Multi-modal 3D image-based simulation of hydrogen embrittlement crack initiation in Al-Zn-Mg alloy

Higa, Ryota*; Fujihara, Hiro*; Toda, Hiroyuki*; Kobayashi, Masakazu*; Ebihara, Kenichi; Takeuchi, Akihisa*

Keikinzoku, 73(11), p.530 - 536, 2023/11

https://doi.org/10.2464/jilm.73.530

In Al-Zn-Mg alloys, suppression of hydrogen embrittlement is necessary to improve their strength. In this study, the distribution of stress, strain, and hydrogen concentration in the actual fracture region was investigated using the crystal plasticity finite element method and hydrogen diffusion analysis based on a model derived from three-dimensional polycrystalline microstructural data obtained by X-ray CT. In addition, the distributions of stress, strain, and hydrogen concentration were compared with the actual crack initiation behavior by combining in-situ observation of tensile tests using X-ray CT and simulation. The results show that stress loading perpendicular to the grain boundary due to crystal plasticity dominates grain boundary crack initiation. It was also found that internal hydrogen accumulation due to crystal plasticity has little effect on crack initiation.

Energy dissipation of para-positronium in polymers and silica glass

Kobayashi, Yoshinori*; Sato, Kiminori*; Yamawaki, Masato*; Michishio, Koji*; Oka, Toshitaka; Washio, Masakazu*

Applied Physics Express, 15(7), p.076001_1 - 076001_4, 2022/07

https://doi.org/10.35848/1882-0786/ac7c54

We discuss the energy dissipation of short-lived -positronium (-Ps) in polymers and silica glass. The parameter characterizing the Doppler broadening of -Ps annihilation is determined from the previously reported systematic data of positron annihilation age momentum correlation for various polymers and silica glass. A comparison of the parameter with that expected for thermalized -Ps trapped in a free volume reveals that -Ps is not thermalized and possesses excess energy in fluorinated polymers and silica glass, indicating that it is difficult for Ps to lose energy in substances containing heavy elements such as fluorine and silicon.

Verification of alternative dew point hygrometer for CV-LRT in MONJU; Short- and long-term verification for capacitance-type dew point hygrometer (Translated document)

Ichikawa, Shoichi; Chiba, Yusuke; Ono, Fumiyasu; Hatori, Masakazu; Kobayashi, Takanori; Uekura, Ryoichi; Hashiri, Nobuo*; Inuzuka, Taisuke*; Kitano, Hiroshi*; Abe, Hisashi*

JAEA-Research 2017-001, 40 Pages, 2017/03

JAEA-Research-2017-001.pdf:5.19MB

In order to reduce the influence on a plant schedule of the MONJU by the maintenance of dew point hygrometers, The JAEA examined a capacitance type dew point hygrometer as an alternative dew point hygrometer for a lithium-chloride type dew point hygrometer which had been used at the CV-LRT in the MONJU. As a result of comparing a capacitance type dew point hygrometer with a lithium-chloride type dew point hygrometer at the CV-LRT (Atmosphere: nitrogen, Testing time: 24 hours), there weren't significant difference between a capacitance type dew point hygrometer and a lithium-chloride type dew point hygrometer. As a result of comparing a capacitance dew point hygrometer with a high-mirror-surface type dew point hygrometer for long term verification (Atmosphere: air, Testing time: 24 months), the JAEA confirmed that a capacitance type dew point hygrometer satisfied the instrument specification (2.04C) required by the JEAC4203-2008.

Technical estimation for mass production of highly-concentrated Tc solution from Mo to be obtained by () reaction; A Preliminary study using inactive Re instead of Tc

Tanase, Masakazu*; Fujisaki, Saburo*; Ota, Akio*; Shiina, Takayuki*; Yamabayashi, Hisamichi*; Takeuchi, Nobuhiro*; Tsuchiya, Kunihiko; Kimura, Akihiro; Suzuki, Yoshitaka; Ishida, Takuya; et al.

Radioisotopes, 65(5), p.237 - 245, 2016/05

https://doi.org/10.3769/radioisotopes.65.237

no abstracts in English

Establishment of experimental system for Mo/Tc production by neutron activation method

Ishida, Takuya; Shiina, Takayuki*; Ota, Akio*; Kimura, Akihiro; Nishikata, Kaori; Shibata, Akira; Tanase, Masakazu*; Kobayashi, Masaaki*; Sano, Tadafumi*; Fujihara, Yasuyuki*; et al.

JAEA-Technology 2015-030, 42 Pages, 2015/11

JAEA-Technology-2015-030.pdf:4.82MB

The research and development (R&D) on the production of Mo/Tc by neutron activation method ((n, ) method) using JMTR has been carried out in the Neutron Irradiation and Testing Reactor Center. The specific radioactivity of Mo by (n, ) method is extremely low compared with that by fission method ((n,f) method), and as a result, the radioactive concentration of the obtained Tc solution is also lowered. To solve the problem, we propose the solvent extraction with methyl ethyl ketone (MEK) for recovery of Tc from Mo produced by (n, ) method. We have developed the Mo/Tc separation/extraction/concentration devices and have carried out the performance tests for recovery of Tc from Mo produced by (n, ) method. In this paper, in order to establish an experimental system for Mo/Tc production, the R&D results of the system are summarized on the improvement of the devices for high-recovery rate of Tc, on the dissolution of the pellets, which is the high-density molybdenum trioxide (MoO) pellets irradiated in Kyoto University Research Reactor (KUR), on the production of Tc, and on the inspection of the recovered Tc solutions.

