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Journal Articles

Soin-contrast-variation neutron scattering; Innovation in structural analysis

Kumada, Takayuki

Hamon, 36(2), p.62 - 65, 2026/05

no abstracts in English

Journal Articles

Quantitative evaluation of confined water distribution in ionomers within catalyst layers of fuel cells

Iwase, Hiroki*; Arima-Osonoi, Hiroshi*; Harada, Masashi*; Kumada, Takayuki

Hamon, 36(2), p.84 - 88, 2026/05

no abstracts in English

Journal Articles

Spin-contrast-variation small-angle neutron scattering study of fully and partially swollen silica-filled rubber

Noda, Yohei*; Kumada, Takayuki; 7 of others*

Journal of Applied Crystallography, 59(2), p.492 - 512, 2026/04

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

Journal Articles

Journal Articles

Magnetic-lens-generated polarized neutron beam with enhanced intensity and Q resolution for small-angle neutron scattering

Hiroi, Kosuke; Nakabe, Rintaro; Oku, Takayuki; Kumada, Takayuki; Motokawa, Ryuhei

Journal of Applied Crystallography, 59(1), p.69 - 79, 2026/02

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

Journal Articles

Phase diagram of the polystyrene/near-critical water system

Shibata, Motoki*; Takenaka, Mikihito*; Motokawa, Ryuhei; Kumada, Takayuki; Ueda, Yuki; Miyazaki, Tsukasa*; Nakanishi, Yohei*; Abe, Jun*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; et al.

Polymer, 340, p.129203_1 - 129203_7, 2025/12

 Times Cited Count:0 Percentile:0.00(Polymer Science)

Journal Articles

Introduction to recent research in structural food science

Nakagawa, Hiroshi; Hirata, Yoshinobu; Kumada, Takayuki

Shiki, 69, p.5 - 9, 2025/12

The physical properties of food, such as texture, shelf life, and stability, are determined by a hierarchical structure from molecular-scale interactions within food ingredients to macroscopic tissue structures. Elucidating the relationship between microstructure and macroscopic properties is a key theme in food science. In recent years, the perspective of viewing food as soft matter has gained traction. Consequently, numerous studies aim to establish a unified framework for understanding the structural properties of food, which share commonalities with gels, colloids, liquid crystals, and amorphous materials, across scales from molecular and nanoscale to millimeter scale. We introduce the latest findings in structural food science research linking molecular structures to macroscopic properties, focusing primarily on studies utilizing neutron scattering. It also covers the physicochemical states of food materials that control food properties such as water content and amorphous states within foods, alongside cutting-edge analytical techniques.

Journal Articles

Formation of rod-like particles with periodic interior by hydroxypropylmethyl cellulose samples with narrow molar mass distributions in aqueous solutions

Yoshida, Misato*; Arai, Kengo*; Nakagawa, Daiki*; Horikawa, Yoshiki*; Iwase, Hiroki*; Kumada, Takayuki; Motokawa, Ryuhei; Shikata, Toshiyuki*

Biomacromolecules, 26(11), p.8332 - 8342, 2025/11

 Times Cited Count:1 Percentile:38.91(Biochemistry & Molecular Biology)

Journal Articles

None

Kumada, Takayuki

Denshi Supin Saiensu, (45), p.103 - 106, 2025/10

no abstracts in English

Journal Articles

Nanostructural analysis of composite materials by spin-contrast variation small-angle neutron scattering and neutron reflectometry

Kumada, Takayuki

For the Future of Hydrogen Science and Technology, 3(1), p.2 - 6, 2025/10

Journal Articles

Effects of the size of fillers on viscoelasticity in the glassy state of poly(styrene-$$co$$-butadiene) reinforced by carbon black

Watanabe, Yuki*; Kumagawa, Daiki*; Karitani, Shu*; Inoue, Tadashi*; Iwabuki, Hitoshi*; Nakanishi, Yohei*; Shibata, Motoki*; Motokawa, Ryuhei; Sugita, Tsuyoshi; Ueda, Yuki; et al.

Macromolecules, 58(16), p.8641 - 8648, 2025/08

 Times Cited Count:0 Percentile:0.00(Polymer Science)

Journal Articles

Confined water distribution in the ionomer within the catalyst layers of polymer electrolyte fuel cells; A Small-angle neutron scattering study

Iwase, Hiroki*; Arima, Hiroshi*; Harada, Masashi*; Kumada, Takayuki

Chemical Engineering Journal, 510, p.161321_1 - 161321_11, 2025/04

 Times Cited Count:2 Percentile:43.02(Engineering, Environmental)

Journal Articles

None

Kumada, Takayuki; Iwahara, Daisuke*

Isotope News, (798), p.26 - 27, 2025/04

no abstracts in English

Journal Articles

Kinetics of structural changes in starch retrogradation observed by simultaneous SANS/FTIR-ATR measurements

Hirata, Yoshinobu*; Kaneko, Fumitoshi*; Radulescu, A.*; Nishizu, Takahisa*; Katsuno, Nakako*; Imaizumi, Teppei*; Motokawa, Ryuhei; Kumada, Takayuki; Nakagawa, Hiroshi

