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Journal Articles

Magnetic ground state of YbCo$$_2$$Zn$$_{20}$$ probed by muon spin relaxation

Higemoto, Wataru; Sato, Kazuhiko*; Ito, Takashi; Oishi, Kazuki*; Saiga, Yuta*; Kosaka, Masashi*; Matsubayashi, Kazuyuki*; Uwatoko, Yoshiya*

Journal of Physics; Conference Series, 2462, p.012039_1 - 012039_5, 2023/03

 Times Cited Count:0 Percentile:0.2(Physics, Applied)

The cubic compound YbCo$$_2$$Zn$$_{20}$$ has huge electronic specific heat coefficient and its ground state could be located in the vicinity of the quantum critical point. Indeed, a magnetic long-range order was observed under pressure above 1-2 GPa. To investigate magnetic ground state, we have carried out muon spin relaxation measurements and confirm non-magnetic ground state with fluctuating tiny magnetic moment.

Journal Articles

Development of evaluation method for variability of groundwater flow conditions associated with long-term topographic change and climate perturbations

Onoe, Hironori; Kosaka, Hiroshi*; Matsuoka, Toshiyuki; Komatsu, Tetsuya; Takeuchi, Ryuji; Iwatsuki, Teruki; Yasue, Kenichi

Genshiryoku Bakkuendo Kenkyu (CD-ROM), 26(1), p.3 - 14, 2019/06

In this study, it is focused on topographic changes due to uplift and denudation, also climate perturbations, a method which is able to assess the long-term variability of groundwater flow conditions using the coefficient variation based on some steady-state groundwater flow simulation results was developed. Spatial distribution of long residence time area which is not much influenced due to long-term topographic change and recharge rate change during the past one million years was able to estimate through the case study of the Tono area, Central Japan. By applying this evaluation method, it is possible to identify the local area that has low variability of groundwater flow conditions due to topographic changes and climate perturbations from the regional area quantitatively and spatially.

Journal Articles

Retreat from stress; Rattling in a planar coordination

Suekuni, Koichiro*; Lee, C. H.*; Tanaka, Hiromi*; Nishibori, Eiji*; Nakamura, Atsushi*; Kasai, Hidetaka*; Mori, Hitoshi*; Usui, Hidetomo*; Ochi, Masayuki*; Hasegawa, Takumi*; et al.

Advanced Materials, 30(13), p.1706230_1 - 1706230_6, 2018/03

 Times Cited Count:51 Percentile:89.35(Chemistry, Multidisciplinary)

Thermoelectric materials for highly efficient devices must satisfy conflicting requirements of high electrical conductivity and low thermal conductivity. In this paper, we studied the crystal structure and phonon dynamics of tetrahedrites (Cu,Zn)$$_{12}$$(Sb,As)$$_{4}$$S$$_{13}$$. The results revealed that the Cu atoms in a planar coordination are rattling, which effectively scatter phonons. These findings provide a new strategy for the development of highly efficient thermoelectric materials with planar coordination.

Journal Articles

Crystallization and preliminary X-ray diffraction analysis of tetrathionate hydrolase from ${it Acidithiobacillus ferrooxidans}$

Kanao, Tadayoshi*; Kosaka, Megumi*; Yoshida, Kyoya*; Nakayama, Hisayuki*; Tamada, Taro; Kuroki, Ryota; Yamada, Hidenori; Takada, Jun*; Kamimura, Kazuo*

Acta Crystallographica Section F, 69(6), p.692 - 694, 2013/06

 Times Cited Count:10 Percentile:59.68(Biochemical Research Methods)

Tetrathionate hydrolase (4THase) from the iron- and sulfur-oxidizing bacterium ${it Acidithiobacillus ferrooxidans}$ catalyses the disproportionate hydrolysis of tetrathionate to elemental sulfur, thiosulfate and sulfate. The gene encoding 4THase (${it Af-tth}$) was expressed as inclusion bodies in recombinant ${it Escherichia coli}$. Recombinant ${it Af}$-Tth was activated by refolding under acidic conditions and was then purified to homogeneity. The recombinant protein was crystallized in 20 m${it M}$ glycine buffer pH 10 containing 50 m${it M}$ sodium chloride and 33%(${it v/v}$) PEG 1000 using the hanging-drop vapour-diffusion method. The crystal was a hexagonal cylinder with dimensions of 0.2 $$times$$ 0.05 $$times$$ 0.05 mm. X-ray crystallographic analysis showed that the crystal diffracted to 2.15 ${AA}$ resolution and belongs to space group ${it P}$3$$_{1}$$ or ${it P}$3$$_{2}$$, with unit-cell parameters ${it a}$ = ${it b}$ = 92.1, ${it c}$ = 232.6 ${AA}$.

