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Sano, Kyohei; Tameta, Yuito; Akuzawa, Tadashi; Kato, Soma; Takano, Yugo*; Akiyama, Kazuki
JAEA-Technology 2024-018, 68 Pages, 2025/02
High Active Solid Waste Storage Facility (HASWS) at the Tokai Reprocessing Plant (TRP) is a facility for storing highly radioactive solid waste generated from the reprocessing operation. Wet cells in HASWS store hull cans that contain fuel cladding tubes (hull) and fuel end pieces remained after the spent nuclear fuel shearing and dissolving, as well as used filters and contaminated equipment. Dry cells in HASWS store analytical waste containers that contain waste jugs and the other waste generated from analytical operation of samples in TRP. Since HASWS does not have waste recovery equipment from the cells, it is considered that recovery equipment to be installed. In the wet cells, methods of recovery wet-stored waste are being considered that utilize a ROV, which has been used in decommissioning in the UK, and a lifter, which is used in the marine industry to float and transport items sinking to the bottom of the sea. To confirm the feasibility of the recovery method that combines the functions of the ROV and the lifter, tests for removing waste were conducted in steps that came closer to the real environment: a "unit test" to confirm the functions required of each of the ROV and the lifter, a "combination test" to combine the ROV and the lifter to move waste underwater, and a "comprehensive test" to retrieve waste in an environment simulating the hull storage facility. Through this test, the ROV and the lifter were able to perform a series of tasks required to recovery waste - cutting the wires attached to the waste, attaching a lifter to the waste, moving the waste to under the opening, and attaching the recovery device to the moved waste - in series, confirming the feasibility of the method for recovery wet-stored waste using the ROV and the lifter.
Soma, Yasutaka; Kato, Chiaki
Zairyo To Kankyo 2022 Koenshu (CD-ROM), p.219 - 220, 2022/05
It is important to understand the electrochemical properties of stainless steel in environment created within crevice of stainless steel in high temperature water (crevice environment). This is because acidification and concentration of impurity ions occur in the crevice environment and this is common inside the stress corrosion crack. In this study, we reproduced the crevice environment in bulk scale and investigated mainly the effect of Cr concentration on the electrochemical properties of Fe-Cr-Ni alloys. Polarization curves of Fe-20Ni-xCr (x=16.4, 23, 26) were measured in water with a temperature of 288C, a Cl concentration of 2
10
mol/dm
, a pH value of about 4.5, and a dissolved hydrogen concentration of 10 ppb. The peak currents of active dissolution (at -400 mV) and passive current density (at -50 mV) for specimens with Cr concentrations x = 16.4, 23, and 26% were approximately 13.8, 15.9, 10.0
Acm
, and 18.4, 8.5, 8.5
Acm
, respectively. Although the current values of x=26 were slightly lower in both cases, it was concluded that there was no clear dependence of the polarization curve on Cr concentration in this environment.
Soma, Yasutaka; Kato, Chiaki
Dai-68-Kai Zairyo To Kankyo Toronkai Koenshu (CD-ROM), p.205 - 206, 2021/10
This study investigates the effect of temperature on dissipation behavior of Cl ion within the crevice of stainless steel. Concentration of Cl ion was evaluated by conductivity measured by using sensors installed at crevice specimen. At 50 and 80 C, Cl ions within the crevice of PEEK and Pt dissipated in accordance with concentration diffusion. On the contrary, dissipation speed of Cl ions inside the Type-304L stainless steel were much lower than those anticipated by simple concentration diffusion. This behavior attribute to the anodic dissolution of stainless steel inside the crevice, therefore, to quantitatively understand the effect of temperature on the dissipation behavior, it is necessary to know the anodic dissolution rate and occurrence of localized corrosion. Numerical analysis taking the effect of concentration diffusion and migration into account is also needed.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
Proceedings of the 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, Vol.2, p.509 - 521, 2018/00
In-situ electrochemical measurement within crevice of stainless steel in 288C water has been conducted to analyze crevice water chemistry. Small sensors (
250
m) measured local solution electrical conductivity,
, polarization resistance, and electrochemical corrosion potential. Real-time response of the
as functions of bulk water conductivity, dissolved oxygen (DO) concentration has been quantitatively analyzed. The effect of geometrical factors on the crevice environment was also studied. The
differ more than an order of magnitude depending on the oxygen potential inside the crevice. The
increased by small amount of bulk DO (e.g. 30 ppb). Maximum
was observed with DO of 32000 ppb and became more than 100 times higher than that of bulk water. Crevice geometry affected significantly on the water chemistry inside.
