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論文

Enhanced elastocaloric cooling beyond Clausius-Clapeyron limits

Song, Y.*; Xu, S.*; 大森 俊洋*; 川崎 卓郎; 石川 喜久*; 鬼柳 亮嗣; 貝沼 亮介*

Nature Communications (Internet), 17, p.3747_1 - 3747_8, 2026/04

 被引用回数:0 パーセンタイル:0.00(Multidisciplinary Sciences)

The elastocaloric effect, driven by stress-induced martensitic transformations, offers a promising route toward efficient and environmentally friendly solid-state cooling. However, its practical implementation has been hindered by an inherent trade-off: materials exhibiting large isothermal entropy changes typically operate over narrow temperature windows, thereby limiting their overall cooling performance. Here, we demonstrate an elastocaloric response in a Ti-Al-Cr superelastic alloy that overcomes this limitation. Direct measurements reveal a pronounced elastocaloric cooling effect over an ultra-wide temperature range of 305 K, from 97 K to 402 K. This temperature span exceeds that predicted by the Clausius-Clapeyron relationship (235 K), indicating a significant deviation from conventional thermodynamic expectations. At room temperature, a large adiabatic temperature change of ~10 K is directly measured, corresponding to a cooling output of 5.76 Jg$$^{-1}$$ and a material coefficient of performance of 4.6, demonstrating competitive cooling performance at practical operating conditions. In addition, the elastocaloric response is maintained over the entire temperature range despite the expected decrease in entropy change at lower temperatures, indicating that the conventional trade-off between temperature span and cooling strength is effectively mitigated. This exceptional behavior originates from a combination of anomalous temperature dependence of the critical stress for martensitic transformation and high mechanical strength, which together enable fully reversible stress-induced transformations across a broad thermal domain. Our findings reveal a new regime of elastocaloric behavior and establish a guiding principle for overcoming the apparent limitations imposed by Clausius-Clapeyron-based descriptions in caloric materials.

論文

Magnetic signature of chiral phonons revealed by neutron spectroscopy in ferrimagnetic Fe$$_{1.75}$$Zn$$_{0.25}$$Mo$$_{3}$$O$$_{8}$$

Bao, S.*; Liao, J.*; Huang, Z.*; Shangguan, Y.*; Ma, Z.*; Zhang, B.*; Cheng, S.*; Xu, H.*; Song, Z.*; Dong, S.*; et al.

Physical Review Letters, 136(9), p.096502_1 - 096502_8, 2026/03

 被引用回数:3 パーセンタイル:80.48(Physics, Multidisciplinary)

Lattice vibrations can carry angular momentum and magnetic moments under broken inversion or time-reversal symmetry, forming so-called chiral phonons. While such excitations have been explored in nonmagnetic systems via optical probes, their direct detection in magnetic materials and coupling to spin excitations remain largely unexplored. Here, using neutron spectroscopy, sensitive to both nuclear and magnetic scattering, we reveal the magnetic signature of chiral phonons in ferrimagnetic Fe$$_{1.75}$$Zn$$_{0.25}$$Mo$$_{3}$$O$$_{8}$$ with Curie temperature $$T_C sim 49$$ K. Below $$T_C$$, we observe enhanced magnetic scattering of phonons at small momenta, arising from strong magnon-phonon coupling. In addition, out-of-plane intensity modulation, phonon mode splitting, and field-induced Zeeman shifts are observed, all closely associated with the ferrimagnetic order. These features vanish above $$T_C$$, where phonon spectra are dominated by nuclear scattering. These observations demonstrate the existence of chiral phonons carrying substantial magnetic moments that directly contribute to magnetic scattering, and establish neutron spectroscopy as a powerful, momentum-resolved probe of their magnetic character.

論文

Magnetic evolution, phase transitions, and electronic band structure of the ferrotoroidic candidate Ba$$_6$$Cr$$_2$$S$$_{10}$$

Zhao, G.*; Li, J.*; Zhang, J.*; 小嶋 健児*; Cai, Y.*; 伊藤 孝; Yoon, S. W.*; Wang, X.*; 前川 禎通*; Su, G.*; et al.

