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Journal Articles

Structural and thermal confinement of Schwarz crystals

Huang, D.*; Fu, H.*; Lyu, M.*; Feng, Y.*; Kajimoto, Ryoichi; Nakamura, Mitsutaka; Honda, Takashi*; Liu, E.*; Li, B.*; Li, X.*; et al.

Physical Review Research (Internet), 8(3), p.033017_1 - 033017_7, 2026/07

Journal Articles

Assessing and tackling the barocaloric fatigue for applicable solid-state refrigeration

Xue, J.*; Huang, D.*; Hattori, Takanori; Li, L.*; Feng, Y.*; Wang, H.*; Fan, X.*; Yao, J.*; Wang, Y.*; Liu, Z.*; et al.

Applied Physics Letters, 128(20), p.201903_1 - 201903_8, 2026/05

 Times Cited Count:0 Percentile:0.00(Physics, Applied)

The cycling fatigue and barocaloric response of NH$$_4$$I is directly assessed under loading-unloading cycles with stress up to 100,MPa, with the adiabatic temperature change ($$Delta T_{mathrm{ad}}$$) decaying from 15,K to approximately 0.8,K after 100 cycles. $emph{In situ}$ X-ray diffraction, Raman spectroscopy, and neutron diffraction concertedly reveal the existence of the residual high-pressure phase even after the first unloading, whose fraction is rapidly increased to 90% at the 100th cycle. A phenomenological model is developed to elucidate this fatigue behavior, and an excellent agreement with experimental data has been achieved. To relieve the intergranular stress and enhance the mobility of grains, we encapsulate the composite of NH$$_4$$I particles and silicone oil into a 3D-printed polymer shell. Such an architectural tailoring has markedly improved the cyclic stability of the barocaloric effect with $$Delta T_{mathrm{ad}}$$ rising to c.a. 4.6,K after 100 cycles. Our results establish a fundamental understanding of the barocaloric fatigue behavior and pave a feasible route to applicable barocaloric cooling technology.

Journal Articles

Interplay of dynamic strain aging and dynamic precipitation in the Portevin-Le Ch$^{a}$telier effect in an Al-Mg-Zn-based crossover aluminum alloy

Zhang, X.*; Li, Y.*; Wei, S.*; Guo, H.*; He, Z.*; Yang, C.*; Gong, W.; Harjo, S.; Zhou, D.*; Li, Z.*; et al.

Acta Materialia, 308, p.121990_1 - 121990_18, 2026/04

 Times Cited Count:7 Percentile:98.38(Materials Science, Multidisciplinary)

Journal Articles

Super-ductile magnesium alloy at room temperature

Li, H.*; Gong, W.; Kawasaki, Takuro; Harjo, S.; Zheng, R.*; 6 of others*

Acta Materialia, 305, p.121884_1 - 121884_10, 2026/02

 Times Cited Count:3 Percentile:96.93(Materials Science, Multidisciplinary)

Journal Articles

Shape evolution in neutron-rich Rh isotopes; First measurement of negative-parity isomers in $$^{117,119}$$Rh

Zhang, J. Z.*; Chen, Z. Q.*; Qu, T.*; Wang, Y. K.*; Li, Z. H.*; Orlandi, R.; 62 of others*

Physics Letters B, 873, p.140144_1 - 140144_9, 2026/02

 Times Cited Count:0 Percentile:0.00(Astronomy & Astrophysics)

Journal Articles

Fused-ring nanothread synthesized via high-pressure polymerization of naphthalene

Fei, Y.*; Wang, Y.*; Zhang, J.*; Liu, J.*; Zhao, Z.*; Hattori, Takanori; Abe, Jun*; Dong, X.*; Mao, H.-K.*; Zheng, H.*; et al.

Chemistry; A European Journal, p.e71096_1 - e71096_11, 2026/00

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

We systematically investigated the high-pressure polymerization of naphthalene, the simplest polycyclic aromatic hydrocarbons (PAHs), using multiple cutting-edge methods. Naphthalene molecules were stacked in herringbone style, and underwent [4+2] cycloaddition reactions along the a-b direction above 20 GPa, yielding one-dimensional Carbon nanothreads (CNThs). In contrast to the formation of many CNThs, the nucleation of the CNThs occurs during compression while their growth proceeds during decompression, which is likely prevalent among herringbone-stacked aromatics. The unit cell of the obtained CNTh crystal is determined and the possible structure of the CNTh product is also proposed. Our research reveals the polymerization characteristics of naphthalene under high pressure, highlighting the fact that the slip-angle plays an important role in governing the polymerization pathway.