Watakabe, Tomoyoshi; Yamamoto, Tomohiko; Fukasawa, Tsuyoshi*; Okamura, Shigeki*; Somaki, Takahiro*; Morobishi, Ryota*; Sakurai, Yu*; Kato, Koji*
Nihon Kikai Gakkai Rombunshu (Internet), 83(850), p.16-00444_1 - 16-00444_14, 2017/06
A seismic isolation system composed of a thick rubber bearing and an oil damper has been developed for Sodium-Cooled Fast Reactor. This paper focused on the aging properties of thick rubber bearings, such as basic mechanical properties and ultimate strength. Aging of the rubber bearings was reproduced using thermal degradation based on Arrhenius law.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
Fushoku Boshoku Kyokai Dai-63-Kai Zairyo To Kankyo Toronkai Koenshu (CD-ROM), p.253 - 256, 2016/10
Contribution of corrosion to advance of stress corrosion cracking (SCC) of stainless steel in high temperature water must be assessed because serious corrosion can be found within SCC of light water reactors. The corrosion took the form of both intergranular and grain-matrix attack indicate aggressive corrosion condition was formed in the crevice of the SCC. We have investigated the crevice environment electrochemically and found that local electrical conductivity of the crevice solution at satisfactory narrow crevice gap having more than 100 times higher than that of bulk solution. In this research we assessed effect of cyclic deaerated and aerated bulk solution to the crevice environment. The result showed that electrical conductivity of the crevice solution under the deaerated bulk solution increased more than 10times by injection of pure oxygen suggest that the dissolved oxygen caused aggressive corrosion condition within the crevice.
Watakabe, Tomoyoshi; Yamamoto, Tomohiko; Fukasawa, Tsuyoshi*; Okamura, Shigeki*; Somaki, Takahiro*; Morobishi, Ryota*; Sakurai, Yu*; Kato, Koji*
Proceedings of 2016 ASME Pressure Vessels and Piping Conference (PVP 2016) (Internet), 8 Pages, 2016/07
A seismic isolation system composed of a thick rubber bearing and an oil damper has been developed for Sodium cooled Fast Reactor. One of the advantages of the isolation system is employing the thick rubber bearing in order to realize the longer vertical natural period of a plant, and it leads to mitigation of seismic loads to mechanical components. Rubber bearing technology has progressed based on many past studies, but test data regarding an aging effect is not enough. Also, there is no data of linear strain limit and breaking behavior for the thick rubber bearing after aging. This paper focuses on aging properties of the thick rubber bearing, such as basic mechanical properties and ultimate strength. An aging promote test of the thick rubber bearing was performed by using 1/2 scale and 1/8 scale rubber bearings. Aging of the rubber bearing was reproduced by thermal degradation, where the target aging period was 30 years and 60 years. The load deflection curves of the thick rubber bearing after aging were obtained through the horizontal and vertical static loading tests, and the aging effect was evaluated by comparing with the initial mechanical properties.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
Proceedings of 23rd International Conference on Nuclear Engineering (ICONE-23) (DVD-ROM), 8 Pages, 2015/05
Intergranular oxidation (corrosion) occurred within crevice of austenitic low-carbon stainless steel (solution treated, almost no applied stress) after immersion in high temperature water (288C, 8.5 MPa, dissolved oxygen conc. 32 ppm, electrical conductivity: 1.2
0.2
S (measured value at 25
C)) for 500 h. The intergranular oxidation occurred at specific position within the crevice that is relatively distant from the crevice mouth with relatively low crevice gap. Both the grain boundary and grain matrix were oxidized. In the oxidized area, Fe and Ni were depleted and Cr was enriched compared to the matrix. Maximum penetration depth of the oxidation was approximately 50
