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Journal Articles

Field-induced insulator-metal transition in EuTe$$_2$$

Takeuchi, Tetsuya*; Honda, Fuminori*; Aoki, Dai*; Haga, Yoshinori; Kida, Takanori*; Narumi, Yasuo*; Hagiwara, Masayuki*; Kindo, Koichi*; Karube, Kosuke*; Harima, Hisatomo*; et al.

Journal of the Physical Society of Japan, 93(4), p.044708_1 - 044708_10, 2024/04

Journal Articles

Magnetic properties of single crystalline Tb$$_5$$Sb$$_3$$

Kitaori, Aki*; Kanazawa, Naoya*; Kida, Takanori*; Narumi, Yasuo*; Hagiwara, Masayuki*; Kindo, Koichi*; Takeuchi, Tetsuya*; Nakamura, Ai*; Aoki, Dai*; Haga, Yoshinori; et al.

Journal of the Physical Society of Japan, 92(2), p.024702_1 - 024702_6, 2023/02

 Times Cited Count:0 Percentile:0(Physics, Multidisciplinary)

Journal Articles

Spin excitations of the $$S$$=1/2 one-dimensional Ising-like antiferromagnet BaCo$$_{2}$$V$$_{2}$$O$$_{8}$$ in transverse magnetic fields

Okutani, Akira*; Onishi, Hiroaki; Kimura, Shojiro*; Takeuchi, Tetsuya*; Kida, Takanori*; Mori, Michiyasu; Miyake, Atsushi*; Tokunaga, Masashi*; Kindo, Koichi*; Hagiwara, Masayuki*

Journal of the Physical Society of Japan, 90(4), p.044704_1 - 044704_9, 2021/04

 Times Cited Count:3 Percentile:30.35(Physics, Multidisciplinary)

Journal Articles

Spin glass behavior in EuCu$$_2$$Si$$_2$$ single crystal grown by the flux method

Takeuchi, Tetsuya*; Haga, Yoshinori; Taniguchi, Toshifumi*; Iha, Wataru*; Ashitomi, Yosuke*; Yara, Tomoyuki*; Kida, Takanori*; Tahara, Taimu*; Hagiwara, Masayuki*; Nakashima, Miho*; et al.

Journal of the Physical Society of Japan, 89(3), p.034705_1 - 034705_15, 2020/03

 Times Cited Count:0 Percentile:0(Physics, Multidisciplinary)

Journal Articles

Effects of magnetic field and pressure on the valence-fluctuating antiferromagnetic compound EuPt$$_2$$Si$$_2$$

Takeuchi, Tetsuya*; Yara, Tomoyuki*; Ashitomi, Yosuke*; Iha, Wataru*; Kakihana, Masashi*; Nakashima, Miho*; Amako, Yasushi*; Honda, Fuminori*; Homma, Yoshiya*; Aoki, Dai*; et al.

Journal of the Physical Society of Japan, 87(7), p.074709_1 - 074709_14, 2018/07

 Times Cited Count:12 Percentile:64.96(Physics, Multidisciplinary)

Journal Articles

Electronic states in EuCu$$_2$$(Ge$$_{1-x}$$Si$$_x$$)$$_2$$ based on the doniach phase diagram

Iha, Wataru*; Yara, Tomoyuki*; Ashitomi, Yosuke*; Kakihana, Masashi*; Takeuchi, Tetsuya*; Honda, Fuminori*; Nakamura, Ai*; Aoki, Dai*; Gochi, Jun*; Uwatoko, Yoshiya*; et al.

Journal of the Physical Society of Japan, 87(6), p.064706_1 - 064706_14, 2018/06

 Times Cited Count:19 Percentile:75.67(Physics, Multidisciplinary)

Journal Articles

Synthesis of hexagonal boron carbonitride without nitrogen void defects

Mannan, M. A.*; Baba, Yuji; Kida, Tetsuya*; Nagano, Masamitsu*; Noguchi, Hideyuki*