Physical Review Research (Internet), 8(1), p.013331_1 - 013331_10, 2026/03

Ferrotoroidic materials, which break both time- and space-reversal symmetries to enhance magnetoelectric responses, are of great interest for applications. Ba$$_6$$Cr$$_2$$S$$_{10}$$, a recently synthesized quasi-one-dimensional ferrotoroidic candidate, combines polarization, magnetization, and toroidal moment, yet its electronic band structure, magnetic evolution, and phase transitions remain incompletely understood to date. Here, we investigate Ba$$_6$$Cr$$_2$$S$$_{10}$$, using electrical transport, direct current magnetization, alternating current susceptibility, specific heat, and muon spin rotation ($$mu$$SR) measurements, along with various first-principles calculations. Electrical transport measurements and density functional theory confirm a narrow band gap ($$sim$$0.707~eV, experimentally; $$sim$$0.680~eV, theoretically). $$mu$$SR measurements reveal that static magnetism dominates down to 2~K, with an ordered volume fraction of $$sim$$89% at this temperature. Two distinct transitions are identified: one around the N$'{e}$el temperature [$$T_{rm N}=(8pm 1)$$~K] and another corresponding to a phase transition near 30~K, as consistently indicated by our complementary experimental techniques. The absence of dynamic critical behaviors and the lack of a $$lambda$$-type specific heat anomaly are consistent with a first-order-like transition at $$T_{rm N}$$. Based on various complementary experimental results and theoretical calculations, we propose a hypothesis that the $$sim$$30~K broad feature arises from the complex interplay between crystal structure distortion and magnetic coupling, which is potentially directly linked to ferrotoroidicity. As the first study integrating $$mu$$SR with complementary experiments and first-principles calculations to explore ferrotoroidicity, this work provides key insights into the underlying physics of Ba$$_6$$Cr$$_2$$S$$_{10}$$ and related compounds in this area.

論文

Coupled dimerized alternating-bond quantum spin chains in the distorted honeycomb-lattice magnet Cu$$_{5}$$SbO$$_{6}$$

Piyakulworawat, C.*; 森田 克洋*; 福元 好志*; Hsieh, W.-Y.*; Chen, W.-T.*; 中島 健次; 河村 聖子; Zhao, Y.*; Wannapaiboon, S.*; Piyawongwatthana, P.; et al.

Physical Review Research (Internet), 8(1), p.013247_1 - 013247_16, 2026/03

歪んだハニカム化合物Cu$$_{5}$$SbO$$_{6}$$の中性子非弾性散乱および磁化データを、一次のダイマー展開計算と量子モンテカルロシミュレーションを用いて解析した。これまでに提案されたハニカム格子モデルとは対照的に、この系は相互作用するダイマースピン鎖を有し、鎖に沿って強磁性-反強磁性結合が交互に現れることが示された。さらに、他のCu$$^{2+}$$ベースの歪んだハニカム磁性体で観測される典型的な結合とは異なり、スピン鎖は、予想される層間の鎖間結合ではなく、主にハニカム層間に生じる反強磁性結合を介して結合する。つまり、Cu$$_{5}$$SbO$$_{6}$$の磁気結合スキームが異なることが明らかになった。さらに、X線分光法と透過型電子顕微鏡を利用して、化合物の結晶構造と積層欠陥モデルも従来のモデルをより精密化した。

論文

Spin excitation continuum from degenerate states in the mixed ferro-antiferromagnetic exchange system CeMgAl$$_{11}$$O$$_{19}$$

Gao, B.*; Chen, T.*; Liu, C.*; Klemm, M. L.*; Zhang, S.*; Ma, Z.*; Xu, X.*; Won, C.*; McCandless, G. T.*; Rao, K.*; et al.

