Suppression of segmental chain dynamics on a particle's surface in well-dispersed polymer nanocomposites

Kim, J.*; Thompson, B. R.*; Tominaga, Taiki*; Osawa, Takahito; Egami, Takeshi*; Frster, S.*; Ohl, M.*; Senses, E.*; Faraone, A.*; Wagner, N. J.*

ACS Macro Letters (Internet), 13(6), p.720 - 725, 2024/06

https://doi.org/10.1021/acsmacrolett.4c00168

The Rouse dynamics of polymer chains in model nanocomposite PolyEthylene Oxide (PEO)/Silica NanoParticles (NPs) was investigated using QuasiElastic Neutron Scattering (QENS). The apparent Rouse rate of the polymer chains decreases as the particle loading increases. However, there is no evidence of an immobile segment population on the probed time scale of tens of ps. The slowing down of the dynamics is interpreted in terms of modified Rouse models for the chains in the NP inter-phase region. Thus, two chain populations, one bulk like and the other characterized by a suppression of Rouse modes, are identified. The spatial extent of the interphase region is estimated to be about twice the adsorbed layer thickness, or about 2 nm. These findings provide a detailed description of the suppression of the chain dynamics on the surface of NPs. These results are relevant insights on surface effects and confinement and provide a foundation for the understanding of the rheological properties of Polymer NanoComposites (PNCs) with well-dispersed NPs.

CSNI leak-before-break benchmark; Summary of phase 1

Tregoning, R.*; Wallace, J.*; Bouydo, A.*; Costa-Garrido, O.*; Dillstrm, P.*; Duan, X.*; Heckmann, K.*; Kim, Y.-B.*; Kim, Y.*; Kurth-Twombly, E.*; et al.

Transactions of the 26th International Conference on Structural Mechanics in Reactor Technology (SMiRT-26) (Internet), 11 Pages, 2022/07

Fourteen organizations, representing eleven countries, participated in a leak-before-break (LBB) benchmark exercise that compared results from analyses among participating countries and identified the effects of weld residual stress (WRS) and crack morphology on crack opening displacement (COD), critical bending moment (CBM), and leak rate (LR) results. The participants determined whether the initial problem would meet their country's LBB acceptance criteria and then evaluated the effects of crack morphology and WRS for a prescribed crack size, geometry and loading. Six out of fourteen participants indicated that the initial problem met their LBB requirements. In the follow-on tasks, differences among the participant's CBM predictions were principally due to the material properties used in the analysis while the type of failure model chosen contributed much less. Most of the differences in the LR predictions were directly attributable to differences among the COD models, but a portion was attributable to the treatment of crack face pressure (CFP). The benchmark identified several aspects of an LBB analysis that could support a more realistic evaluation.

Development of negative muonium ion source for muon acceleration

Kitamura, Ryo; Bae, S.*; Choi, S.*; Fukao, Yoshinori*; Iinuma, Hiromi*; Ishida, Katsuhiko*; Kawamura, Naritoshi*; Kim, B.*; Kondo, Yasuhiro; Mibe, Tsutomu*; et al.

Physical Review Accelerators and Beams (Internet), 24(3), p.033403_1 - 033403_9, 2021/03

https://doi.org/10.1103/PhysRevAccelBeams.24.033403

A negative muonium ion (Mu) source using an aluminum foil target was developed as a low-energy muon source. An experiment to produce Mu ions was conducted to evaluate the performance of the Mu ion source. The measured event rate of Mu ions was Mu/s when the event rate of the incident muon beam was /s. The formation probability, defined as the ratio of the Mu ions to the incident muons on the Al target, was . This Mu ion source boosted the development of the muon accelerator, and the practicality of this low-energy muon source obtained using a relatively simple apparatus was demonstrated.

