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Journal Articles

Intercalative and non-intercalative photo-recharge using all-solid-state cells for solar energy conversion and storage

Yoshimoto, Masataka*; Tamura, Kazuhisa; Watanabe, Kenta*; Shimizu, Keisuke*; Horisawa, Yuhei*; Kobayashi, Takeshi*; Tsurita, Hanae*; Suzuki, Kota*; Kanno, Ryoji*; Hirayama, Masaaki*

Sustainable Energy & Fuels (Internet), 8(6), p.1236 - 1244, 2024/03

 Times Cited Count:0

Photo-rechargeable systems, which can efficiently convert and store solar energy into chemical energy within single devices, are essential to harness sunlight effectively. Photo-(de)intercalation plays a pivotal role in the functionality of photorechargeable systems. Nevertheless, the photo-(de)intercalation process has not been conclusively confirmed owing to potential interference from side reactions, such as the decomposition of liquid electrolytes and the elution of electrode materials. In this study, we successfully demonstrated photo-responsive Li$$^{+}$$-deintercalation using an all-solid-state thin-film battery comprised of epitaxially-grown anatase TiO$$_{2}$$ doped with Nb (a-TiO$$_{2}$$:Nb) as the cathode. Under light irradiation, Li$$^{+}$$-deintercalation occurred and was subsequently reversibly intercalated into a-TiO$$_{2}$$:Nb during discharge.

Journal Articles

Phase analysis of simulated nuclear fuel debris synthesized using UO$$_{2}$$, Zr, and stainless steel and leaching behavior of the fission products and matrix elements

Tonna, Ryutaro*; Sasaki, Takayuki*; Kodama, Yuji*; Kobayashi, Taishi*; Akiyama, Daisuke*; Kirishima, Akira*; Sato, Nobuaki*; Kumagai, Yuta; Kusaka, Ryoji; Watanabe, Masayuki

Nuclear Engineering and Technology, 55(4), p.1300 - 1309, 2023/04

 Times Cited Count:1 Percentile:72.91(Nuclear Science & Technology)

Simulated debris was synthesized using UO$$_{2}$$, Zr, and stainless steel and a heat treatment method under inert or oxidizing conditions. The primary U solid phase of the debris synthesized at 1473 K under inert conditions was UO$$_{2}$$, whereas a (U,Zr)O$$_{2}$$ solid solution formed at 1873 K. Under oxidizing conditions, a mixture of U$$_{3}$$O$$_{8}$$ and (Fe,Cr)UO$$_{4}$$ phases formed at 1473 K whereas a (U,Zr)O$$_{2+x}$$ solid solution formed at 1873 K. The leaching behavior of the fission products from the simulated debris was evaluated using two methods: the irradiation method, for which fission products were produced via neutron irradiation, and the doping method, for which trace amounts of non-radioactive elements were doped into the debris. The dissolution behavior of U depended on the properties of the debris and aqueous medium the debris was immersed in. Cs, Sr, and Ba leached out regardless of the primary solid phases. The leaching of high-valence Eu and Ru ions was suppressed, possibly owing to their solid-solution reaction with or incorporation into the uranium compounds of the simulated debris.

Journal Articles

Sodium-cooled Fast Reactors

Ohshima, Hiroyuki; Morishita, Masaki*; Aizawa, Kosuke; Ando, Masanori; Ashida, Takashi; Chikazawa, Yoshitaka; Doda, Norihiro; Enuma, Yasuhiro; Ezure, Toshiki; Fukano, Yoshitaka; et al.

Sodium-cooled Fast Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.3, 631 Pages, 2022/07

This book is a collection of the past experience of design, construction, and operation of two reactors, the latest knowledge and technology for SFR designs, and the future prospects of SFR development in Japan. It is intended to provide the perspective and the relevant knowledge to enable readers to become more familiar with SFR technology.

Journal Articles

Nanoscopic structure of borosilicate glass with additives for nuclear waste vitrification

Motokawa, Ryuhei; Kaneko, Koji; Oba, Yojiro; Nagai, Takayuki; Okamoto, Yoshihiro; Kobayashi, Taishi*; Kumada, Takayuki; Heller, W. T.*

Journal of Non-Crystalline Solids, 578, p.121352_1 - 121352_7, 2022/02

 Times Cited Count:3 Percentile:22.84(Materials Science, Ceramics)

Journal Articles

Age-hardening mechanisms of heterogeneous-nanostructured SUS316LN stainless steel fabricated by heavy cold rolling

Miura, Hiromi*; Watanabe, Chihiro*; Aoyagi, Yoshiteru*; Oba, Yojiro; Kobayashi, Masakazu*; Yoshinaga, Naoki*

