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Journal Articles

Structural Approach to Understanding the Formation of Amorphous Metal Hydroxides

Kobayashi, Taishi*; Fushimi, Tomokazu*; Mizukoshi, Hirofumi*; Motokawa, Ryuhei; Sasaki, Takayuki*

Langmuir, 38(48), p.14656 - 14665, 2022/12

 Times Cited Count:2 Percentile:27.64(Chemistry, Multidisciplinary)

no abstracts in English

Journal Articles

Local structure investigations of accumulated damage in irradiated MgAl$$_{2}$$O$$_{4}$$

Yoshioka, Satoru*; Tsuruta, Konosuke*; Yamamoto, Tomokazu*; Yasuda, Kazuhiro*; Matsumura, Sho*; Sugiyama, Takeharu*; Oba, Yojiro; Ishikawa, Norito; Kobayashi, Eiichi*; Okudaira, Koji*

Journal of the American Ceramic Society, 103(8), p.4654 - 4663, 2020/08

 Times Cited Count:4 Percentile:22.32(Materials Science, Ceramics)

X-ray absorption near edge structure (XANES) and small-angle X-ray scattering (SAXS) reveal the damaged structures in MgAl$$_{2}$$O$$_{4}$$ spinel induced by swift heavy ions. SAXS indicates the formation of ion tracks with cylindrical shape with a diameter of 5 nm. XANES indicates the cationic disordering between tetrahedral and octahedral sites by the irradiation. Quantitative analysis of XANES also reveals that cations preferably occupy the octahedral sites at high fluence.

Journal Articles

X-ray absorption near edge structure and first-principles spectral investigations of cationic disorder in MgAl$$_{2}$$O$$_{4}$$ induced by swift heavy ions

Yoshioka, Satoru*; Tsuruta, Konosuke*; Yamamoto, Tomokazu*; Yasuda, Kazuhiro*; Matsumura, Sho*; Ishikawa, Norito; Kobayashi, Eiichi*

Physical Chemistry Chemical Physics, 20(7), p.4962 - 4969, 2018/02

 Times Cited Count:5 Percentile:22.84(Chemistry, Physical)

Cationic disorder in the MgAl$$_{2}$$O$$_{4}$$ spinel induced by swift heavy ions was investigated using the X-ray absorption near edge structure. With changes in the irradiation fluences of 200 MeV Xe ions, the Mg K-edge and Al K-edge spectra were synchronously changed. The calculated spectra based on density function theory indicate that the change in the experimental spectra was due to cationic disorder between Mg in tetrahedral sites and Al in octahedral sites. These results suggest a high inversion degree to an extent that the completely random configuration is achieved in MgAl$$_{2}$$O$$_{4}$$ induced by the high density electronic excitation under swift heavy ion irradiation.

Journal Articles

Superdeformation in $$^{35}$$S

Go, Shintaro*; Ideguchi, Eiji*; Yokoyama, Rin*; Kobayashi, Motoki*; Kisamori, Keiichi*; Takaki, Motonobu*; Miya, Hiroyuki*; Ota, Shinsuke*; Michimasa, Shinichiro*; Shimoura, Susumu*; et al.

JPS Conference Proceedings (Internet), 6, p.030005_1 - 030005_4, 2015/06

Journal Articles

Dismantlement of large fusion experimental device JT-60U

Ikeda, Yoshitaka; Okano, Fuminori; Sakasai, Akira; Hanada, Masaya; Akino, Noboru; Ichige, Hisashi; Kaminaga, Atsushi; Kiyono, Kimihiro; Kubo, Hirotaka; Kobayashi, Kazuhiro; et al.

Nihon Genshiryoku Gakkai Wabun Rombunshi, 13(4), p.167 - 178, 2014/12

The JT-60U torus was disassembled so as to newly install the superconducting tokamak JT-60SA torus. The JT-60U used the deuterium for 18 years, so the disassembly project of the JT-60U was the first disassembly experience of a fusion device with radioactivation in Japan. All disassembly components were stored with recording the data such as dose rate, weight and kind of material, so as to apply the clearance level regulation in future. The lessons learned from the disassembly project indicated that the cutting technologies and storage management of disassembly components were the key factors to conduct the disassembly project in an efficient way. After completing the disassembly project, efforts have been made to analyze the data for characterizing disassembly activities, so as to contribute the estimation of manpower needs and the radioactivation of the disassembly components on other fusion devices.