Materials Sciences and Applications, 6(5), p.353 - 359, 2015/05

The synthesis and structure of hexagonal boron carbonitride (h-BCN) film on polycrystalline diamond surface were reported. Polycrystalline diamond and/or diamond-like carbon were first fabricated on Si (100) and then it was used as substrate. The deposition was performed by radio frequency plasma enhanced chemical vapor deposition. In order to reduce the content of nitrogen void defects, the deposition was performed at the high temperature of 950$$^{circ}$$C under the working pressure of 2.6 Pa. The typical sample with atomic composition of B$$_{31}$$C$$_{37}$$N$$_{26}$$O$$_{6}$$ in the h-BCN lattice was characterized by X-ray photoelectron spectroscopy. The fine structure of the film was studied by near-edge X-ray absorption fine structure (NEXAFS) measurements. The B K-edge and N K-edge of NEXAFS spectra revealed that the synthesized h-BCN film has the ideal honeycomb-like BN$$_{3}$$ configuration without nitrogen void defects.

Journal Articles

Hexagonal nano-crystalline BCN films grown on Si (100) substrate studied by X-ray absorption spectroscopy

Mannan, M. A.*; Baba, Yuji; Hirao, Norie; Kida, Tetsuya*; Nagano, Masamitsu*; Noguchi, Hideyuki*

Materials Sciences and Applications, 4(5A), p.11 - 19, 2013/05

Hexagonal nano-crystalline boron carbonitride (h-BCN) films grown on Si (100) substrate have been investigated. The films were synthesized by radio frequency plasma enhanced chemical vapor deposition using tris-dimethylamino borane as a precursor. Formation of the nano-crystalline h-BCN compound has been confirmed by X-ray diffraction analysis. The films composed of B, C, and N atoms with different B-N, B-C, C-N chemical bonds in forming the sp2-BCN atomic configuration studied by X-ray photoelectron spectroscopy. Orientation and local structures of the h-BCN hybrid were studied by near-edge X-ray absorption fine structure (NEXAFS) measurements. The dominant presence of $$pi$$$$^{*}$$ and $$sigma$$$$^{*}$$ resonance peaks of the sp2-hybrid orbitals in the B K-edge NEXAFS spectra revealed the formation of the flat sp2-BCN configuration around B atoms which are bound with three nitrogen atoms.

Journal Articles

Development of a magnetic sensor system for predictive IASCC diagnosis on stainless steels in a nuclear reactor

Nemoto, Yoshiyuki; Keyakida, Satoshi*; Uchimoto, Tetsuya*; Takaya, Shigeru; Tsukada, Takashi

International Journal of Applied Electromagnetics and Mechanics, 35(2), p.123 - 139, 2011/02

 Times Cited Count:1 Percentile:11.16(Engineering, Electrical & Electronic)JP, 2008-301850   Patent publication (In Japanese)

This paper presents a study conducted to develop a diagnostic system that can detect IASCC precursors in stainless steels by measuring the magnetic properties of the material. The eddy current method and alternating current (AC) magnetization method were used, as these will be more practical for use in actual reactors. Probes were developed for these measurement methods, providing sufficient tolerance for environments in nuclear reactors. An attempt was also made to improve spatial resolution by manufacturing a smaller probe. A sensor system was designed for remote control, performance tests were conducted by measuring neutron-irradiated specimens and mock specimens, and magnetic data were evaluated by comparing the IASCC susceptibility of the specimens. It was proved that the sensor system developed in this study is capable of detecting IASCC precursors. Further developments necessary for application in actual nuclear reactors and the mechanism of correlation between magnetic properties and IASCC susceptibility were also discussed.

Journal Articles

Orientation of B-C-N hybrid films deposited on Ni (111) and polycrystalline Ti substrates explored by X-ray absorption spectroscopy

Mannan, M. A.; Baba, Yuji; Kida, Tetsuya*; Nagano, Masamitsu*; Shimoyama, Iwao; Hirao, Norie; Noguchi, Hideyuki*

Thin Solid Films, 519(6), p.1780 - 1786, 2011/01

 Times Cited Count:19 Percentile:61.3(Materials Science, Multidisciplinary)