Plastic collapse stresses based on flaw combination rules for pipes containing two circumferential similar flaws

Hasegawa, Kunio; Li, Y.; Kim, Y.-J.*; Lacroix, V.*; Strnadel, B.*

Journal of Pressure Vessel Technology, 141(3), p.031201_1 - 031201_5, 2019/06

https://doi.org/10.1115/1.4042991

When discrete multiple flaws are in the same plane, and they are close to each other, it can be determined whether they are combined or standalone in accordance with combination rules provided by Fitness-For-Service (FFS) codes. However, specific criteria of the rules are different amongst these FFS codes. On the other hand, plastic collapse bending stresses for stainless steel pipes with two circumferential similar flaws were obtained by experiments and the prediction procedure for collapse stresses for pipes with two similar flaws were developed analytically. Using the experimental data and the analytical procedure, plastic collapse stresses for pipes with two similar flaws are compared with the stresses in compliance with the flaw combination criteria. It is shown that the calculated plastic collapse stresses based on the flaw combination criteria are significantly different from the experimental and analytical stresses.

Search for violation with kinematic asymmetries in the decay

Kim, J. B.*; Tanida, Kiyoshi; Belle Collaboration*; 182 of others*

Physical Review D, 99(1), p.011104_1 - 011104_7, 2019/01

AA2019-0534.pdf:0.39MB

https://doi.org/10.1103/PhysRevD.99.011104

Laboratory examination of greenhouse gaseous and microbial dynamics during thawing of frozen soil core collected from a black spruce forest in Interior Alaska

Nagano, Hirohiko; Kim, Y.*; Lee, B.-Y.*; Shigeta, Haruka*; Inubushi, Kazuyuki*

Soil Science and Plant Nutrition, 64(6), p.793 - 802, 2018/12

https://doi.org/10.1080/00380768.2018.1525267

In this study, we conducted an incubation experiment on a frozen soil core collected from a black spruce forest in Interior Alaska, in order to investigate potential changes in greenhouse gaseous (GHG) and microbial dynamics during thawing of frozen soil. The soil thawing is an important environmental process determining the annual GHG balance in the northern high-latitude ecosystem. A core spanning the ground surface to upper permafrost with a depth of 90 cm was vertically grouped into three layers (top, middle, and bottom layers). Then, 12 soil samples from 3 layers (i.e., 4 soil samples per layer) were incubated for 3 weeks, and net carbon dioxide (Co) and methane (CH) release/uptake rates were estimated. During the incubation, temperature was changed weekly from 0 to 5, then 10C. The net amounts of CO released by six of the eight soil samples from the top and middle layers were 1.5 to 19.2-fold greater at 5C than at 0C, while the release at 10C was reduced in the cases of three of these six soil samples. Net CH release was the greatest in bottom-layer soil samples incubated at 0C. Then, low but apparent CH release was observed in top and middle-layer soil samples incubated at 0C. At 5 and 10C, net CH release from bottom-layer soil samples was decreased. Then, net CH uptake was observed in the top and the middle-layer soil samples. Both net uptake and release of CH were reduced upon the addition of a chemical inhibitor (i.e., 2-bromoethane sulfonate) of anaerobic methanotrophic and methanogenic activity. The bacterial and archaeal community structures based on 16S rRNA amplicon analysis were changed along the depth, while they were less changed during thawing. Thus, it was found that soil GHG dynamics responded sensitively and variously to thawing, while there was less change in 16S rRNA-based microbial community structures during the thawing prog

Result of the first muon acceleration with radio frequency quadrupole

Kitamura, Ryo*; Otani, Masashi*; Fukao, Yoshinori*; Futatsukawa, Kenta*; Kawamura, Naritoshi*; Mibe, Tsutomu*; Miyake, Yasuhiro*; Yamazaki, Takayuki*; Kondo, Yasuhiro; Hasegawa, Kazuo; et al.

