

 Times Cited Count:47 Percentile:85.67(Multidisciplinary Sciences)

Iron hydride FeH$$_x$$, is thermodynamically stable only at high hydrogen pressure of several GPa. To investigate the hydrogenation process and hydrogen state in iron hydride, it is necessary to carry out the in-situ measurement under high pressure and high temperature. In this study, we performed the in-situ neutron diffraction measurement of Fe-D system using the high pressure neutron diffractometer PLANET in the MLF, J-PARC, and determined the deuterium occupying sites and occupancies in fcc-FeD$$_x$$. We found the minor occupation of tetrahedral sites under high pressure and high temperature. We considered the mechanism of the minor occupation based on the Quantum-mechanical calculation.

Journal Articles

Synthesis and formation process of Al$$_{2}$$CuH$$_{x}$$; A New class of interstitial aluminum-based alloy hydride

Saito, Hiroyuki; Takagi, Shigeyuki*; Endo, Naruki; Machida, Akihiko; Aoki, Katsutoshi; Orimo, Shinichi*; Katayama, Yoshinori

APL Materials (Internet), 1(3), p.032113_1 - 032113_7, 2013/09

 Times Cited Count:14 Percentile:54.37(Nanoscience & Nanotechnology)

Journal Articles

Formation of an Fe-H complex anion in YFe$$_{2}$$; Adjustment of imbalanced charge by additional Li as an electron donor

Matsuo, Motoaki*; Saito, Hiroyuki; Machida, Akihiko; Sato, Ryutaro*; Takagi, Shigeyuki*; Miwa, Kazutoshi*; Watanuki, Tetsu; Katayama, Yoshinori; Aoki, Katsutoshi; Orimo, Shinichi*

RSC Advances (Internet), 3(4), p.1013 - 1016, 2013/01

 Times Cited Count:16 Percentile:52.52(Chemistry, Multidisciplinary)

Journal Articles

Real-time X-ray diffraction of metastable phases during solidification from the undercooled LuFeO$$_{3}$$ melt by two-dimensional detector at 1 kHz

Kumar, M. V.*; Kuribayashi, Kazuhiko*; Nagashio, Kosuke*; Ishikawa, Takehiko*; Okada, Jumpei*; Yu, J.*; Yoda, Shinichi*; Katayama, Yoshinori

Applied Physics Letters, 100(19), p.191905_1 - 191905_4, 2012/05

 Times Cited Count:2 Percentile:9(Physics, Applied)

${it In-situ}$ identification of metastable phases formed from the undercooled LuFeO$$_{3}$$ melt under controlled oxygen partial pressure $$P$$o$$_{2}$$ was studied by X-ray diffraction measurements at a synchrotron radiation source. Real-time observation of the formation and growth of individual phases during the single recalescence of Lu$$_{3}$$Fe$$_{2}$$O$$_{7}$$ and LuFe$$_{2}$$O$$_{4}$$ phases at $$P$$o$$_{2}$$ of 1$$times$$10$$^{3}$$ Pa has been revealed by a high speed imaging system at 1 kHz. The obtained diffraction pattern of the metastable phase in the LuFeO$$_{3}$$ system was consistent with that of the metastable and stable phases reported in the Lu-Fe-O system.

Journal Articles

Tilted-foil technique for producing a spin-polarized radioactive isotope beam

Hirayama, Yoshikazu*; Mihara, Mototsugu*; Watanabe, Yutaka*; Jeong, S. C.*; Miyatake, Hiroari*; Momota, Sadao*; Hashimoto, Takashi*; Imai, Nobuaki*; Matsuta, Kensaku*; Ishiyama, Hironobu*; et al.

