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O
with electrochemical Li
intercalationMurase, Satoshi*; Yoshikawa, Yumi*; Fujiwara, Kosuke*; Fukada, Yukimasa*; Teranishi, Takashi*; Kano, Jun*; Fujii, Tatsuo*; Inada, Yasuhiro*; Katayama, Misaki*; Yoshii, Kenji; et al.
Journal of Physics and Chemistry of Solids, 162, p.110468_1 - 110468_6, 2022/03
Times Cited Count：0 Percentile：0(Chemistry, Multidisciplinary)We report a trial of the valence control for mixed valence iron triangular oxide YbFeO in order to develop an effective technique to control the frustration of charges in strongly correlated electron systems. The electro-chemical doping of Li into YbFeO was examined on the cell type sample similar to the Li-ion secondary battery cell. Systematic change of the lattice constant, Fe-Fe and Fe-Yb distance were observed with Li doping. Maximum value of the doping was over 300 mAh/g. An EXAFS experiment indicated that Li positioned between Yb octahedron layer (U-layer) and Fe-bipyramidal layer (W-layer). However, detailed change of iron valence state of YbFeO was not clearly observed because of the superimpose of the signal from iron metal nano particles in XANES observation. The results indicate that the electrochemical method might be one of the potential technique to control the frustration of charges in YbFeO.
Nakashima, Hiroyoshi*; Koyama, Tomofumi*; Tatsuta, Keisuke*; Katayama, Tatsuo*; Aoyagi, Kazuhei
Dai-14-Kai Iwa No Rikigaku Kokunai Shimpojiumu Koen Rombunshu (Internet), 6 Pages, 2017/01
In this study, we created the three dimensional model based on equivalent continuum approach to study the penetration length and enhancement of the hydraulic conductivity of the rock mass. The developed numerical model was applied to the in situ grout injection conducted in the ventilation shaft of the Horonobe Underground Research Laboratory. We evaluated the hydraulic conductivity of the rock mass after the grout operation. As a result, hydraulic conductivity of the highly permeable fault was decreased in 4 orders of magnitude, which is almost consistent with the in situ hydraulic conductivity obtained from in situ Luegeon test after the grout injection. Thus the simulation method described in this paper can be applied to the evaluation of the efficiency of in situ grout injection.
Koyama, Tomofumi*; Katayama, Tatsuo*; Tanaka, Tatsuya*; Kuzuha, Yuji; Onishi, Yuzo*
Proceedings of 7th Asian Rock Mechanics Symposium (ARMS-7) (USB Flash Drive), p.712 - 720, 2012/10
Grouting is commonly used to decrease the hydraulic conductivity of the fractured rock masses and control the groundwater inflow. Since underground facilities were constructed in various geological conditions, different types of grout material and mixing/injection methods were developed for effective and economical grout injection. It is also important to evaluate the grout arrival distance and the range of altered hydraulic conductivity field after grout injection. However, the mechanism of grout injection process has not been clarified sufficiently yet due to complicated chemical and physical processes of grout. In this study, to simulate the grout injection process, the three-dimensional numerical model based on equivalent continuum approach was developed and applied to the in-situ grout injection tests at Grimsel test site, Switzerland. In the simulations, the injection pressure and/or injection rate was given as a boundary condition and total amount of injected grout (silica sol) was calculated. The simulation results were also compared with the ones obtained from in-situ measurements/monitoring and show qualitatively good agreement.
Koyama, Tomofumi*; Onishi, Yuzo*; Bruines, P.*; Tanaka, Tatsuya*; Hasui, Akinori*; Katayama, Tatsuo*; Kishi, Hirokazu; Kuzuha, Yuji
Proceedings of 2012 ISRM International Symposium; Rock Engineering and Technology for Sustainable Underground Construction (EUROCK 2012) (USB Flash Drive), 10 Pages, 2012/05
Grouting, which involves injection of grout material, is commonly used to decrease the hydraulic conductivity of the fractured rock masses and control the groundwater inflow. However, the mechanism of grout injection process has not been clarified sufficiently yet due to complicated chemical and physical processes of grout. In this study, to simulate the grout injection process, the three-dimensional numerical model based on equivalent continuum approach was developed.
Koyama, Tomofumi*; Katayama, Tatsuo*; Hasui, Akinori*; Tanaka, Tatsuya*; Kishi, Hirokazu; Onishi, Yuzo*
Dai-41-Kai Gamban Rikigaku Ni Kansuru Shimpojiumu Koenshu (CD-ROM), p.83 - 88, 2012/01
In this study, to simulate the grout injection process, the 3-D numerical model based on equivalent continuum approach was developed. The viscosity measurements for silica sol was performed to measure the time-dependent viscosity. The developed numerical model was applied to the planned in-situ grout injection tests at Grimsel test site (GTS), Switzerland. The rock type is fractured granite and the equivalent porous media was created from the DFN (Discrete Fracture Network) based on the frature data obtained from the observation boreholes. The preliminary simulation was carried out to determine the suitable grout injection pressure and investigate the arrival distance of grout from injection boreholes.
Ohashi, Hideki*; Koyama, Tomofumi*; Hasui, Akinori*; Katayama, Tatsuo*; Kuzuha, Yuji
Doboku Gakkai Heisei-23-Nendo Zenkoku Taikai Dai-66-Kai Nenji Gakujutsu Koenkai Koen Gaiyoshu (DVD-ROM), p.77 - 78, 2011/09
no abstracts in English
Kuzuha, Yuji; Kishi, Hirokazu; Hasui, Akinori*; Katayama, Tatsuo*; Koyama, Tomofumi*
Doboku Gakkai Heisei-23-Nendo Zenkoku Taikai Dai-66-Kai Nenji Gakujutsu Koenkai Koen Gaiyoshu (DVD-ROM), p.79 - 80, 2011/09
no abstracts in English
Marushita, Motoharu*; Mitsui, Takaya; Fukuda, Tatsuo; Takahashi, Masamitsu; Inami, Toshiya; Katayama, Yoshinori; Shiwaku, Hideaki; Mizuki, Junichiro
Nuclear Instruments and Methods in Physics Research A, 467-468(Part.1), p.392 - 395, 2001/07
Times Cited Count：4 Percentile：33.81(Instruments & Instrumentation)no abstracts in English