Journal Articles

Safe disassembly and storage of radioactive components of JT-60U torus

Ikeda, Yoshitaka; Okano, Fuminori; Hanada, Masaya; Sakasai, Akira; Kubo, Hirotaka; Akino, Noboru; Chiba, Shinichi; Ichige, Hisashi; Kaminaga, Atsushi; Kiyono, Kimihiro; et al.

Fusion Engineering and Design, 89(9-10), p.2018 - 2023, 2014/10

 Times Cited Count:2 Percentile:16.35(Nuclear Science & Technology)

Disassembly of the JT-60U torus was started in 2009 after 18-years D$$_{2}$$ operations, and was completed in October 2012. The JT-60U torus was featured by the complicated and welded structure against the strong electromagnetic force, and by the radioactivation due to D-D reactions. Since this work is the first experience of disassembling a large radioactive fusion device in Japan, careful disassembly activities have been made. About 13,000 components cut into pieces with measuring the dose rates were removed from the torus hall and stored safely in storage facilities by using a total wokers of 41,000 person-days during 3 years. The total weight of the disassembly components reached up to 5,400 tons. Most of the disassembly components will be treated as non-radioactive ones after the clearance verification under the Japanese regulation in future. The assembly of JT-60SA has started in January 2013 after this disassembly of JT-60U torus.

Journal Articles

Detection and activity of iodine-131 in brown algae collected in the Japanese coastal areas

Morita, Takami*; Niwa, Kentaro*; Fujimoto, Ken*; Kasai, Hiromi*; Yamada, Haruya*; Nishiuchi, Ko*; Sakamoto, Tatsuya*; Godo, Waichiro*; Taino, Seiya*; Hayashi, Yoshihiro*; et al.

Science of the Total Environment, 408(16), p.3443 - 3447, 2010/06

 Times Cited Count:13 Percentile:32.9(Environmental Sciences)

Iodine-131 ($$^{131}$$I) was detected in brown algae collected off the Japanese coast. The maximum measured specific activity of $$^{131}$$I in brown algae was 0.37$$pm$$0.010 Bq/kg-wet. Cesium-137 ($$^{137}$$Cs) was also detected in all brown algal samples used in this study. There was no correlation between specific activities of $$^{131}$$I and $$^{137}$$Cs in these seaweeds. Low specific activity and minimal variability of $$^{137}$$Cs in brown algae indicated that past nuclear weapon tests were the source of $$^{137}$$Cs. Although nuclear power facilities are known to be pollution sources of $$^{131}$$I, there was no relationship between the sites where $$^{131}$$I was detected and the locations of nuclear power facilities. Most of the sites where $$^{131}$$I was detected were near big cities with large populations. On the basis of the results, we suggest that the likely pollution source of $$^{131}$$I, detected in brown seaweeds, is not nuclear power facilities, but nuclear medicine procedures.

JAEA Reports

Re-Evaluation of a Method for Monitoring Airborne$$^{14}$$C Discharge and its Contribution to Development of an Advanced Method

Koarashi, Jun; Isaka, Keisuke*; Yokota, Tomokazu*; Kozawa, Tomoyasu*; Mikami, Satoshi; Akiyama, Kiyomitsu; Kobayashi, Hirohide

JNC TN8410 2005-005, 55 Pages, 2005/05

JNC-TN8410-2005-005.pdf:2.0MB

Some investigations were made for re-evaluating collection and measurement techniques in an airborne $$^{14}$$C discharge monitoring at the Tokai reprocessing plant (TRP), which include (1)collection efficiency of CO$$_{2}$$ in a carbon sampler using monoethanolamine as CO$$_{2}$$ absorbent;(2)affect of incorporating tritiated water into the carbon sampler on quantitative estimation of $$^{14}$$C activity in airborne effluent; (3)affect of leakage in air sampling on evaluating airborne $$^{14}$$C discharge; and (4)determination of chemical forms of $$^{14}$$C in airborne release from the TRP. The results presented not only the validity of the TRP's monitoring method, but also the technical aspects required for establishing a more reliable and effective monitoring method.