Materials Science & Engineering A, 833, p.142531_1 - 142531_12, 2022/01

 Times Cited Count:3 Percentile:45.58(Nanoscience & Nanotechnology)

Journal Articles

Local structure investigations of accumulated damage in irradiated MgAl$$_{2}$$O$$_{4}$$

Yoshioka, Satoru*; Tsuruta, Konosuke*; Yamamoto, Tomokazu*; Yasuda, Kazuhiro*; Matsumura, Sho*; Sugiyama, Takeharu*; Oba, Yojiro; Ishikawa, Norito; Kobayashi, Eiichi*; Okudaira, Koji*

Journal of the American Ceramic Society, 103(8), p.4654 - 4663, 2020/08

 Times Cited Count:4 Percentile:23.05(Materials Science, Ceramics)

X-ray absorption near edge structure (XANES) and small-angle X-ray scattering (SAXS) reveal the damaged structures in MgAl$$_{2}$$O$$_{4}$$ spinel induced by swift heavy ions. SAXS indicates the formation of ion tracks with cylindrical shape with a diameter of 5 nm. XANES indicates the cationic disordering between tetrahedral and octahedral sites by the irradiation. Quantitative analysis of XANES also reveals that cations preferably occupy the octahedral sites at high fluence.

Journal Articles

Multi-step magnetic transitions in EuNiIn$$_4$$

Ikeda, Shugo*; Kaneko, Koji; Tanaka, Yuki*; Kawasaki, Takuro; Hanashima, Takayasu*; Munakata, Koji*; Nakao, Akiko*; Kiyanagi, Ryoji; Ohara, Takashi; Mochizuki, Kensei*; et al.

Journal of the Physical Society of Japan, 89(1), p.014707_1 - 014707_7, 2020/01

 Times Cited Count:1 Percentile:12.02(Physics, Multidisciplinary)

JAEA Reports

Study on engineering technologies in the Mizunami Underground Research Laboratory (FY 2015); Development of design and construction planning and countermeasure technologies (Contract research)

Toguri, Satohito*; Kobayashi, Shinji*; Tsuji, Masakuni*; Yahagi, Ryoji*; Yamada, Toshiko*; Matsui, Hiroya; Sato, Toshinori; Mikake, Shinichiro; Aoyagi, Yoshiaki

JAEA-Technology 2017-005, 43 Pages, 2017/03

JAEA-Technology-2017-005.pdf:4.4MB

The study on engineering technology in the Mizunami Underground Research Laboratory (MIU) project roughly consists of (1) development of design and construction planning technologies, (2) development of construction technology, (3) development of countermeasure technology, (4) development of technology for security, and (5) development of technologies regarding restoration and mitigating of the excavation effect. In FY2015, as a part of the important issues on the research program, water-tight grouting method has been developed. Grouting methods utilized in the MIU were evaluated and the post-excavation grouting at the -500m Access/Research Gallery-South was planned based on these evaluation results. Also, technology development from the viewpoint of geological disposal was summarized, and information on the alternative method to the grouting method was collected and organized.

Journal Articles

Excited configurations of hydrogen in the BaTiO$$_{3-x}$$H$$_x$$ perovskite lattice associated with hydrogen exchange and transport

Ito, Takashi; Koda, Akihiro*; Shimomura, Koichiro*; Higemoto, Wataru; Matsuzaki, Teiichiro*; Kobayashi, Yoji*; Kageyama, Hiroshi*

Physical Review B, 95(2), p.020301_1 - 020301_5, 2017/01

 Times Cited Count:11 Percentile:48.83(Materials Science, Multidisciplinary)

Journal Articles

Excavation cycle times recorded during sinking of a deep shaft in crystalline rock; A Case example at ventilation shaft of Mizunami URL, Japan

Sanada, Hiroyuki; Sato, Toshinori; Horiuchi, Yasuharu*; Mikake, Shinichiro; Okihara, Mitsunobu*; Yahagi, Ryoji*; Kobayashi, Shinji*

Tunnelling and Underground Space Technology, 50, p.68 - 78, 2015/08

 Times Cited Count:5 Percentile:19.84(Construction & Building Technology)

The Japan Atomic Energy Agency (JAEA) is implementing the Mizunami Underground Research Laboratory (MIU) Project to establish the scientific and technological basis for the geological disposal of High-level Radioactive Waste (HLW) in crystalline rocks. Excavation cycle times were recorded during the Ventilation Shaft sinking and compared with the planned excavation cycle times for evaluation of the baseline design plan. This included review of the cycle times in the design process and comparison with the actual construction results. The recorded results indicate that actual cycle times were twice as long as the design plan. This paper describes discussions on differences in cycle times between the design and actual times.