Journal Articles

Uniaxial-pressure control of magnetic phase transitions in a frustrated magnet CuFe$$_{1-x}$$Ga$$_{x}$$O$$_{2}$$ (x =0, 0.018)

Nakajima, Taro*; Mitsuda, Setsuo*; Takahashi, Keiichiro*; Yoshitomi, Keisuke*; Masuda, Kazuya*; Kaneko, Chikafumi*; Homma, Yuki*; Kobayashi, Satoru*; Kitazawa, Hideaki*; Kosaka, Masashi*; et al.

Journal of the Physical Society of Japan, 81(9), p.094710_1 - 094710_8, 2012/09

Journal Articles

Uniaxial-pressure control of magnetic phase transitions in a frustrated magnet CuFe$$_{1-x}$$Ga$$_{x}$$O$$_{2}$$ ($$x$$ = 0, 0.018)

Nakajima, Taro*; Mitsuda, Setsuo*; Takahashi, Keiichiro*; Yoshitomi, Keisuke*; Masuda, Kazuya*; Kaneko, Chikafumi*; Homma, Yuki*; Kobayashi, Satoru*; Kitazawa, Hideaki*; Kosaka, Masashi*; et al.

Journal of the Physical Society of Japan, 81(9), p.094710_1 - 094710_8, 2012/09

 Times Cited Count:13 Percentile:63.29(Physics, Multidisciplinary)

Journal Articles

An Attempt to evaluate horizontal crustal movement by geodetic and geological approach in the Horonobe area, northern Hokkaido, Japan

Tokiwa, Tetsuya; Asamori, Koichi; Niizato, Tadafumi; Nohara, Tsuyoshi; Matsuura, Yuki*; Kosaka, Hideki*

Proceedings of 13th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2010) (CD-ROM), p.407 - 413, 2010/10

In this study, we present the preliminary results for the estimation of a horizontal crustal movement by using geodetic and geological approach in the Horonobe area, northern Hokkaido, Japan. The estimations have been carried out by using a GPS data and a geological cross section obtained by applying balanced-section method. As results of this study, both of the shortening rates estimated by GPS data and balanced-section method indicate several millimeters per year. Namely, there is no contradiction between geodetic and geological data, and it is considered that Horonobe area is still situated similar tendency and magnitude of a crustal movement. Geodetic data is not usually used to evaluate the long-term crustal movement. However, the results of this study indicate that geodetic data provide valuable information for estimating the long-term crustal movement in the area.

JAEA Reports

Fast Reactor Cycle Technology Development Project (FaCT Project); A Design study on an engineering-scale hot test facility (Interim report)

Nakamura, Hirofumi; Nagai, Toshihisa; Suto, Toshiyuki; Kosaka, Ichiro; Nakazaki, Katsutoshi; Suto, Shinya; Nakamura, Tomotaka; Nakabayashi, Hiroki; Hayashi, Naoto; Sumida, Daisaku

JAEA-Technology 2008-077, 276 Pages, 2008/12

JAEA-Technology-2008-077.pdf:25.66MB

Japan Atomic Energy Agency (JAEA) has been conducting "Fast Reactor Cycle Technology Development Project (FaCT Project)" for the purposes of researching and developing the technologies for the fast breeder reactor cycle commercialization since Japanese fiscal year (JFY) 2007. Based on the above R&D program for reprocessing system, the engineering-scale hot test would provide demonstration data on the specification, operation and maintenance of the adapted innovative technologies, system and plant. And more, these results would be fed to the design of the demonstration facility planning on the FaCT project road map. This report is the interim report of design studies about the engineering-scale hot test facility and includes not only design of the equipment and facility, but also consideration for design principle, requirements and facility basic planning.