Journal Articles

Grain size dependence of $$<hkl>$$ intergranular lattice strain generated by plastic deformation in ferritic steel

Tomota, Yo*; Li, H.*; Tsuchida, Noriyuki*; Gong, W.; Harjo, S.; Omura, Takahito*

Materials Science & Engineering A, 946, p.149136_1 - 149136_12, 2025/11

 Times Cited Count:2 Percentile:46.97(Nanoscience & Nanotechnology)

Journal Articles

Seniority structure in neutron-rich nucleus $$^{128}$$Ag; Evidence for robustness of $$N$$=82 shell closure in silver isotopes

Luo, D. W.*; Zhang, J. Z.*; Li, Z. H.*; Orlandi, R.; 64 of others*

Physical Review Letters, 134(23), p.232502_1 - 232502_7, 2025/06

 Times Cited Count:4 Percentile:79.04(Physics, Multidisciplinary)

Journal Articles

Pressure-induced polymerization of 1,4-difluorobenzene towards fluorinated diamond nanothreads

Che, G.*; Fei, Y.*; Tang, X.*; Zhao, Z.*; Hattori, Takanori; Abe, Jun*; Wang, X.*; Ju, J.*; Dong, X.*; Wang, Y.*; et al.

Physical Chemistry Chemical Physics, 27(2), p.1112 - 1118, 2025/01

 Times Cited Count:4 Percentile:48.43(Chemistry, Physical)

Pressure-induced polymerization (PIP) of aromatic molecules has emerged as an effective method for synthesizing various carbon-based materials. In this work, PIP of 1,4-difluorobenzene (1,4-DFB) was investigated. ${it In situ}$ high-pressure investigations of 1,4-DFB reveal a phase transition at approximately 12.0 GPa and an irreversible chemical reaction at 18.7 GPa. Structural analysis of the product and the kinetics of the reaction uncovered the formation of pseudohexagonal stacked fluoro-diamond nanothreads with linear growth. Compared to the crystal structures of benzene under high pressure, 1,4-DFB exhibits higher compression along the [001] axis. The anisotropic compression is attributed to the stronger H$$cdot cdot cdot pi$$ interaction along the [01$$overline{1}$$] axis and the potential compression-inhibiting H$$cdot cdot cdot$$F interactions along the [100] and [010] axes, and it facilitates a possible reaction pathway along the [01$$overline{1}$$] axis. This work emphasizes the crucial role of functionalization in modulating molecular stacking and influencing the reaction pathway.

Journal Articles

Application of neutron characterization techniques to metallic structural materials

Wang, Y.*; Gong, W.; Su, Y. H.; Li, B.*

Acta Metallurgica Sinica, 60(8), p.1001 - 1016, 2024/08

 Times Cited Count:6 Percentile:29.98(Metallurgy & Metallurgical Engineering)

Journal Articles

Spectral evidence for Dirac spinons in a kagome lattice antiferromagnet

Zeng, Z.*; Zhou, C.*; Zhou, H.*; Han, L.*; Chi, R.*; Li, K.*; Kofu, Maiko; Nakajima, Kenji; Wei, Y.*; Zhang, W.*; et al.

Nature Physics, 20(7), p.1097 - 1102, 2024/07

 Times Cited Count:30 Percentile:96.19(Physics, Multidisciplinary)

Journal Articles

Possibility of secondary $$i$$- and $$s$$-processes following $$r$$-process in the collapsar jet

He, Z.*; Kajino, Toshitaka*; Kusakabe, Motohiko*; Zhou, S.-G.*; Koura, Hiroyuki; Chiba, Satoshi*; Li, H.*; Lin, Y.*

Astrophysical Journal Letters, 966(2), p.L37_1 - L37_7, 2024/05

 Times Cited Count:9 Percentile:69.49(Astronomy & Astrophysics)

Journal Articles

Microscopic origin of the spin-reorientation transition in the kagome topological magnet TbMn$$_{6}$$Sn$$_{6}$$

Huang, Z.*; Wang, W.*; Ye, H.*; Bao, S.*; Shangguan, Y.*; Liao, J.*; Cao, S.*; Kajimoto, Ryoichi; Ikeuchi, Kazuhiko*; Deng, G.*; et al.

Physical Review B, 109(1), p.014434_1 - 014434_9, 2024/01

 Times Cited Count:7 Percentile:56.50(Materials Science, Multidisciplinary)

Journal Articles

Deformation mechanism of a strong and ductile maraging steel investigated using ${it in situ}$ X-ray synchrotron diffraction

Li, H.*; Liu, Y.*; Zhao, W.*; Liu, B.*; Tominaga, Aki; Shobu, Takahisa; Wei, D.*

International Journal of Plasticity, 165, p.103612_1 - 103612_20, 2023/06

 Times Cited Count:51 Percentile:97.57(Engineering, Mechanical)

In order to clarify the strength properties of Co-free maraging steel, ${it in situ}$ tensile experiment using high energy synchrotron X-ray diffraction was performed. Diffraction profiles from the martensitic and austenitic phases were obtained, and their strength and width were observed to vary as loading. Analysis of the diffraction profiles showed that the content of martensite in the as-aged material decreased slowly at low stress levels and decreased rapidly at high stress levels. On the other hand, the austenite phase in the as-solution materials was significantly transformed the martensite phase as the stress increased. It was clarified to be responsible for their respective strength properties.