Science Advances (Internet), 12(10), p.eaed7778_1 - eaed7778_7, 2026/03

In the search for unconventional magnetism, exotic quantum states are characterized by a lack of order and a broad spin excitation continuum approaching zero temperature. We study the two-dimensional triangular-lattice effective spin-system CeMgAl$$_{11}$$O$$_{19}$$, which shows slight disorder but no magnetic ordering down to 100 millikelvin. Spin-wave analysis in the magnetic-field-polarized state determines the spin Hamiltonian featuring a mixed ferromagnetic-antiferromagnetic nearest-neighbor exchange interaction. This places the system near an exactly solvable point of the spin-triangular-lattice XXZ model with extensive ground-state degeneracy. In zero field, neutron spectroscopy reveals a prominent continuum; we show that this arises from an ensemble average of spin-wave spectra across the degenerate ground-state manifold. This demonstrates that the role of weak quenched disorder can be quantitatively constrained: It inhibits unique ground-state selection and stabilizes a local distribution within the degenerate manifold, yielding continuum-like spectra that necessitate a critical reevaluation of the experimental signatures of exotic quantum states.

論文

Tailoring neutron-shielding boron-metakaolin geopolymers with B$$_{4}$$C filler; Surfactant-driven interfacial and microstructural control

Niu, X.*; Elakneswaran, Y.*; 菊池 亮佑*; Li, A.*; Seralathan, S.*; 平木 義久; 佐藤 淳也; 大杉 武史; 加美山 隆*; Walkley, B.*

Cement and Concrete Research, 200, p.108096_1 - 108096_17, 2026/02

 被引用回数:2 パーセンタイル:23.63(Construction & Building Technology)

The incorporation of boron (B) as a neutron absorber into metakaolin-based geopolymers for the remediation of radioactive debris following nuclear accidents has attracted considerable attention. In this study, boron carbide (B$$_{4}$$C) was employed as a functional filler, while cetyltrimethylammonium bromide (CTAB) acted as both a dispersant and a stabiliser to enhance the neutron shielding properties of metakaolin-based geopolymers. Although the addition of B$$_{4}$$C improved processability via a roller-ball effect and had no discernible impact on the geopolymerisation process, its weakly polar, negatively charged surface led to the formation of a loose, weak-shell interfacial transition zone (ITZ) between the filler and the matrix, thereby reducing mechanical strength and chemical stability. In contrast, CTAB self-assembled into an interdigitated monolayer on the B$$_{4}$$C surface, reversing its surface charge to positive and promoting its uniform dispersion within the matrix. This work offers a promising approach for engineering high-performance, multifunctional geopolymer composites for nuclear and environmental applications.

論文

Incommensurate magnetism drives singular angular magnetoresistance in the magnetic Weyl semimetal CeAlGe

Yao, X.*; Chen, P.*; Verma, R.*; Zhao, X.*; Yang, H.-Y.*; DeBeer-Schmitt, L.*; Aczel, A. A.*; Wu, C.-M.*; Alba Venero, D.*; 大原 高志; et al.

Physical Review Letters, 136(8), p.086702_1 - 086702_6, 2026/02

 被引用回数:1 パーセンタイル:80.48(Physics, Multidisciplinary)

We demonstrate that a multi-k incommensurate magnetic state in the Weyl semimetal CeAlGe gives rise to a singular angular magnetoresistance (SAMR), which is an electrical transport signature capable of detecting magnetic field direction with exceptional precision. In contrast, its sister compound CeAlSi is devoid of both multi-k order and SAMR. We reveal that both phenomena appear upon 57% Ge substitution in CeAlSi1-xGex and coincide with electronic structure changes that soften the single-ion in-plane anisotropy and enhance Weyl-mediated magnetic interactions. These results unveil a remarkable connection between band topology, electronic transport, and collective magnetism in Weyl semimetals.

論文

Formation of high-aspect-ratio nanocavity in LiF crystal using a femtosecond X-ray free-electron laser pulse

Makarov, S. S.*; Zhakhovsky, V. V.*; Grigoryev, S. Yu.*; Chuprov, P.*; Pikuz, T. A.*; Inogamov, N. A.*; Khokhlov, V. A.*; Petrov, Y. V.*; Perov, E. A.*; Shepelev, V. V.*; et al.

Nature Communications (Internet), 16, p.11504_1 - 11504_13, 2025/12

 被引用回数:1 パーセンタイル:0.00(Multidisciplinary Sciences)

We demonstrate that a single 9-keV pulse from X-ray free-electron-laser can form a nanoscale mm-long cavity in LiF. The laser-generated shock pressure results in channel formation with >1,000 length-to-diameter aspect ratio. The development of void is analyzed via continuum and atomistic simulations revealing a sequence of processes leading to the final long cavity structure. This work presents the study of mm-long nanochannel formation by a single high-brilliance X-ray free-electron laser pulse.