Journal of Applied Glycoscience, 72(1), p.7201102_1 - 7201102_9, 2025/02

A simultaneous measurement system of SANS/FTIR-ATR was applied to record multiple structural changes in potato starch during retrogradation. In the SANS patterns, the shoulder-like peak becomes more pronounced with time. The peak intensity, Imax, which represents the amount of orderly arranged double helical structures, increased over time, showing that starch reassembled orderly on the nanoscale upon retrogradation. In the FTIR-ATR spectra, the increase of the ratio of absorptions at 1042 cm$$^{-1}$$ and 1016 cm$$^{-1}$$, indicating the amount of short-range ordered structure in starch increased during retrogradation. The time to obtain half of the equilibrium value for $$R_{1042/1016}$$ was larger than that for Imax. Changes in the short-range ordered structure of starch were observed to converge prior to changes in the nanostructure. These results indicate that the double-helix structures are initially formed by amylopectin side chains, and then these double-helical structures are arranged orderly.

Journal Articles

Nanostructure analysis of composite materials using polarized neutrons and polarized protons

Kumada, Takayuki

Shiki, 63, p.2 - 5, 2024/07

We introduce recent studies of spin-contrast-variation neutron scatterings, which utilizes the property that scattering power of neutron against proton remarkably depends on their relative spin directions, to reveal nanostructure of composite materials.

Journal Articles

Low-background ultrahigh-purity aluminium window for small-angle neutron scattering using monochromatic cold neutrons

Kumada, Takayuki; Motokawa, Ryuhei; Iwase, Hiroki*

Journal of Applied Crystallography, 57(Part 3), p.728 - 733, 2024/06

 Times Cited Count:12 Percentile:93.80(Chemistry, Multidisciplinary)

Journal Articles

Analyses of hierarchical structures in SBR rubber by using contrast-variation SANS; Effects of a silane coupling agent

Nakanishi, Yohei*; Shibata, Motoki*; Sawada, Satoshi*; Kondo, Hiroaki*; Motokawa, Ryuhei; Kumada, Takayuki; Yamamoto, Katsuhiro*; Mita, Kazuki*; Miyazaki, Tsukasa*; Takenaka, Mikihito*

Polymer, 306, p.127209_1 - 127209_7, 2024/06

 Times Cited Count:9 Percentile:65.72(Polymer Science)

Journal Articles

Nanometer-thick crystalline ice plates in rapidly-frozen glucose solution observed by spin-contrast-variation small-angle neutron scattering

Kumada, Takayuki; Nakagawa, Hiroshi; Miura, Daisuke; Sekine, Yurina; Motokawa, Ryuhei; Hiroi, Kosuke; Inamura, Yasuhiro; Oku, Takayuki; Oishi, Kazuki*; Morikawa, Toshiaki*; et al.

Hamon, 34(2), p.50 - 53, 2024/05

Spin-contrast-variation (SCV) small-angle neutron scattering (SANS) enabled us to determine structure of nano-ice crystals that were generated in rapidly frozen sugar solution. In the frozen glucose solution, we found that the nano-ice crystals formed a planar structure with a radius larger than several tens of nanometers and a thickness of 2-3 nm, which was close to the critical nucleation size of ice crystals in supercooled water. This result suggests that the glucose molecules were preferentially bound to a specific face of nano-ice crystals, and then blocked the crystal growth perpendicular to that face.

Journal Articles

Interpenetration of rubber and silane coupling agent on an inorganic substrate revealed by spin-contrast-variation neutron reflectivity

Kumada, Takayuki; Iwahara, Daisuke*; Nishitsuji, Shotaro*; Akutsu, Kazuhiro*; Miura, Daisuke; Motokawa, Ryuhei; Sugita, Tsuyoshi; Torikai, Naoya*; Amino, Naoya*; Oku, Takayuki; et al.

Journal of Physical Chemistry C, 128(21), p.8797 - 8802, 2024/05

 Times Cited Count:6 Percentile:42.42(Chemistry, Physical)

We elucidated the entanglement of polybutadiene and silane coupling agent (SCA) molecules bound to Si substrates using spin-contrast-variation (SCV) neutron reflectivity (NR). In an annealed integral blend film of polybutadiene and SCA, a SCA layer generated on the Si substrate was composed of 70 vol. percent SCA molecules extended perpendicularly from the silicon substrate and entangled with 30 vol. percent polybutadiene molecules. By contrast, in an SCA-precoated polybutadiene film, the SCA-precoated layer is composed of densely packed SCA molecules forming crystal-like structure, and thus did not become entangled with the postcoated polybutadiene molecules. This poor entanglement resulted in poor binding between polybutadiene and Si substrate.

Journal Articles

New standard for low temperature sample environment at JAEA/JRR-3

Kaneko, Koji; Tabata, Chihiro; Hagihara, Masato; Yamauchi, Hiroki; Oba, Yojiro; Kumada, Takayuki; Kubota, Masato; Kojima, Yuki*; Nabatame, Nozomi; Sasaki, Miki; et al.

JPS Conference Proceedings (Internet), 41, p.011015_1 - 011015_6, 2024/03

248 (Records 1-20 displayed on this page)