Orientation of BCN hybrid films synthesized on Ni (111) and Ti substrates by radio frequency plasma enhanced chemical vapor deposition has been investigated. Formation of the $$sp$$$$^{2}$$-BCN hybrids was confirmed by X-ray diffraction. Raman spectra also suggested the presence of graphite-like $$sp$$$$^{2}$$-BCN hybrid bonds. Orientation and local structures of the films were studied by the near-edge X-ray absorption fine structure (NEXAFS) measurements using synchrotron radiation. The B K-edge NEXAFS spectra revealed the preferred formation of the $$sp$$$$^{2}$$-BCN hybrid configuration around the B atoms like-BN$$_{3}$$ on Ni (111). It was revealed that the BCN film is parallel to the surface on Ni(111). On the other hand, the film is randomly oriented on Ti surface. It was suggested that the chemical reactivity of the metal surface affects the orientation of the BCN hybrid film.

Journal Articles

Evaluation of susceptibility to stress corrosion cracking based on non-linear eddy current method

Oikawa, Ryota*; Uchimoto, Tetsuya*; Takagi, Toshiyuki*; Urayama, Ryoichi*; Nemoto, Yoshiyuki; Takaya, Shigeru; Keyakida, Satoshi*

International Journal of Applied Electromagnetics and Mechanics, 33(3-4), p.1303 - 1308, 2010/10

 Times Cited Count:5 Percentile:35(Engineering, Electrical & Electronic)

This paper discusses feasibility of non-linear eddy current method to evaluate material degradations of austenitic stainless steels associated with irradiation assisted stress corrosion cracking (IASCC). For the purpose, tensile test at elevated temperature was conducted using model alloys simulating radiation induced segregation (RIS), then magnetization curve of the specimens was measured by vibrating sample magnetometer (VSM), and microstructure of magnetization was observed by magnetic force microscopy (MFM). Moreover non-linear eddy current method was carried out. It was shown that the 3rd higher harmonic ration of the pick-up signal would relate to nominal strain of the specimens.

Journal Articles

Growth and characterization of stoichiometric BCN films on highly oriented pyrolytic graphite by radiofrequency plasma enhanced chemical vapor deposition

Mannan, M. A.; Noguchi, Hideyuki*; Kida, Tetsuya*; Nagano, Masamitsu*; Hirao, Norie; Baba, Yuji

Thin Solid Films, 518(15), p.4163 - 4169, 2010/05

 Times Cited Count:30 Percentile:73.92(Materials Science, Multidisciplinary)

Hexagonal boron carbonitride (h-BCN) hybrid films have been synthesized on highly oriented pyrolytic graphite by radiofrequency plasma enhanced chemical vapor deposition using tris-(dimethylamino)borane as a single-source molecular precursor. The films were characterized by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopic measurements. XPS measurement showed that the B atoms were bonded to C and N atoms to form the $$sp$$$$^{2}$$ BCN hybrid chemical environment. The atomic composition estimated from the XPS of the typical sample was found to be almost B1C1N1. NEXAFS spectra of the B K-edge and the N K-edge had the peaks due to the $$pi$$$$^{*}$$ and $$sigma$$$$^{*}$$ resonances of $$sp$$$$^{2}$$ hybrid orbitals implying the existence of the $$sp2$$ hybrid configurations of h-BCN around the B atoms.

Journal Articles

Synthesis of boron carbonitride (BCN) films by plasma-enhanced chemical vapor deposition using trimethylamine borane as a molecular precursor

Kida, Tetsuya*; Shigezumi, Kazuya*; Mannan, M. A.*; Akiyama, Morito*; Baba, Yuji; Nagano, Masamitsu*

Vacuum, 83(8), p.1143 - 1146, 2009/05

 Times Cited Count:15 Percentile:51.83(Materials Science, Multidisciplinary)

Boron carbonitride films were deposited on Si substrates by plasma-enhanced chemical vapor deposition using a powdered precursor of trimethylamine borane. The effect of using different carrier gasses and microwave powers was investigated. Field emission scanning electron microscopy revealed that the films have a nanofibrous structure with elongated features 20 nm in diameter and 200 nm in length. Fourier transfer infrared spectroscopy was used to investigate chemical bonding states present in the deposited films. The FT-IR results suggested that the films have multiple chemical bonding states including C-N, B-N, and B-C bonds, as well as oxygen incorporation in the form of B-O bonds. Mixing the powdered precursor with molecular sieve was found to reduce the oxygen content in the films by removing surface adsorbed water from the precursor.