Proceedings of 9th International Particle Accelerator Conference (IPAC '18) (Internet), p.1190 - 1193, 2018/06

https://doi.org/10.18429/JACoW-IPAC2018-TUPAL076

Muon acceleration using radio-frequency accelerators makes it possible to precisely measure the muon anomalous magnetic moment and the electric dipole moment. The first muon acceleration was demonstrated using a radio-frequency quadrupole (RFQ) linac. A negative muonium ion (Mu) with less than 2 keV energy was produced from an incident muon with 3 MeV energy using a thin aluminum foil target in order to cool the muon beam for the acceleration, because the designed input energy of the RFQ is 5.6 keV. The Mu was first accelerated to 5.6 keV using an electrostatic accelerator, and was subsequently accelerated to 90 keV using the RFQ. This accelerated Mu was selected using a diagnostic beam line and was identified based on Time-Of-Flight measurements.

Current preparation and prospects of the muon acceleration test with RFQ in J-PARC

Kitamura, Ryo*; Otani, Masashi*; Kondo, Yasuhiro; Bae, S.*; Choi, S.*; Fukao, Yoshinori*; Futatsukawa, Kenta*; Hasegawa, Kazuo; Iinuma, Hiromi*; Ishida, Katsuhiko*; et al.

Proceedings of 14th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.100 - 103, 2017/12

Muon acceleration is an important technique in exploring the new frontier of physics. A new measurement of the muon dipole moments is planned in J-PARC using the muon linear accelerator. The low-energy (LE) muon source using the thin metal foil target and beam diagnostic system were developed for the world's first muon acceleration. Negative muonium ions from the thin metal foil target as the LE muon source was successfully observed. Also the beam profile of the LE positive muon was measured by the LE-dedicated beam profile monitor. The muon acceleration test using a Radio-Frequency Quadrupole linac (RFQ) is being prepared as the first step of the muon accelerator development. In this paper, the latest status of the first muon acceleration test is described.

Studies of high density baryon matter with high intensity heavy-ion beams at J-PARC

Sako, Hiroyuki; Harada, Hiroyuki; Sakaguchi, Takao*; Chujo, Tatsuya*; Esumi, Shinichi*; Gunji, Taku*; Hasegawa, Shoichi; Hwang, S.; Ichikawa, Yudai; Imai, Kenichi; et al.

Nuclear Physics A, 956, p.850 - 853, 2016/12

https://doi.org/10.1016/j.nuclphysa.2016.03.030

Evaluation of large 3600 MWth sodium-cooled fast reactor OECD neutronic benchmarks

Buiron, L.*; Rimpault, G*; Fontaine, B.*; Kim, T. K.*; Stauff, N. E.*; Taiwo, T. A.*; Yamaji, Akifumi*; Gulliford, J.*; Fridmann, E.*; Pataki, I.*; et al.

Proceedings of International Conference on the Physics of Reactors; The Role of Reactor Physics toward a Sustainable Future (PHYSOR 2014) (CD-ROM), 16 Pages, 2014/09

Within the activities of the Working Party on Scientific Issues of Reactor Systems (WPRS) of the OECD, an international collaboration is ongoing on the neutronic analyses of several Generation-IV Sodium-cooled Fast Reactor (SFR) concepts. This paper summarizes the results obtained by participants from institutions of different countries (ANL, CEA, ENEA, HZDR, JAEA, CER, KIT, UIUC) for the large core numerical benchmarks. These results have been obtained using different calculation methods and analysis tools to estimate the core reactivity and isotopic composition evolution, neutronic feedbacks and power distribution. For the different core concepts analyzed, a satisfactory agreement was obtained between participants despite the different calculation schemes used. A good agreement was generally obtained when comparing compositions after burnup, the delayed neutron fraction, the Doppler coefficient, and the sodium void worth. However, some noticeable discrepancies between the k-effective values were observed and are explained in this paper. These are mostly due to the different neutronic libraries employed (JEFF3.1, ENDFB7.0 or JENDL-4.0) and to a lesser extent the calculations methods.