m after 500 h. In order to understand potential-pH condition within the crevice, surface oxide layer was microscopically and thermodynamically investigated. Thermodynamic properties of the surface oxides near the intergranular oxidized area indicated lowered pH of approximately 3.2 to 3.4. In-situ measurement of local solution electrical conductivity was carried out using small electrodes (dia. 800
m) imbedded into the crevice former plate. The solution pH was estimated using theoretically calculated pH vs. electrical conductivity relationship. In the area where the intergranular oxidation occurred, the solution electrical conductivity was nearly 100 times higher than that of bulk water and which indicated lowered pH of approximately 3.5. The above results suggested that, in the high temperature and relatively high purity water, acidification occurs within crevice of stainless steels and such aggressive corrosion condition result in the intergranular oxidation.
Soma, Yasutaka; Kato, Chiaki; Yamamoto, Masahiro
Corrosion, 70(4), p.366 - 374, 2014/04
Times Cited Count:10 Percentile:39.54(Materials Science, Multidisciplinary)Surface oxide layers were formed within crevices of type 316L stainless steels in pure water at 288C and 8 MPa. Cross-sectional structures of the surface oxides were analyzed using transmission electron microscopy. In the condition of dissolved oxygen concentration of 2 ppm, the properties of the surface oxide layer changed with position and dual or triplex layered oxides were formed at a certain distance from the crevice mouth. The multilayered oxides were composed of Fe-based oxide in the core and a high-Cr content in the outer layer, which had not been observed on a boldly exposed surface. On the contrary, in deaerated condition, the surface oxide layers were composed of a Fe
O
-based outer and a Cr-enriched inner oxide layer, regardless of the crevice position. Electrochemical condition within the crevice was identified by using E-pH diagram. It was suggested that, at 400
m distance from the crevice mouth, the potential lowered at the early stage of exposure and then, shifted to noble direction with decrement of pH. Consequently, even within a narrow crevice with a gap size of a few
m, the uniqueness of the crevice electrochemistry, characterized by the position and time dependence of both the potential and the pH, has been exhibited.
Soma, Yasutaka; Kato, Chiaki; Yamamoto, Masahiro
Journal of the Electrochemical Society, 159(8), p.C334 - C340, 2012/07
Times Cited Count:10 Percentile:30.22(Electrochemistry)Surface oxide layers on stainless steel were formed in 561 K pure water at different potentials. To understand the oxide's properties in terms of their potential dependence, cross-sectional views of the oxide layer were analyzed using an electron microprobe technique and potential-solubility (equilibrium concentration of ionic species) diagram. In the potential range investigated, duplex oxide layers composed of mono- and bimetallic oxide were formed. Both the structure and composition of the oxide layer were affected by solubility of oxides.
Soma, Yasutaka; Kato, Chiaki; Yamamoto, Masahiro
Materials Transactions, 53(1), p.195 - 200, 2012/01
Times Cited Count:10 Percentile:48.54(Materials Science, Multidisciplinary)Surface oxide layer on SUS316L stainless steels exposed to 288C pure water with 2ppm dissolved oxygen (DO) for 1
100h were analyzed using Focused Ion Beam and Scanning Transmission Electron Microscope equipped with EDS to understand the early stage of surface oxide layer formation. At 1h exposure, double oxide layer which is composed of compact inner oxide layer and outer oxide layer with Fe-rich and Ni-rich oxide particles was formed. At the outermost region of the SUS316L substrate, Ni and Cr were enriched. At 100h exposure, growth of the inner oxide layer was suppressed and the Ni and Cr enriched region at the alloy substrate was preserved underneath the Ni-rich outer oxide particles. At 1h exposure, most of the outer oxide particles were composed of Fe-rich ones, at 10h exposure, another Ni-rich outer oxide particles were nucleated and grew faster than Fe-rich ones. Consequently, a part of pre-formed Fe-rich outer oxide particles were covered with Ni-rich ones.