Journal Articles

Analysis of excavation cycle time during sinking of the ventilation shaft at the Mizunami Underground Research Laboratory

Sanada, Hiroyuki; Sato, Toshinori; Horiuchi, Yasuharu*; Mikake, Shinichiro; Okihara, Mitsunobu*; Yahagi, Ryoji*; Kobayashi, Shinji*

Proceedings of 8th Asian Rock Mechanics Symposium (ARMS-8) (USB Flash Drive), 7 Pages, 2014/10

The Japan Atomic Energy Agency (JAEA) is implementing the Mizunami Underground Research Laboratory (MIU) Project to establish the scientific and technological basis for the geological disposal of High-level Radioactive Waste (HLW) in crystalline rocks. Excavation cycle times were recorded during the Ventilation Shaft sinking and compared with the planned excavation cycle times for evaluation of the baseline design plan. This included review of the cycle times in the design process and comparison with the actual construction results. The recorded results indicate that actual cycle times were twice as long as the design plan. This paper describes discussions on differences in cycle times between the design and result.

Journal Articles

Investigation of advanced divertor magnetic configuration for DEMO tokamak reactor

Asakura, Nobuyuki; Shinya, Kichiro*; Tobita, Kenji; Hoshino, Kazuo; Shimizu, Katsuhiro; Uto, Hiroyasu; Someya, Yoji; Nakamura, Makoto; Ono, Noriyasu*; Kobayashi, Masahiro*; et al.

Fusion Science and Technology, 63(1T), p.70 - 75, 2013/05

no abstracts in English

Journal Articles

Investigation of advanced divertor magnetic configuration for Demo tokamak reactor

Asakura, Nobuyuki; Shinya, Kichiro*; Tobita, Kenji; Hoshino, Kazuo; Shimizu, Katsuhiro; Uto, Hiroyasu; Someya, Yoji; Nakamura, Makoto; Ono, Noriyasu*; Kobayashi, Masahiro*; et al.

Fusion Science and Technology, 63(1T), p.70 - 75, 2013/05

 Times Cited Count:14 Percentile:72.14(Nuclear Science & Technology)

Design study of poloidal field coil (PFC) locations and current distribution for the advanced divertor in the Demo tokamak reactor was presented. Concept of the super-X divertor (SXD) for Demo reactor has an outer divertor leg longer than the conventional divertor, and it extends outboard to increase both the target wetted area and connection length to the outer target ($$L_{//}$$). Equilibrium calculation code, TOSCA, was developed by introducing two parameters, i.e. super-X null radius ($$R_{SX}$$) and a ratio of the poloidal flux at the super-X null to that at the separatrix ($$f_{SX}$$). Some SXD magnetic configurations with minimal number of PFCs located outside toroidal field coil (TFC) were Demonstrated. Locations of the divertor target were also investigated. It was found that the flux expansion can be increased up to 4-10 depending on the target location and $$f_{SX}$$, and that SXD has an advantage to increase $$L_{//}$$ with $$f_{SX}$$. Thus, the divertor plasma temperature is expected to decrease at the same upstream plasma density. On the other hand, large currents for the divertor PFCs were necessary. Other arrangements of PFCs such as (1) larger $$R_{SX}$$ and (2) inside TFC, can reduce the PFC currents.

JAEA Reports

Cracking investigation of Monju emergency generator C unit cylinder liner; Cylinder liner soundness confirmation by a fall cause of the materials strength of the cylinder liner and the supersonic wave speed

Kobayashi, Takanori; Sakon, Miyoji; Takada, Osamu; Hatori, Masakazu; Sakamoto, Tsutomu; Sato, Toshiyuki; Kazama, Akihito*; Ishizawa, Yoshihiro*; Igawa, Katsuhisa*; Nakae, Hideo*

JAEA-Review 2011-047, 48 Pages, 2012/02

JAEA-Review-2011-047.pdf:9.58MB

I confirmed a leak of the effluent gas from cylinder part during a load examination after the check of the emergency generator C unit on December 28, 2010 of the facilities check average and confirmed crack in No.8 cylinder liner part. As a result, because it was not performed oil pressure management properly without attaching an oil pressure gauge when I removed cylinder liner about the cause, crack occurred by having been able to write excessive stress for the cylinder liner and reached damage. By a process of this investigation, a fall of the materials strength of some cylinder liner was confirmed, but because a lead ingredient got mixed with materials by a casting process at the time of the production of the cylinder liner, as for this, Widmannst tten graphite occurred, and it became clear that materials strength fell. In addition, I performed inspection by the supersonic wave velocity measurement as technique to distinguish this Widmannst tten graphite easily and confirmed that I was effective.