Journal Articles

Structural phase transition in the spin gap system YbAl$$_3$$C$$_3$$

Matsumura, Takeshi*; Inami, Toshiya; Kosaka, Masashi*; Kato, Yoshiaki*; Inukai, Takaki*; Ochiai, Akira*; Nakao, Hironori*; Murakami, Yoichi*; Katano, Susumu*; Suzuki, Hiroyuki*

Journal of the Physical Society of Japan, 77(10), p.103601_1 - 103601_4, 2008/10

 Times Cited Count:14 Percentile:62.95(Physics, Multidisciplinary)

Journal Articles

Quasiparticle interference and superconducting gap in Ca$$_{2-x}$$Na$$_x$$CuO$$_2$$Cl$$_2$$

Hanaguri, Tetsuo*; Kosaka, Yuki*; Davis, J. C.*; Lupien, C.*; Yamada, Ikuya*; Azuma, Masaki*; Takano, Mikio*; Oishi, Kazuki; Ono, Masaki*; Takagi, Hidenori*

Nature Physics, 3(12), p.865 - 871, 2007/12

 Times Cited Count:141 Percentile:95.65(Physics, Multidisciplinary)

Journal Articles

Low-energy spectroscopic mapping studies in optimally-doped Ca$$_{2-x}$$Na$$_x$$CuO$$_2$$Cl$$_2$$

Hanaguri, Tetsuo*; Kosaka, Yuki*; Davis, J. C.*; Lupien, C.*; Yamada, Ikuya*; Azuma, Masaki*; Takano, Mikio*; Oishi, Kazuki; Takagi, Hidenori*

Physica C, 460-462, p.954 - 955, 2007/09

 Times Cited Count:1 Percentile:6.7(Physics, Applied)

We performed high-resolution scanning tunneling microscopy/spectroscopy on an optimally-doped Ca$$_{2-x}$$Na$$_x$$CuO$$_2$$Cl$$_2$$ crystal. The so-called checkerboard local-density-of-state modulation manifests in the spectroscopic map of the optimally-doped sample. In addition, spatially-inhomogeneous energy gap is observed. The gap tends to be buried at elevated temperatures and correlates with the checkerboard modulation. These results suggest that the gap is related to superconductivity which coexists with the checkerboard modulation.

Journal Articles

"Crystal lattice engineering", an approach to engineer protein crystal contacts by creating intermolecular symmetry; Crystallization and structure determination of a mutant human RNase 1 with a hydrophobic interface of leucines

Yamada, Hidenori*; Tamada, Taro; Kosaka, Megumi*; Miyata, Kohei*; Fujiki, Shinya*; Tano, Masaru*; Moriya, Masayuki*; Yamanishi, Mamoru*; Honjo, Eijiro; Tada, Horiko*; et al.

Protein Science, 16(7), p.1389 - 1397, 2007/07

 Times Cited Count:39 Percentile:59.61(Biochemistry & Molecular Biology)

In an attempt to control protein incorporation in a crystal lattice, a leucine zipper-like hydrophobic interface (comprising four leucine residues) was introduced into a helical region (helix 2) of the human pancreatic ribonuclease 1 (RNase 1) that was predicted to form a suitable crystallization interface. Although crystallization of wild type RNase 1 has not yet been reported, the RNase 1 mutant having four leucines (4L-RNase 1) was successfully crystallized under several different conditions. The crystal structures were subsequently determined by X-ray crystallography by molecular replacement using the structure of bovine RNase A. The overall structure of 4L-RNase 1 is quite similar to that of the bovine RNase A, and the introduced leucine residues formed the designed crystal interface. To further characterize the role of the introduced leucine residues in crystallization of RNase 1, the number of leucines was reduced to three or two (3L- and 2L-RNase 1, respectively). Both mutants crystallized and a similar hydrophobic interface as in 4L-RNase 1 was observed. A related approach to engineer crystal contacts at helix 3 of RNase 1 (N4L-RNase 1) was also evaluated. N4L-RNase 1 also successfully crystallized, and formed the expected hydrophobic packing interface. These results suggest that appropriate introduction of a leucine zipper-like hydrophobic interface can promote intra molecular symmetry for more efficient protein crystallization in crystal lattice engineering efforts.

JAEA Reports

Study on the prediction accuracy of nuclide generation and depletion with JENDL

Okumura, Keisuke; Oki, Shigeo*; Yamamoto, Munenari*; Matsumoto, Hideki*; Ando, Yoshihira*; Tsujimoto, Kazufumi; Sasahara, Akihiro*; Katakura, Junichi; Matsumura, Tetsuo*; Aoyama, Takafumi*; et al.