論文

Spatial polarization distribution measurements of gamma rays produced by inverse Compton scattering

Yang, Y.*; 平 義隆*; 静間 俊行*; Omer, M.

Proceedings of 16th International Particle Accelerator Conference (IPAC25) (Internet), p.194 - 196, 2025/11

Highly polarized MeV gamma-rays, produced by Laser Compton Scattered (LCS) of a polarized laser with an electron beam, offer a unique probe for basic and applied physics research. As the polarization characteristics of these gamma-rays vary with the position of the beam cross section, it is essential to understand the polarization properties when using polarized gamma-rays. However, detailed measurements of the two-dimensional spatial polarization distribution have not yet been conducted. In the UVSOR synchrotron facility, a polarimeter was developed to measure the spatial polarization distribution of linearly polarized gamma-rays. The polarimeter is based on asymmetry measurements of the Compton scattering cross section. In this conference, we will report on measurement results of the spatial polarization distribution of linearly and circularly polarized LCS gamma-rays. The polarization axis of the polarized gamma-rays was clearly measured to vary with scattering and azimuth angle. In the near future, we plan to use the developed polarimeter to also measure the spatial polarization distribution of gamma-rays generated by an axially symmetric polarized laser.

論文

Generation and measurement of gamma rays with axially symmetric polarization states via Compton scattering

平 義隆*; Yang, Y.*; 静間 俊行*; Omer, M.

Physical Review Research (Internet), 7(3), p.033130_1 - 033130_17, 2025/08

Highly polarized gamma rays with linear or circular polarization are essential light sources for nuclear and particle physics experiments, astronomical detector evaluations, and relativistic electron beam diagnostics. In this study, we demonstrate gamma-ray generation via Compton scattering with unique polarization states, termed axially symmetric polarization. To investigate this, we developed a polarimeter for Compton gamma-ray sources to measure their two-dimensional polarization distribution. We found two methods to generate gamma rays whose polarization axis follows the azimuthal direction. The first method exploits the inherent azimuthal polarization of gamma rays produced using a circularly polarized laser. In this configuration, the gamma rays along the central axis are circularly polarized, while the linear polarization components in the outer region of the beam cross section are aligned azimuthally. The second method utilizes azimuthal polarization that arises in the outer region of the beam due to the incoherent superposition of multiple linearly polarized gamma rays with varying polarization axes, generated by an axially symmetric polarized laser. Additionally, our calculations indicate the feasibility of generating gamma rays with polarization axes oriented along the radial direction. This radial polarization, observed near the beam axis, results from the incoherent superposition of second harmonic gamma rays produced through nonlinear interactions induced by an intense axially symmetric polarized laser.

論文

Experimental studies on spatial resolution of a delay-line current-biased kinetic inductance detector

Vu, TheDang*; 宍戸 寛明*; 相澤 一也; 奥 隆之; 及川 健一; 原田 正英; 小嶋 健児*; 宮嶋 茂之*; 曽山 和彦; 小山 富男*; et al.

Nuclear Instruments and Methods in Physics Research A, 1075, p.170425_1 - 170425_9, 2025/06

 被引用回数:0 パーセンタイル:0.00(Instruments & Instrumentation)

A current-biased kinetic inductance detector (CB-KID) is a novel superconducting detector to construct a neutron transmission imaging system. The characteristics of a superconducting neutron detector have been systematically studied to improve spatial resolution of our CB-KID neutron detector. In this study, we investigated the distribution of spatial resolutions under different operating conditions and examined the homogeneity of spatial resolutions in the detector in detail. We found that controlling the detector temperature precisely enough to realize stable propagation velocities of the signals in the detector to achieve the best spatial resolution with a delay-line CB-KID technique.

論文

Magnetism of kagome metals (Fe$$_{1-x}$$Co$$_x$$)Sn studied by $$mu$$SR

Cai, Y.*; Yoon, S.*; Sheng, Q.*; Zhao, G.*; Seewald, E. F.*; Ghosh, S.*; Ingham, J.*; Pasupathy, A. N.*; Queiroz, R.*; Lei, H.*; et al.