Mo-Tc production process by (n,) reaction with irradiated high-density MoO pellets

Tsuchiya, Kunihiko; Nishikata, Kaori; Tanase, Masakazu*; Shiina, Takayuki*; Ota, Akio*; Kobayashi, Masaaki*; Yamamoto, Asaki*; Morikawa, Yasumasa*; Takeuchi, Nobuhiro*; Kaminaga, Masanori; et al.

Proceedings of 6th International Symposium on Material Testing Reactors (ISMTR-6) (Internet), 9 Pages, 2013/10

http://www.invap.com.ar/ismtr/images/stories/trabajos/Tsuchiya-Paper.pdf

http://www.invap.com.ar/ismtr/images/stories/trabajos/Tsuchiya-Presentation.pdf

no abstracts in English

Development of Tc production from (n, ) Mo

Tanase, Masakazu*; Shiina, Takayuki*; Kimura, Akihiro; Nishikata, Kaori; Fujisaki, Saburo*; Ota, Akio*; Kobayashi, Masaaki*; Yamamoto, Asaki*; Kawauchi, Yukimasa*; Tsuchiya, Kunihiko; et al.

Proceedings of 5th International Symposium on Material Testing Reactors (ISMTR-5) (Internet), 9 Pages, 2012/10

http://www.murr.missouri.edu/ismtr/papercall/Papers/Chiyoda%20Technol/Tanase_M=PAPER_Dev%20of%20Tc99m%20Prod%20from%20n-g%20Mo99.pdf

Tc is used as a radiopharmaceutical and manufactured from the parent nuclide of Mo. Extraction method of Tc from (n, ) Mo have been developed, as a part of the industrial use expansion after JMTR will re-start. In this research, the method proposed would be applicable to a practical production of Tc obtained from (n, ) Mo in large quantities. The method proposed would be applicable to a practical production of Tc obtained from (n, ) Mo in large quantities.

Analysis of relaxation times of radicals in irradiated black pepper using pulse-ESR and CW-ESR

Kameya, Hiromi*; Kikuchi, Masahiro; Todoriki, Setsuko*; Furuta, Masakazu*; Kobayashi, Yasuhiko; Hara, Hideyuki*; Shimoyama, Yuhei; Ukai, Mitsuko*

Shokuhin Shosha, 47(1), p.6 - 10, 2012/09

https://doi.org/10.5986/jrafi.47.6

no abstracts in English

Cracking investigation of Monju emergency generator C unit cylinder liner; Cylinder liner soundness confirmation by a fall cause of the materials strength of the cylinder liner and the supersonic wave speed

Kobayashi, Takanori; Sakon, Miyoji; Takada, Osamu; Hatori, Masakazu; Sakamoto, Tsutomu; Sato, Toshiyuki; Kazama, Akihito*; Ishizawa, Yoshihiro*; Igawa, Katsuhisa*; Nakae, Hideo*

JAEA-Review 2011-047, 48 Pages, 2012/02

JAEA-Review-2011-047.pdf:9.58MB

I confirmed a leak of the effluent gas from cylinder part during a load examination after the check of the emergency generator C unit on December 28, 2010 of the facilities check average and confirmed crack in No.8 cylinder liner part. As a result, because it was not performed oil pressure management properly without attaching an oil pressure gauge when I removed cylinder liner about the cause, crack occurred by having been able to write excessive stress for the cylinder liner and reached damage. By a process of this investigation, a fall of the materials strength of some cylinder liner was confirmed, but because a lead ingredient got mixed with materials by a casting process at the time of the production of the cylinder liner, as for this, Widmannst tten graphite occurred, and it became clear that materials strength fell. In addition, I performed inspection by the supersonic wave velocity measurement as technique to distinguish this Widmannst tten graphite easily and confirmed that I was effective.

Simulation of the spalling phenomena at the sp Pillar Stability Experiment by the coupled T-H-M analysis using the damage model

Chijimatsu, Masakazu*; Koyama, Tomofumi*; Kobayashi, Akira*; Shimizu, Hiroyuki*; Nakama, Shigeo

Proceedings of 4th International Conference on Coupled T-H-M-C Processes in Geosystems: Fundamentals, Modeling, Experiments and Applications (GeoProc 2011) (CD-ROM), 13 Pages, 2011/07

The experiment was performed at the sp Hard Rock Laboratory facility owned by the Swedish Nuclear Fuel and Waste Management Co. For the experiment an oval shape tunnel was excavated in which two large holes, 1.75 m and depth 6.5 m, were excavated. The holes were placed so that a 1 m wide vertical pillar was created between them. The pillar volume was then heated to increase the tangential stress so that yielding could propagate along the borehole wall. Analysis of the coupled thermal, hydraulic and mechanical processes is carried out with the computer code named THAMES. In order to evaluate the spalling phenomena, the damage model was included in the computer code. In the damage mechanics, the change in mechanical behavior due to the growth of damage (cracks) in material is considered. The parameters of this damage model were determined by the unconfined compression test. When the parameters determined by laboratory test were used, the damage did not occur. This is because the parameters were determined from the experiment of the rock core, and it is thought that the parameter of actual bedrock is inferior to that of the rock core. Therefore, the calibration of the damage parameters was performed. When the calibrated parameters were used, simulation results agree qualitatively well with the experimental results. During the simulation of excavation, generating of damage is seen to similar to the observation by the in-situ experiment. Furthermore, temperature change during heating after the excavation of borehole also shows the good agreement between the measured and simulated results. Therefore, it can be said that the spalling phenomenon is expressible even by the application with the continuum model by the use of the suitable parameters.