JAERI-Research 2004-025, 154 Pages, 2005/01

JAERI-Research-2004-025.pdf:19.46MB

This report summarizes the activity (FY2000-2003) of Working Group (WG) on Evaluation of Nuclide Generation and Depletion under Subcommittee on Nuclear Fuel Cycle of Japanese Nuclear Data Committee. In the WG, analyses of Post Irradiation Examinations have been carried out for UO$$_{2}$$ and MOX fuels irradiated in PWRs, BWRs and FBRs, and for actinide samples irradiated in fast reactors, by using ORIGEN or more detailed calculation codes with their libraries based on JENDL-3.2, JENDL-3.3 and other foreign nuclear data files. From these results, current prediction accuracy and problems for evaluation of nuclide generation and depletion are discussed. Furthermore, this report covers other products of our activity; development of the ORIGEN libraries for PWR, BWR and FBR based on JENDL-3.3, study on introduction of neutron spectrum index to ORIGEN calculations, and results of questionnaire survey on desirable accuracy of ORIGEN calculations.

JAEA Reports

The Dissolving Test of the Uranium Oxide using Amide System Extraction Solvent

Mizuno, Mineo*; Kosaka, Yuji*; Mori, Yukihide*; Shimada, Takashi*

JNC TJ8410 2004-006, 85 Pages, 2004/03

JNC-TJ8410-2004-006.pdf:3.05MB

/The process (the UPRISE method) of dissolving uranium and plutonium selectively and separating from oxide fuel using the amide system extraction solvent have been investigated. By the cold test which used Nd oxide so far, the dissolving of Nd with about 0.2 mol to the solvent of 250mL is confirmed. In this work, the investigations of the dissolving tendency of uranium to the amide system extraction solvent and decontamination factor (DF) of the typical fission product (FP) such as Nd were carried out, and following results are obtained. (1)In the test of the same dissolving conditions, the uranium dissolving rate to extraction solvent DOBA was approximately equivalent to the case of the DOiBA. (2)Three kinds of extraction solvent were examined in the same dissolving condition, the difference of the uranium dissolving rate was observed. The results of the dissolving rates indicated the order of NN'-hexyl-2, ethyl-hexan-amid-1.6 mol/L nitric acid complex $$>$$ NN'-dibutyl-butyl-amid-1.7 mol/L nitric acid complex $$>$$ NN'-di-isobutyl-isobutyl-amid-1.5 mol/L nitric acid complex. (3)In the case of DOBA extraction solvent, the dissolving rate increased by about 2 order with the increase of the nitric acid concentration from 1mol/L up to 3.5mol/L and strong influence of the nitric acid concentration was confirmed to the dissolving rate. (4)In the tests with the NN'-dibutyl-butyl-amid-1.7 mol/L nitrie acid complex and NN'-di-isobutyl-isobutyl-amid-1.5 mol/L nitric acid complex, the DF values of Zr, Ru and Ce increased with the elapse of the test duration and exceeded 100 after 150 hours of test duration. On the other hand, the DF value indicated around 1 for Sr, Mo and Pd, and around 0.1 for Nd. (5)In the test with the NN'-hexyl-2-ehyl-hexan-amid-1.6 mol/L nitric acid complex, significant difference wasn't observed in the tendency of the elapsed change among the DF values of the FP elements. The DF values of all FP elements except Nd and Pd exceeded 100 after 100 ...