Journal Articles

Atomic arrangement, composition and orientation of hexagonal BCN films synthesized by radiofrequency plasma enhanced CVD

Mannan, M. A.*; Kida, Tetsuya*; Noguchi, Hideyuki*; Nagano, Masamitsu*; Shimoyama, Iwao; Hirao, Norie; Baba, Yuji

Journal of the Ceramic Society of Japan, 117(1364), p.503 - 507, 2009/04

 Times Cited Count:11 Percentile:53.79(Materials Science, Ceramics)

Oriented hexagonal BCN films were synthesized on Si(100) substrate by radiofrequency plasma enhanced chemical vapor deposition using tris-(dimethylamino)borane as a precursor. The formation of the crystalline hexagonal BCN hybrids was confirmed by FT-IR and XRD. CH$$_{4}$$ + H$$_{2}$$ carrier gas increased the C content in the films in comparison with N$$_{2}$$ carrier gas. XPS measurement showed that the films were composed of a variety of B-N, B-C, C-N bonds to form the BCN atomic hybrids. The $$pi$$$$^{*}$$ resonance peak in the B K-edge NEXAFS spectra also indicated the presence of the ${it sp$^{2}$}$ hybrid configuration of B-C-N bonds like BN$$_{3}$$ in h-BN. The $$sigma$$$$^{*}$$ resonance peaks suggested the diversity in the $$sigma$$ bonds in the films. Orientation of the h-BCN hybrids was suggested on the basis of the polarization dependence of NEXAFS.

Journal Articles

Material deterioration diagnosis of austenite stainless steel by measurement of leakage magnetic flux density

Takaya, Shigeru; Nemoto, Yoshiyuki; Uchimoto, Tetsuya*; Keyakida, Satoshi*

Nihon AEM Gakkai-Shi, 17(1), p.156 - 161, 2009/03

In a previous study, authors showed experimentally the correlation between leakage magnetic flux density and irradiation assisted stress corrosion cracking susceptibility of high purity model austenitic stainless steels. This study aimed to investigate mechanism of the correlation. Tensile test at elevated temperature and aging test were conducted on materials simulating irradiation-induced segregation, and leakage magnetic flux density was measured before and after these tests in order to study the influence of chemical composition change and lattice defect to leakage magnetic flux density. Furthermore, dependency of magnetic moment on chemical composition and vacancy was evaluated by first principle calculation. As result, it was shown that leakage magnetic flux density of irradiated materials is thought to increase in severe irradiation-induced segregation region with and without vacancy.

Journal Articles

A Study of correlativity between IASCC susceptibility and magnetic property of stainless steel

Nemoto, Yoshiyuki; Keyakida, Satoshi*; Uchimoto, Tetsuya*; Takaya, Shigeru; Tsukada, Takashi

Hozengaku, 7(4), p.57 - 68, 2009/01

Authors previously reported leakage magnetic flux density measured by flux gate (FG) sensor seems to depend on irradiation assisted stress corrosion cracking (IASCC) susceptibility of neutron irradiated austenitic stainless steels. This study aimed to evaluate possibility to develop diagnostic method to detect symptom of IASCC by more practical methods such as Eddy current method and AC magnetization method. Magnetic properties of neutron irradiated specimens and mockup specimens were studied and dependence on IASCC susceptibility was revealed. Microstructure observation using transmission electron microscope (TEM) was conducted to study magnetic phase formation by radiation induced segregation. It was shown that measurement of magnetic signal changed by magnetic phase formation along grain boundaries caused by radiation induced segregation would be a mechanism of the diagnostic method to detect symptom of IASCC.