European Physical Journal A, 48(5), p.54_1 - 54_10, 2012/05

 Times Cited Count:2 Percentile:16.89(Physics, Nuclear)

Journal Articles

Hydrogen storage using aluminum hydride

Ikeda, Kazuki*; Orimo, Shinichi*; Saito, Hiroyuki; Machida, Akihiko; Katayama, Yoshinori; Aoki, Katsutoshi

Suiso Seizo, Kyuzo, Chozo Zairyo To Anzenka, p.317 - 327, 2010/08

AlH$$_{3}$$ is a metal hydride with a large gravimetric and volumetric hydrogen content (10.1 wt.% and 149kgH$$_{2}$$/m$$^{3}$$, respectively), and therefore it is promising as a hydrogen storage material. The high capacity and low desorption temperature (80$$sim$$150$$^{circ}$$C) have attracted much attention. In situ X-ray diffraction measurements for the Al-H binary system at high pressures and temperatures were performed to investigate the hydrogenation of aluminum metal immersed in hydrogen fluid as well as the phase stability of the aluminum hydride formed.

Journal Articles

Metamagnetic behavior in heavy-fermion compound YbIr$$_2$$Zn$$_{20}$$

Takeuchi, Tetsuya*; Yasui, Shinichi*; Toda, Masatoshi*; Matsushita, Masaki*; Yoshiuchi, Shingo*; Oya, Masahiro*; Katayama, Keisuke*; Hirose, Yusuke*; Yoshitani, Naohisa*; Honda, Fuminori*; et al.

Journal of the Physical Society of Japan, 79(6), p.064609_1 - 064609_15, 2010/06

 Times Cited Count:42 Percentile:83.85(Physics, Multidisciplinary)

Journal Articles

Heavy fermion state in YbIr$$_2$$Zn$$_{20}$$

Yoshiuchi, Shingo*; Toda, Masatoshi*; Matsushita, Masaki*; Yasui, Shinichi*; Hirose, Yusuke*; Oya, Masahiro*; Katayama, Keisuke*; Honda, Fuminori*; Sugiyama, Kiyohiro*; Hagiwara, Masayuki*; et al.

Journal of the Physical Society of Japan, 78(12), p.123711_1 - 123711_4, 2009/12

 Times Cited Count:39 Percentile:82.87(Physics, Multidisciplinary)

Journal Articles

On-line diffusion tracing in Li ionic conductors by the short-lived radioactive beam of $$^{8}$$Li

Jeong, S.-C.*; Katayama, Ichiro*; Kawakami, Hirokane*; Watanabe, Yutaka*; Ishiyama, Hironobu*; Imai, Nobuaki*; Hirayama, Yoshikazu*; Miyatake, Hiroari; Sataka, Masao; Sugai, Hiroyuki; et al.

Japanese Journal of Applied Physics, 47(8), p.6413 - 6415, 2008/08

 Times Cited Count:5 Percentile:22.83(Physics, Applied)

A non-destructive and on-line diffusion tracing in Li ionic conductors has been demonstrated. As a tracer, pulsed beam of $$^{8}$$Li was implanted into LiGa. By analyzing the time dependent yield of the $$alpha$$-particles decaying from $$^{8}$$Li, diffusion coefficients were extracted with a high accuracy. The ordering of Li vacancies in the Li-deficient $$beta$$ phase of LiGa was observed for the first time in terms of the Li diffusion.

Journal Articles

Microstructure formation and in situ phase identification from undercooled Co-61.8 at.% Si melts solidified on an electromagnetic levitator and an electrostatic levitator

Li, M.*; Nagashio, Kosuke*; Ishikawa, Takehiko*; Mizuno, Akitoshi*; Adachi, Masayoshi*; Watanabe, Masahito*; Yoda, Shinichi*; Kuribayashi, Kazuhiko*; Katayama, Yoshinori

Acta Materialia, 56(11), p.2514 - 2525, 2008/06

 Times Cited Count:23 Percentile:72(Materials Science, Multidisciplinary)