JAEA Reports

Re-Evaluation of a Method for Monitoring Airborne $$^{3}$$H Discharge and its Contribution to Development of an Advanced Method

Koarashi, Jun; Yokota, Tomokazu*; Kozawa, Tomoyasu*; Isaka, Keisuke*; Mikami, Satoshi; Akiyama, Kiyomitsu; Kobayashi, Hirohide

JNC TN8410 2005-004, 73 Pages, 2005/05

JNC-TN8410-2005-004.pdf:2.48MB

Some investigations were made for re-evaluating collection and measurement techniques in an airborn $$^{3}$$H discharge monitoring at the Tokai reprocessing plant (TRP), which include (1)collection efficiency of water in a tritium sampler; (2)quench correction in $$^{3}$$H activity measurement by liquid scintillation counting; (3)affect of leakage in air sampling on evaluating airborne $$^{3}$$H discharge; and (4)determination of chemical forms of $$^{3}$$H in airborne release from the TRP. The results presented not only the validity of the TRP's monitoring method, but also the technical aspects required for establishing a more reliable and effective monitoring method.

Journal Articles

Radiation damage effects in superplastic 3Y-TZP irradiated with Zr ions

Motohashi, Yoshinobu*; Kobayashi, Tomokazu*; Harjo, S.*; Sakuma, Takaaki*; Shibata, Taiju; Ishihara, Masahiro; Baba, Shinichi; Hoshiya, Taiji

Nuclear Instruments and Methods in Physics Research B, 206, p.144 - 147, 2003/05

 Times Cited Count:4 Percentile:33.7(Instruments & Instrumentation)

The 3mol% yttria containing tetragonal zirconia polycrystals(3Y-TZP) were irradiated using 130MeV Zr$$^{11+}$$ ions in the TANDEM accelerator facility at Tokai Research Establishment, JAERI. Irradiation was performed with the fluence of 3.5$$times$$10$$^{16}$$ and 2.1$$times$$10$$^{17}$$ ions/m$$^{2}$$. Residual stress and changes in mechanical properties caused by the ion irradiation and the effects of the subsequent annealing are studied. The occurrence of compressive residual stresses and increases in hardness and fracture toughness were found at the surface regions of as-irradiated specimens. It was found from the subsequent annealing that these quantities decreased gradually with raising the annealing temperature and returned to that of un-irradiated state at around 1173K. A most probable cause of the increases in the hardness and fracture toughness after the irradiation may, therefore, be the residual compressive stresses left in the irradiated surface region.

Journal Articles

Superplastic deformation characteristics of 3Y-TZP after Zr ion irradiation

Shibata, Taiju; Ishihara, Masahiro; Motohashi, Yoshinobu*; Baba, Shinichi; Hoshiya, Taiji; Kobayashi, Tomokazu*; Harjo, S.*; Sakuma, Takaaki*

Nuclear Instruments and Methods in Physics Research B, 206, p.139 - 143, 2003/05

 Times Cited Count:4 Percentile:33.7(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Effects of 293-1573K annealing on some properties of 3Y-TZP irradiated with Zr ions

Sakuma, Takaaki*; Motohashi, Yoshinobu*; Kobayashi, Tomokazu*; Harjo, S.*; Shibata, Taiju; Ishihara, Masahiro; Baba, Shinichi; Hoshiya, Taiji

Nihon Kikai Gakkai Kanto Shibu Ibaraki Koenkai (2002) Koen Rombunshu (No.020-3), p.125 - 126, 2002/09

no abstracts in English

JAEA Reports

Investigation of safety concept of spallation neutron source

Kobayashi, Kaoru*; Kaminaga, Masanori; Haga, Katsuhiro; Kinoshita, Hidetaka; Aso, Tomokazu; Hino, Ryutaro