Journal Articles

Characterization of BCN films synthesized by radiofrequency plasma enhanced chemical vapor deposition

Mannan, M. A.*; Nagano, Masamitsu*; Kida, Tetsuya*; Hirao, Norie; Baba, Yuji

Journal of Physics and Chemistry of Solids, 70(1), p.20 - 25, 2009/01

 Times Cited Count:50 Percentile:83.99(Chemistry, Multidisciplinary)

Boron carbonitride (BCN) films have been synthesized on Si(100) substrate by radio frequency plasma enhanced chemical vapor deposition using Tris-(dimethylamino)borane (TDMAB) as a precursor. The formation of the sp$$^{2}$$-bonded BCN phase was confirmed by Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy measurements showed that B atoms were bonded to C and N atoms to form the BCN atomic hybrid configurations. Near-edge X-ray absorption fine structure measurements indicated that B atoms were bonded not only to N atoms but also to C atoms to form various configurations of sp$$^{2}$$-BCN atomic hybrids. The polarization-dependence of NEXAFS suggested that the predominant hybrid configuration of sp$$^{2}$$-BCN films oriented in the direction perpendicular to the Si substrate.

Journal Articles

Chemical bonding states and local structures of the oriented hexagonal BCN films synthesized by microwave plasma CVD

Mannan, M. A.; Noguchi, Hideyuki*; Kida, Tetsuya*; Nagano, Masamitsu*; Hirao, Norie; Baba, Yuji

Materials Science in Semiconductor Processing, 11(3), p.100 - 105, 2008/06

 Times Cited Count:24 Percentile:72.81(Engineering, Electrical & Electronic)

In order to synthesize oriented hexagonal boron carbonitride (h-BCN) films, borane-triethylamine complex was used as a single-source precursor. The films were deposited on Si(100) substrate by microwave plasma-enhanced chemical-vapor deposition using CH$$_{4}$$+H$$_{2}$$ as the carrier gas. Fourier transform infrared spectroscopy (FT-IR) confirmed the formation of hexagonal BCN phase in a short-range order. The chemical composition and the local structures of films were studied by X-ray photoelectron spectroscopy (XPS) and the near-edge X-ray absorption fine structure (NEXAFS) spectroscopic measurements. The NEXAFS measurement suggested that the B atoms are bonded not only to the N atoms but also to the C atoms to form various local structures of sp$$^{2}$$ B-C-N hybrid configurations. The polarization dependence of NEXAFS suggested that the local structures of the sp$$^{2}$$ BCN layers have different atomic orientations to the substrate.

Journal Articles

Characterization of boron carbonitride (BCN) thin films deposited by radiofrequency and microwave plasma enhanced chemical vapor deposition

Mannan, M. A.*; Nagano, Masamitsu*; Shigezumi, Kazuya*; Kida, Tetsuya*; Hirao, Norie*; Baba, Yuji

American Journal of Applied Sciences, 5(6), p.736 - 741, 2008/00

Boron carbonitride thin films with a thickness of 4 micrometer were synthesized on Si(100) substrate by radiofrequency and microwave plasma enhanced vapor deposition using trimethylamine boran as a precursor. It has bee observed that the films were adhered well to the silicon substrate even after being broken mechanically. X-ray diffraction (XRD) and filed emission scanning electron microscopy (FE-SEM) results showed that the films were amorphous and the surface was rough with inhomogeneous microstructure. On the basis of the X-ray photoelectron spectra (XPS), it was elucidated that B, C and N atoms have different chemical bonds such as B-N, B-C and C-N.

Journal Articles

Plasma enhanced chemical vapor deposition of B-C-N films

Mannan, M. A.*; Kida, Tetsuya*; Nagano, Masamitsu*; Hirao, Norie*; Baba, Yuji

Advanced Ceramic Processing International, 3(1), p.51 - 54, 2006/11

B-C-N hybrid thin films were synthesized by plasma enhanced chemical vapor deposition using liquid organic molecules (tris-dimethylamine borane and trimethylamine borane) as molecular precursors. The Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy investigations suggest that the films are composed of hybridized boron, carbon and nitrogen atoms. The X-ray diffraction and field emission scanning electron microscopy investigations reveal that the films are almost amorphous and have micro-structure at 4.2-4.5 $$mu$$m. The micro-hardness of the as-deposited B-C-N films is found to be approximately 2-7 Gpa. It was concluded that the plasma enhanced chemical vapor deposition using the present organic molecules are suited for the synthesis of B-C-N hybrid thin films.

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