Soma, Yasutaka; Kato, Chiaki; Yamamoto, Masahiro
no journal, ,
Surface oxide layers on crevice of 316L stainless steels in high temperature and high pressure water containing 2ppm dissolved oxygen (DO) were investigated by using SEM, STEM, and Raman spectroscopy. Effects of distance from open-mouse of the crevices (Y) and corresponding DO concentration on surface oxide layer were studied. Depending on the Y value, four different regions with different surface oxide layer were observed if the crevice were sufficiently narrow. The oxide layers were consisted of inner and outer oxide layer at the all regions. Change in composition of outer oxide layer clearly showed that the DO concentration decreased with increasing Y value. However, thickness of the inner oxide layer showed maximum value at certain Y value and then, decreased with the Y value. This behavior considered to be brought by differences in the DO concentration, ionic concentration and pH.
Soma, Yasutaka; Kato, Chiaki; Yamamoto, Masahiro
no journal, ,
Surface oxide layers were formed within crevices of type 316L stainless steels in pure water at 561 K and 8 MPa. Cross-sectional structures of the surface oxides were analyzed using transmission electron microscopy. Under the condition of a dissolved oxygen concentration of 2 ppm, the properties of the surface oxide layer changed with the crevice position and dual or triplex layered oxides were formed, which had not been observed on a boldly exposed surface. The thickness of the inner oxide layer showed a local maximum at a certain distance from the crevice mouth. These oxide characteristics suggest the presence of locally varying electrochemical conditions. Potential-pH diagrams of the multilayered oxides suggest that the potential decreased at the early stage of exposure and then re-increased, accompanied by weak acidification.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
no journal, ,
Stress corrosion cracking (SCC) on stainless steels have been recognized as one of the most important corrosion-related failure in light water reactors. Many researches have been pointed out that the SCC advances under altered solution chemistry condition at the crack tip region compared to the bulk pure water. However, little works have been done to clarify degree of the alteration as function of bulk water condition, geometrical factor, and time. In this work, we carried out in-situ measurement of solution electrical conductivity within crevice of stainless steels. To create crevice specimen, a couple of stainless steel plate was fixed with bolts and nuts. Small sensors were imbedded into the crevice plate at three different positions with different crevice gaps. The crevice specimen with sensors was exposed to 288C water with pressure of 8 MPa, dissolved oxygen concentration of 32 ppm. The solution electrical conductivity at the crevice gap of 6e-5 m was almost same to that of bulk pure water. At the crevice position with 1e-5 m gap, the maximum conductivity value was nearly 1000 times higher than that of bulk water and that is equivalent to decrease in pH of 3 from the neutral value. This indicates, if the crevice gap was narrow enough, local acidification occurred at the tip of the crevice.
Soma, Yasutaka; Komatsu, Atsushi; Kato, Chiaki
no journal, ,
In this study, the effect of impurities in steel and ppb level of chloride in bulk water on electrical conductivity of stainless steel's crevice solution (K) has been studied. Crevice specimens were made of as-polished Type-316L stainless steel (standard-SS), standard-SS exposed to 60% nitric acid to dissolve sulfur containing inclusions (acid-picked SS), and 316EHP steel in which sulfur and phosphorous concentration was decreased compared to standard-SS (EHP-SS). These crevice specimens were immersed into 561 K, 8 MPa water the K values were measured as a function of time with stepwise increase in dissolved oxygen levels. In addition, effect of 50 ppb Cl added to bulk water was investigated using standard-SS crevice. The all of the standard-SS, acid-picked SS, and 316EHP showed similar K vs time curves. It can be concluded that impurities dissolved from the steel itself do not significantly contribute to the increase of K. The effect of 50 ppb Cl
on K vs time curve was obvious because maximum K value became more that 2 times larger than the solution without Cl
addition. This indicate that small concentration of impurities can be migrated into the crevice.