JAERI-Review 2002-010, 52 Pages, 2002/05

JAERI-Review-2002-010.pdf:3.38MB

no abstracts in English

JAEA Reports

Estimation of thermochemical behavior of spallation products in mercury target

Kobayashi, Kaoru*; Kaminaga, Masanori; Haga, Katsuhiro; Kinoshita, Hidetaka; Aso, Tomokazu; Teshigawara, Makoto; Hino, Ryutaro

JAERI-Tech 2002-005, 118 Pages, 2002/02

JAERI-Tech-2002-005.pdf:9.71MB

In order to examine the radiation safety of a spallation mercury target system, it is necessary to clarify the chemical forms of spallation products generated by spallation reaction with proton beam. As for the chemical forms of spallation products in mercury that involves large amounts of spallation products, these forms were estimated by using the binary phase diagrams and the thermochemical equilibrium calculation based on the amounts of spallation product. Calculation results showed that the mercury would dissolve Al, As, B, Be, Bi, C, Co, Cr, Fe, Ga, Ge, Ir, Mo, Nb, Os, Re, Ru, Sb, Si, Ta, Tc, V and W in the element state, and Ag, Au, Ba, Br, Ca, Cd, Ce, Cl, Cs, Cu, Dy, Er, Eu, F, Gd, Hf, Ho, I, In, K, La, Li, Lu, Mg, Mn, Na, Nd, Ni, O, Pb, Pd, Pr, Pt, Rb, Rh, S, Sc, Se, Sm, Sn, Sr, Tb, Te, Ti, Tl, Tm, Y, Yb, Zn and Zr in the form of inorganic mercury compounds.

Journal Articles

Evaluation of superplastic deformation characteristics of 3Y-TZP utilizing beams with trapezoidal cross-sections

Wan, C.*; Kobayashi, Tomokazu*; Motohashi, Yoshinobu*; Sakuma, Takaaki*; Ishihara, Masahiro; Shibata, Taiju

Ibaraki Daigaku Kogakubu Kenkyu Shuho, 49, p.69 - 79, 2002/02

no abstracts in English

Journal Articles

Present status of spallation neutron source development; JAERI/KEK joint project in Japan

Kaminaga, Masanori; Haga, Katsuhiro; Aso, Tomokazu; Kinoshita, Hidetaka; Kogawa, Hiroyuki; Ishikura, Shuichi*; Terada, Atsuhiko*; Kobayashi, Kaoru*; Adachi, Junichi*; Teraoku, Takuji*; et al.

Proceedings of American Nuclear Society Conference "Nuclear Applications in the New Millennium" (AccApp-ADTTA '01) (CD-ROM), 9 Pages, 2002/00

no abstracts in English

JAEA Reports

Physical and thermochemical properties for inorganic mercury compounds

Kobayashi, Kaoru*; Kaminaga, Masanori; Haga, Katsuhiro; Kinoshita, Hidetaka; Aso, Tomokazu; Kogawa, Hiroyuki; Hino, Ryutaro

JAERI-Data/Code 2000-037, 69 Pages, 2000/12

JAERI-Data-Code-2000-037.pdf:3.21MB

no abstracts in English

JAEA Reports

Proposal of source term methodologies for mercury target system

Kobayashi, Kaoru*; Kaminaga, Masanori; Haga, Katsuhiro; Kinoshita, Hidetaka; Aso, Tomokazu; Kogawa, Hiroyuki; Hino, Ryutaro

JAERI-Tech 2000-050, 43 Pages, 2000/08

JAERI-Tech-2000-050.pdf:2.36MB

no abstracts in English

Oral presentation

An Experience of alpha-radioactivity monitoring aiming at $$gamma$$-rays from Am-241 in airborne effluent

Ito, Yasuhisa; Mikami, Satoshi; Miyauchi, Toru; Akiyama, Kiyomitsu; Kobayashi, Hirohide; Kozawa, Tomoyasu*; Yokota, Tomokazu*

no journal, , 

no abstracts in English

19 (Records 1-19 displayed on this page)
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