Journal Articles

Pressure-modulated magnetism and negative thermal expansion in the Ho$$_2$$Fe$$_{17}$$ intermetallic compound

Cao, Y.*; Zhou, H.*; Khmelevskyi, S.*; Lin, K.*; Avdeev, M.*; Wang, C.-W.*; Wang, B.*; Hu, F.*; Kato, Kenichi*; Hattori, Takanori; et al.

Chemistry of Materials, 35(8), p.3249 - 3255, 2023/04

 Times Cited Count:9 Percentile:49.07(Chemistry, Physical)

Hydrostatic and chemical pressure are efficient stimuli to alter the crystal structure and are commonly used for tuning electronic and magnetic properties in materials science. However, chemical pressure is difficult to quantify and a clear correspondence between these two types of pressure is still lacking. Here, we study intermetallic candidates for a permanent magnet with a negative thermal expansion (NTE). Based on in situ synchrotron X-ray diffraction, negative chemical pressure is revealed in Ho$$_2$$Fe$$_{17}$$ on Al doping and quantitatively evaluated by using temperature and pressure dependence of unit cell volume. A combination of magnetization and neutron diffraction measurements also allowed one to compare the effect of chemical pressure on magnetic ordering with that of hydrostatic pressure. Intriguingly, pressure can be used to control suppression and enhancement of NTE. Electronic structure calculations indicate that pressure affected the top of the majority band with respect to the Fermi level, which has implications for the magnetic stability, which in turn plays a critical role in modulating magnetism and NTE. This work presents a good example of understanding the effect of pressure and utilizing it to control properties of functional materials.

Journal Articles

Mg-ion storage materials based on MnO$$_{2}$$ frameworks

Shimokawa, Kohei*; Hatakeyama, Takuya*; Li, H.*; Ichitsubo, Tetsu

Current Opinion in Electrochemistry, 38, p.101209_1 - 101209_8, 2023/04

 Times Cited Count:11 Percentile:22.42(Chemistry, Physical)

Journal Articles

Mg-Zn-Mn oxide systems for a rechargeable Mg-battery cathode

Ye, X.*; Shimokawa, Kohei*; Kezuka, Yuto*; Hatakeyama, Takuya*; Li, H.*; Ichitsubo, Tetsu

Journal of Physical Chemistry C, 127(11), p.5210 - 5218, 2023/03

 Times Cited Count:3 Percentile:16.43(Chemistry, Physical)

Journal Articles

A Colossal barocaloric effect induced by the creation of a high-pressure phase

Jiang, X.*; Hattori, Takanori; Xu, X.*; Li, M.*; Yu, C.*; Yu, D.*; Mole, R.*; Yano, Shinichiro*; Chen, J.*; He, L.*; et al.

Materials Horizons, 10(3), p.977 - 982, 2023/03

 Times Cited Count:37 Percentile:89.15(Chemistry, Multidisciplinary)

As a promising environment-friendly alternative to current vapor-compression refrigeration, solid-state refrigeration based on the barocaloric effect has been attracting world wide attention. Generally, both phases in which a barocaloric effect occurs are present at ambient pressure. Here, instead, we demonstrate that KPF$$_{6}$$ exhibits a colossal barocaloric effect due to the creation of a high-pressure rhombohedral phase. The phase diagram is constructed based on pressure-dependent calorimetric, Raman scattering, and neutron diffraction measurements. The present study is expected to provide an alternative routine to colossal barocaloric effects through the creation of a high-pressure phase.

Journal Articles

Si-addition contributes to overcoming the strength-ductility trade-off in high-entropy alloys

Wei, D.*; Gong, W.; Tsuru, Tomohito; Lobzenko, I.; Li, X.*; Harjo, S.; Kawasaki, Takuro; Do, H.-S.*; Bae, J. W.*; Wagner, C.*; et al.

International Journal of Plasticity, 159, p.103443_1 - 103443_18, 2022/12

 Times Cited Count:157 Percentile:99.82(Engineering, Mechanical)

Journal Articles

Spin fluctuations in the 112-type iron-based superconductor Ca$$_{0.82}$$La$$_{0.18}$$Fe$$_{0.96}$$Ni$$_{0.04}$$As$$_{2}$$

Xie, T.*; Liu, C.*; Kajimoto, Ryoichi; Ikeuchi, Kazuhiko*; Li, S.*; Luo, H.*

Journal of Physics; Condensed Matter, 34(47), p.474001_1 - 474001_8, 2022/11

 Times Cited Count:0 Percentile:0.00(Physics, Condensed Matter)

127 (Records 1-20 displayed on this page)