Kato, Atsushi; Negishi, Kazuo; Sato, Kenichiro*; Akiyama, Yo*; Hara, Hiroyuki*; Iwasaki, Mikinori*; Abe, Ganji*; Tokiyoshi, Takumi*; Okafuji, Takashi*; Umeki, Katsuhiko*; et al.
no journal, ,
Report research and development activities related to steel plate reinforced concrete containment vessel for the JSFR conducted as a part of METI commissioned research.
Soma, Yasutaka; Komatsu, Atsushi; Kato, Chiaki
no journal, ,
This study investigates the effects of potential (electrochemical corrosion potential (ECP)) on the water chemistry within a crevice of stainless steel in 288C water containing Cl
major anionic impurities. In situ measurements of the electrical conductivity of a solution within a 15
m gap crevice (
) were conducted using small sensors installed at different crevice depths. The ECP at the external surface of the crevice specimen (Eext) was controlled by the dissolved oxygen concentration in the bulk water. An increase in Eext from approximately -0.49 V (versus a standard hydrogen electrode at 288
C) to -0.12 V resulted in an increase in
from 12 to 160.3
S/cm at 21 mm from the crevice mouth. FEM analysis taking into account the electrochemical reaction quantitatively reproduced this behavior. Cl
was considered to be the major anionic species transported into the crevice in this potential range. A further increase in Eext up to 0.3 V led to a decline in
. An increase in the flux of oxidizing (O
and hydrochromate ion) and alkalizing species (OH
) into the crevice was considered the cause of this behavior.
Kato, Atsushi; Negishi, Kazuo; Hara, Hiroyuki*; Somaki, Takahiro*
no journal, ,
Japan Sodium-cooled Fast Reactor (JSFR) adopts a new concept of a containment vessel called steel plate reinforced concrete containment vessel (SCCV). The SCCV is considered to be effective to shorten construction schedule thanks for elimination of rebar work at a site compared with applying the reinforced concrete CV. JAEA has been investigating its characteristics under high thermal load to adopt the SC structure to a CV. This paper mainly describes the experimental study on SCCV bearing wall against lateral load.
Kato, Atsushi; Hara, Hiroyuki*; Takami, Shinji*; Somaki, Takahiro*
no journal, ,
Japan Sodium-cooled Fast Reactor (JSFR) adopts a new concept of a containment vessel called steel plate reinforced concrete containment vessel (SCCV). The SCCV is considered to be effective to shorten construction schedule thanks for elimination of rebar work at a site compared with applying the reinforced concrete CV. JAEA has been investigating its characteristics under high thermal load to adopt the SC structure to a CV. This paper mainly describes the experimental study on SCCV out-of-plane bending property.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
no journal, ,
Within crevice of austenitic stainless steel (solution treated, mirror poloshed) immersed in high-temperature water (561K, 8.5MPa, dissolved oxygen conc. 32ppm, conductivity ca.1 to 1.5e-6S/cm), new form of intergranular oxidation was occured. The intergranular oxidation occured in certain area within the crevice, that is, the area with relatively low crevice gap and distant from the crevice mouth. Cr was enriched in the oxide and the oxidation occured both grain boundary and grain matrix. After the intergranular oxidation, some grain was loosen and peered off. Maximum depth of the intergranular oxidation was 50e-6m/500h. Because almost no stress was applied on the specimen, relationship between this oxidation bahavior and stress corrosion cracking should be clarified by further experiment.