Co-61.8 at.% Si (CoSe-CoSi$$_{2}$$) eutectic alloys were solidified on an electromagnetic levitator (EML) and an electrostatic levitator (ESL) at different undercooling levels. The results indicated that there is only a single recalescence event at low undercooling with the CoSi intermetallic compound as primary phase, which is independent of processing facilities, on either an EML or an ESL. The microstructure, however, is strongly dependent on the processing facility. On high undercooling, double recalescence takes place regardless of levitation condition. In situ X-ray diffraction of alloys solidified on the EML demonstrates that the CoSi$$_{2}$$ compound becomes the primary phase upon the first recalescence, and the CoSi intermetallic phase crystallizes during the second recalescence. In addition to phase identification, real-time diffraction patterns can also provide additional evidence of the fragmentation of the primary phase.

Journal Articles

Diffusion of $$^{8}$$Li short-lived radiotracer in Li ionic conductors of NaTl-type intermetallic compounds

Sugai, Hiroyuki; Sataka, Masao; Okayasu, Satoru; Ichikawa, Shinichi; Nishio, Katsuhisa; Mitsuoka, Shinichi; Nakanoya, Takamitsu; Osa, Akihiko; Sato, Tetsuya; Hashimoto, Takashi; et al.

Defect and Diffusion Forum, 273-276, p.667 - 672, 2008/00

Journal Articles

A New measurement of the astrophysical $$^8$$Li($$alpha$$, n)$$^{11}$$B reaction

Ishiyama, Hironobu*; Hashimoto, Takashi; Ishikawa, Tomoko*; Watanabe, Yutaka*; Das, S. K.*; Miyatake, Hiroari; Mizoi, Yutaka*; Fukuda, Tomokazu*; Tanaka, Masahiko*; Fuchi, Yoshihide*; et al.

Physics Letters B, 640(3), p.82 - 85, 2006/09

 Times Cited Count:32 Percentile:84.6(Astronomy & Astrophysics)

The excitation function of the $$^{8}$$Li($$alpha$$,n)$$^{11}$$B reaction was measured while identifying the final state event by event in the region of E$$_{rm{cm}}$$ = 0.7 - 2.6 MeV using a highly efficient detector system and a low-energy $$^8$$Li beam. The results are much improved both in statistics and precisions, and show smaller cross sections than those of previous measurements by a factor of more than 2 in the low-energy region of E$$_{rm{cm}}le$$ 1.5 MeV. A resonance-like structure is found at around E$$_{rm{cm}}$$ = 0.85 MeV.

Journal Articles

A New measurement of the $$^8$$Li($$alpha$$,n)$$^{11}$$B reaction for astrophysical interest

Das, S. K.*; Fukuda, Tomokazu*; Mizoi, Yutaka*; Ishiyama, Hironobu*; Miyatake, Hiroari*; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Tanaka, Masahiko*; Yoshikawa, Nobuharu*; Jeong, S.-C.*; et al.

AIP Conference Proceedings 847, p.374 - 376, 2006/07

no abstracts in English

Journal Articles

Production of a low-energy radioactive nuclear beam with high purity using JAERI-RMS

Ishiyama, Hironobu*; Ishikawa, Tomoko*; Hashimoto, Takashi; Watanabe, Yutaka*; Hirayama, Yoshikazu*; Imai, Nobuaki*; Miyatake, Hiroari; Tanaka, Masahiko*; Fuchi, Yoshihide*; Yoshikawa, Nobuharu*; et al.

Nuclear Instruments and Methods in Physics Research A, 560(2), p.366 - 372, 2006/05

 Times Cited Count:7 Percentile:47.59(Instruments & Instrumentation)

Thanks to the nature of inverse transfer-reactions, low-energy radioactive nuclear beams in light neutron-rich region were produced. The mass-separation and velocity-separation of the JAERI recoil mass-separator help to form high purity beams. The beams of $$^8$$Li, $$^{12}$$B, and $$^{16}$$N-RNBs are utilized to the experiments, so far, with those beam intensities and purities of 1.4$$times$$10$$^4$$ pps and 99$$%$$, 7.8$$times$$10$$^3$$ pps and 98$$%$$, and 4.7$$times$$10$$^3$$ pps and 98.5$$%$$, respectively.

