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Journal Articles

Investigation of nano porous SiC based fibers synthesized by precursor method

Kita, Kenichiro; Narisawa, Masaki*; Nakahira, Atsushi*; Mabuchi, Hiroshi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

Advances in Polymer Derived Ceramics and Composites; Ceramic Transactions, Vol.213, p.45 - 50, 2010/06

Journal Articles

Synthesis and properties of ceramic fibers from polycarbosilane/polymethylphenylsiloxane polymer blends

Kita, Kenichiro; Narisawa, Masaki*; Nakahira, Atsushi*; Mabuchi, Hiroshi*; Sugimoto, Masaki; Yoshikawa, Masahito

Journal of Materials Science, 45(13), p.3397 - 3404, 2010/04

 Times Cited Count:11 Percentile:34.92(Materials Science, Multidisciplinary)

We synthesized ceramic fibers based on silicon carbide (SiC) from polymer blends of polycarbosilane (PCS) and polymethylphenylsiloxane (PMPhS). PMPhS was compatible with PCS up to 30 mass%. The polymer blend was formed a transparent melt at temperatures higher than 513 K and the softening point was also lowered by adding PMPhS. 15 mass% of PMPhS to PCS was the most suitable condition for obtaining thin fibers with an average diameter of 14.4 $$mu$$m and the ceramic yield of the cured fiber was 85.5% after pyrolysis at 1273 K. In spite of the small diameter, the resulting tensile strength at 1273 K was rather limited at 0.78 GPa. After high temperature pyrolysis at 1673$$sim$$1773 K, a porous nanocrystalline SiC fiber with a unique microstructure was obtained with surface area of 70$$sim$$150 m$$^{2}$$/g.

Journal Articles

High-temperature pyrolysis of ceramic fibers derived from polycarbosilane-polymethylhydrosiloxane polymer blends with porous structures

Kita, Kenichiro; Narisawa, Masaki*; Nakahira, Atsushi*; Mabuchi, Hiroshi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

Journal of Materials Science, 45(1), p.139 - 145, 2010/01

 Times Cited Count:12 Percentile:37.22(Materials Science, Multidisciplinary)

The polymer blends of polycarbosilane (PCS) and polymethylohydrosiloxane with high molecular weight (PMHS-h) were prepared by freeze-drying process. Melt viscosity, themogravimetric analysis, and gas evolution from the polymer blends were analyzed. The polymer blend of HSah15 (15 mass% PMHS-h to PCS) was melt-spun to fiber form, curing by thermal oxidation and pyrolyzed at various temperatures up to 1773 K. The fibers were investigated by tensile tests, FE-SEM observation, and XRD (X-ray diffraction) analysis. After pyrolysis at 1273 K, there were amounts of pores in the cross sections of the fiber derived from HSah15, and after pyrolysis at 1773 K, no remarkable $$beta$$-SiC crystal were formed on the outside surface of the fiber derived from HSah15.

Journal Articles

Formation of continuous pore structures in Si-C-O fibers by adjusting the melt spinning condition of a polycarbosilane - polysiloxane polymer blend

Kita, Kenichiro; Narisawa, Masaki*; Mabuchi, Hiroshi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

Journal of the American Ceramic Society, 92(6), p.1192 - 1197, 2009/06

 Times Cited Count:13 Percentile:58.1(Materials Science, Ceramics)

Journal Articles

Synthesis of SiC based fibers with continuous pore structure by melt-spinning and controlled curing method

Kita, Kenichiro; Narisawa, Masaki*; Mabuchi, Hiroshi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

Advanced Materials Research, 66, p.5 - 8, 2009/04

 Times Cited Count:4 Percentile:81.79(Materials Science, Multidisciplinary)

Journal Articles

Effects of electron irradiation on CuInS$$_{2}$$ crystals

Abe, Kenichiro*; Miyoshi, Yoshihiro*; Ashida, Atsushi*; Wakita, Kazuki*; Oshima, Takeshi; Morishita, Norio; Kamiya, Tomihiro; Watase, Seiji*; Izaki, Masanobu*

Japanese Journal of Applied Physics, 44(1B), p.718 - 721, 2005/01

 Times Cited Count:1 Percentile:4.7(Physics, Applied)

no abstracts in English

Oral presentation

Ion radiation effect of chemical bonding on CuInS$$_{2}$$ crystals

Murakami, Go*; Abe, Kenichiro*; Ashida, Atsushi*; Wakita, Kazuki*; Watase, Seiji*; Izaki, Masanobu*; Oshima, Takeshi; Morishita, Norio; Ito, Hisayoshi

no journal, , 

no abstracts in English

Oral presentation

The Possibility of synthesis of SiC based micro tube through precursor method

Kita, Kenichiro; Narisawa, Masaki*; Mabuchi, Hiroshi*; Sugimoto, Masaki; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

Control of polymer precursor process for micro-sized and nano-sized hole structure formation in SiC based fibers by irradiation curing

Kita, Kenichiro; Narisawa, Masaki*; Mabuchi, Hiroshi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

Synthesis and investigation of SiC based fine fiber by polymethylphenylsiloxane

Kita, Kenichiro; Narisawa, Masaki*; Mabuchi, Hiroshi*; Sugimoto, Masaki; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

Synthesis and formation control of porous ceramics by the using of polysiloxane

Kita, Kenichiro; Narisawa, Masaki*; Nakahira, Atsushi*; Ito, Masayoshi*; Sugimoto, Masaki; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

SiC microtubes or porous fibers derived from polycarbosilane modified with liquid polysiloxanes

Narisawa, Masaki*; Kita, Kenichiro*; Sugimoto, Masaki; Yoshikawa, Masahito

no journal, , 

no abstracts in English

12 (Records 1-12 displayed on this page)
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