JAEA Reports

Dissolution of uranium oxide TBP-HNO$$_{3}$$ complex

Mori, Yukihide*; Shimada, Takashi*; Kosaka, Yuji*; Mizuno, Mineo*

JNC TJ8400 2003-013, 69 Pages, 2002/12

JNC-TJ8400-2003-013.pdf:3.53MB

As a head end process for the pulverization of the spent fuel, the mechanical method (the shredder method) and the pyro-chemical method (oxidization heat-treatment) have been examined. UO$$_{2}$$ is a main ingredient of Uranium oxide powder by the mechaical method, and U$$_{3}$$O$$_{8}$$ is that by the pyro-chemical method. Moreover, the particle size of the pulverized powder depend on the conditions of the pulverizing process. As it was considered that the difference of dissolution rates of samples was caused by the difference of sample chemical forms and dissolution temperature, parametric surveys on chemical form and particle size of powder and dissolution temperature were carried out, and the following results were obtained. (1)The remarkable difference of dissolution rate between U$$_{3}$$3O$$_{8}$$ powder(average particle size 3.7$$mu$$m) and UO$$_{2}$$ powder (average particle size 2.4$$mu$$m) which have comparatively similar particle size was not observed. (2)It was confirmed that the dissolution rate became lower according to the particle size increase (average particle size 2.4$$mu$$m$$sim$$1mm) And it was considered that dissolution rate had strong dependency on particle size, according to the results that the powder with 1mm particle size did not dissolute completely after 5 hours test. (3)The temperature dependency of the dissolution rate was confirmed by dissolution test with UO$$_{2}$$ powder (average particle size 2.4$$mu$$m $$sim$$ 1mm). The higher dissolution rate was obtained in the higher dissolution temperature, and 11 kcal/mol was obtained as activation energy of dissolution. (4)In the dissolution test of UO$$_{2}$$ powder, the nitric acid concentration started to change earlier than that of U$$_{3}$$O$$_{8}$$ powder and concentration change range became larger compared with that in the dissolution test of U$$_{3}$$O$$_{8}$$ powder. It was considered that those differences were caused by difference in mole ratio of Uranium and nitric acid which are consumed in the ...

Journal Articles

Single-crystal growth of transition metal oxides at high pressures of several GPa

Azuma, Masaki*; Saito, Takashi*; Ishiwata, Shintaro*; Yoshida, Hirofumi*; Takano, Mikio*; Kosaka, Yuki*; Takagi, Hidenori*; Utsumi, Wataru

Journal of Physics; Condensed Matter, 14(44), p.11321 - 11324, 2002/11

 Times Cited Count:11 Percentile:50.72(Physics, Condensed Matter)

no abstracts in English

JAEA Reports

Evaluation of incident mitigation systems in Tokai reprocessing plant

Omori, Eiichi; Sudo, Toshiyuki; ; Kosaka, Ichiro; ; ;

JNC TN8410 99-005, 274 Pages, 1999/02

JNC-TN8410-99-005.pdf:19.02MB

Through the investigation of the cause of the fire and explosion incident at Bituminization Demonstration Facility of JNC Tokai Works, the lesson learned is that the safety assessment is necessary even for the licensed facilities by recent knowledge. The safety assessment has been conducted for the facilities in Tokai Reprocessing Plant by recent knowledge and operational experience. This report describes the evaluation results of the incident mitigation systems and the hypothetical accidents. In the evaluation of the incident mitigation system, supposed incidents were solvent fire, rapid reaction of hydrazine decomposition, leakage of radioactive material and loss of power supply. The evaluation was focused on the integrity of the filters in case of the fire and the rapid leaction, the availability of the recovery system in case of the radioactive leakage, and so on. As a result of evaluation, several improvements were pointed out to be necessary for the prevention of incident magnification. In the evaluation of the hypothetical accidents, criticality at a dissolver and fire at solvent extraction mixer-settlers were hypothesized. It was confirmed that the Tokai Reprocessing Plant is still distant enough from the population.

JAEA Reports

Development of reconstitution technique of irradiated specimen; Progress report for FY1993 on cooperated research between JAERI and IHI

Onizawa, Kunio; Fukaya, Kiyoshi; Nishiyama, Yutaka; Suzuki, Masahide; Shibata, Katsuyuki; Kosaka, Atsuo; *; *; *; *; et al.

JAERI-Tech 94-017, 58 Pages, 1994/09

JAERI-Tech-94-017.pdf:2.74MB

no abstracts in English

Journal Articles

Results of reliability test program on light water reactor piping

Shibata, Katsuyuki; Isozaki, Toshikuni; Ueda, Shuzo; Kurihara, Ryoichi; Onizawa, Kunio; Kosaka, Atsuo

Nucl. Eng. Des., 153, p.71 - 86, 1994/00

 Times Cited Count:11 Percentile:68.99(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Overview of reliability test program on primary coolant piping of light water reactors

Shibata, Katsuyuki; Isozaki, Toshikuni; Ueda, Shuzo; Kurihara, Ryoichi; Onizawa, Kunio; Kosaka, Atsuo

Nihon Genshiryoku Gakkai-Shi, 35(10), p.923 - 939, 1993/10

 Times Cited Count:1 Percentile:18.76(Nuclear Science & Technology)

no abstracts in English

30 (Records 1-20 displayed on this page)