Journal Articles

Gated multiple-sampling and tracking proportional chamber; New detector system for nuclear astrophysical study with radioactive nuclear beams

Hashimoto, Takashi; Ishiyama, Hironobu*; Ishikawa, Tomoko*; Kawamura, Takashi*; Nakai, Koji*; Watanabe, Yutaka*; Miyatake, Hiroari; Tanaka, Masahiko*; Fuchi, Yoshihide*; Yoshikawa, Nobuharu*; et al.

Nuclear Instruments and Methods in Physics Research A, 556(1), p.339 - 349, 2006/01

 Times Cited Count:32 Percentile:89.18(Instruments & Instrumentation)

A new type of three dimensional tracking and proportional gas counter has been developed. Adopting a gating-grid system, performance of the detector becomes stable under the injection rate of charged particles less than 4$$times$$10$$^4$$ pps. It is a useful detection system for astrophysical experiments using radioactive nuclear beams, since the efficiency is so high as 100 %.

Journal Articles

Measurement of self-diffusion coefficients in Li ionic conductors by using the short-lived radiotracer of $$^8$$Li

Jeong, S.-C.*; Katayama, Ichiro*; Kawakami, Hirokane*; Watanabe, Yutaka*; Ishiyama, Hironobu*; Imai, Nobuaki*; Hirayama, Yoshikazu*; Miyatake, Hiroari; Sataka, Masao; Okayasu, Satoru; et al.

Journal of Phase Equilibria and Diffusion, 26(5), p.472 - 476, 2005/09

Authors developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound $$beta$$LiAl using an $$alpha$$-emitting radiotracer of $$^8$$Li(T$$_{1/2}$$ = 0.84 s). It was found that the time-dependent yields of the alpha particles from the diffusing 8Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in $$beta$$LiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects.

Journal Articles

Photoemission and core-level absorption spectroscopy of Fe$$_{x}$$NbS$$_{2}$$

Saito, Yuji; Kobayashi, Keisuke*; Fujimori, Atsushi; Yamamura, Yasuhisa*; Koyano, Mikio*; Tsuji, Toshihide*; Katayama, Shinichi*

Journal of Electron Spectroscopy and Related Phenomena, 144-147, p.829 - 832, 2005/06

 Times Cited Count:5 Percentile:27.37(Spectroscopy)

no abstracts in English

Journal Articles

Measurement of diffusion coefficients in solids by the short-lived radioactive beam of $$^{8}$$Li

Jeong, S.-C.*; Katayama, Ichiro*; Kawakami, Hirokane*; Watanabe, Yutaka*; Ishiyama, Hironobu*; Miyatake, Hiroari*; Sataka, Masao; Okayasu, Satoru; Sugai, Hiroyuki; Ichikawa, Shinichi; et al.

Nuclear Instruments and Methods in Physics Research B, 230(1-4), p.596 - 600, 2005/04

 Times Cited Count:6 Percentile:45.61(Instruments & Instrumentation)

no abstracts in English

Journal Articles

A Broad-band RF buncher cavity using finemet cut cores for ion beams

Watanabe, Masao; Chiba, Yoshiaki*; Koseki, Tadashi*; Katayama, Takeshi*; Oshiro, Yukimitsu*; Watanabe, Shinichi*

Proceedings of 17th International Conference on Cyclotrons and Their Applications (CYCLOTRONS 2004) (CD-ROM), 3 Pages, 2005/00

A broad-band rf cavity as a buncher of ion beams has been developed. Operating frequencies of the cavity is between 18 and 45 MHz. The cavity was installed in the beam transport line of the Hi-ECR ion source system in CNS for the beam test. Beam structure of 30 MHz was successfully observed for 10 keV proton beam.

43 (Records 1-20 displayed on this page)