Journal Articles

Changes to the chemical structure of isotactic-polypropylene induced by ion-beam irradiation

Oka, Toshitaka; Oshima, Akihiro*; Motohashi, Ryota*; Seto, Naoto*; Watanabe, Yuji*; Kobayashi, Ryoji*; Saito, Koki*; Kudo, Hisaaki*; Murakami, Takeshi*; Washio, Masakazu*; et al.

Radiation Physics and Chemistry, 80(2), p.278 - 280, 2011/02

 Times Cited Count:7 Percentile:48.91(Chemistry, Physical)

The chemical structures of various ion-beam irradiated isotactic-polypropylene samples were studied. Results of micro-Fourier transform infrared spectroscopy and ultraviolet-visible spectroscopy suggest not only the linear energy transfer, but also the fluence is effective in local transformation of the isotactic-polypropylene.

Journal Articles

Basic vacuum test of 500-kV photocathode DC gun components at KEK

Yamamoto, Masahiro*; Uchiyama, Takashi*; Miyajima, Tsukasa*; Honda, Yosuke*; Sato, Kotaro*; Matsuba, Shunya*; Saito, Yoshio*; Kobayashi, Masanori*; Kurisu, Hiriki*; Hajima, Ryoichi; et al.

Proceedings of 7th Annual Meeting of Particle Accelerator Society of Japan (DVD-ROM), p.717 - 720, 2010/08

A 500-kV photocathode DC electron gun which can supply the beam of a low emittance and a high average current has been developed in collaboration with KEK, JAEA, Hiroshima Univ., Nagoya Univ. and Yamaguchi Univ. The vacuum of the gun chamber has to be lower Extreme High Vacuum for maintain cathode-life time. A titanium chamber and new material of ceramic were employed to reduce outgassing rate. The result of outgassing rate of the gun chamber is described in this report.

Journal Articles

Recent progress in the energy recovery linac project in Japan

Sakanaka, Shogo*; Akemoto, Mitsuo*; Aoto, Tomohiro*; Arakawa, Dai*; Asaoka, Seiji*; Enomoto, Atsushi*; Fukuda, Shigeki*; Furukawa, Kazuro*; Furuya, Takaaki*; Haga, Kaiichi*; et al.

Proceedings of 1st International Particle Accelerator Conference (IPAC '10) (Internet), p.2338 - 2340, 2010/05

Future synchrotron light source using a 5-GeV energy recovery linac (ERL) is under proposal by our Japanese collaboration team, and we are conducting R&D efforts for that. We are developing high-brightness DC photocathode guns, two types of cryomodules for both injector and main superconducting (SC) linacs, and 1.3 GHz high CW-power RF sources. We are also constructing the Compact ERL (cERL) for demonstrating the recirculation of low-emittance, high-current beams using above-mentioned critical technologies.

Journal Articles

Design of a 500kV electron gun for ERL light source at KEK

Yamamoto, Masahiro*; Honda, Yosuke*; Miyajima, Tsukasa*; Uchiyama, Takashi*; Kobayashi, Masanori*; Muto, Toshiya*; Matsuba, Shunya*; Sakanaka, Shogo*; Sato, Kotaro*; Saito, Yoshio*; et al.

Proceedings of 6th Annual Meeting of Particle Accelerator Society of Japan (CD-ROM), p.860 - 862, 2009/08

A newly 500 kV electron gun (2nd - 500 kV gun) for an ERL light source is designed at KEK. A new concept and state of-the-art technologies of vacuum system, ceramic insulators, high voltage power supply, photocathode and preparation system will be employed. The details are described in this report.

Journal Articles

Progress in R&D efforts on the energy recovery linac in Japan

Sakanaka, Shogo*; Ago, Tomonori*; Enomoto, Atsushi*; Fukuda, Shigeki*; Furukawa, Kazuro*; Furuya, Takaaki*; Haga, Kaiichi*; Harada, Kentaro*; Hiramatsu, Shigenori*; Honda, Toru*; et al.

Proceedings of 11th European Particle Accelerator Conference (EPAC '08) (CD-ROM), p.205 - 207, 2008/06

Future synchrotron light sources based on the energy-recovery linacs (ERLs) are expected to be capable of producing super-brilliant and/or ultra-short pulses of synchrotron radiation. Our Japanese collaboration team is making efforts for realizing an ERL-based hard X-ray source. We report recent progress in our R&D efforts.

Journal Articles

Present status and future prospect of JRR-3 and JRR-4

Sakurai, Fumio; Horiguchi, Yoji; Kobayashi, Shinsho; Takayanagi, Masaji

Physica B; Condensed Matter, 311(1-2), p.7 - 13, 2002/01

 Times Cited Count:9 Percentile:45.24(Physics, Condensed Matter)

no abstracts in English

36 (Records 1-20 displayed on this page)