Physical Review B, 111(21), p.214412_1 - 214412_17, 2025/06

 被引用回数:2 パーセンタイル:49.43(Materials Science, Multidisciplinary)

We study the magnetic properties of the metallic kagome system (Fe$$_{1-x}$$Co$$_x$$)Sn by a combination of muon spin relaxation ($$mu$$SR), magnetic susceptibility, and scanning tunneling microscopy (STM) measurements in single crystal specimens with Co concentrations $$x$$ = 0, 0.11, 0.8. In the undoped antiferromagnetic compound FeSn, we find possible signatures for a previously unidentified phase that sets in at $$T^{*}sim 50$$~K, well beneath the Neel temperature $$T_{N}sim 376$$~K as indicated by a peak in the relaxation rate 1/$$T_1$$ observed in zero field (ZF) and longitudinal field (LF) $$mu$$SR measurements, with a corresponding anomaly in the ac and dc susceptibility, and an increase in the static width 1/$$T_2$$ in ZF-$$mu$$SR measurements. No signatures of spatial symmetry breaking are found in STM down to 7~K. Related to the location and motion of muons in FeSn, we confirmed a previous report that about 40% of the implanted muons reside at a field-cancelling high symmetry site at $$T < 250$$~K, while an onset of thermal hopping changes the site occupancy at higher temperatures. In Fe$$_{0.89}$$Co$$_{0.11}$$Sn, where disorder eliminated the field-cancellation effect, all the implanted muons exhibit precession and/or relaxation in the ordered state. In Fe$$_{0.2}$$Co$$_{0.8}$$Sn, we find canonical spin glass behavior with freezing temperature $$T_gsim 3.5$$~K; the ZF and LF-$$mu$$SR time spectra exhibit results similar to those observed in dilute alloy spin glasses CuMn and AuFe, with a critical behavior of $$1/T_1$$ at $$T_g$$ and $$1/T_1to 0$$ as $$Tto 0$$. The absence of spin dynamics at low temperatures makes a clear contrast to the spin dynamics observed by $$mu$$SR in many geometrically frustrated spin systems on insulating kagome, pyrochlore, and triangular lattices. The spin glass behavior of CoSn doped with dilute Fe moments is shown to originate primarily from the randomness of doped Fe moments rather than due to geometrical frustration of the underlying lattice.

論文

Effect of a repulsive three-body interaction on the $$DD^{(*)}K$$ molecule

Pan, Y.-W.*; Lu, J.-X.*; 肥山 詠美子*; Geng, L.-S.*; 保坂 淳

Physical Review D, 111(11), p.114006_1 - 114006_9, 2025/06

 被引用回数:3 パーセンタイル:50.87(Astronomy & Astrophysics)

ガウス展開法を使った三体計算によって$$DD^{(*)}K$$分子に対する斥力三体力の影響を調べた結果を報告する。

論文

Giant Hall effect in a highly conductive frustrated magnet GdCu$$_{2}$$

軽部 皓介*; 大貫 惇睦*; 中島 多朗*; Chen, H.-Y.*; 石塚 大晃*; 木俣 基*; 大原 高志; 宗像 孝司*; 野本 拓也*; 有田 亮太郎*; et al.

npj Quantum Materials (Internet), 10, p.55_1 - 55_9, 2025/06

 被引用回数:8 パーセンタイル:91.11(Materials Science, Multidisciplinary)

The Hall effect is one of the most fundamental but elusive phenomena in condensed matter physics due to the rich variety of underlying mechanisms. Here we report an exceptionally large Hall effect in a frustrated magnet, GdCu$$_{2}$$, with high conductivity. The Hall conductivity at the base temperature shows abrupt sign changes under magnetic fields. Our systematic measurements indicate that the unusual Hall effect can be understood in terms of spin-splitting-induced emergence/disappearance of Fermi pockets as well as skew scattering from spin-chiral cluster fluctuations in a field-polarized state. The present study demonstrates a complex interplay among magnetization, spin-dependent electronic structure, and spin fluctuations in producing the giant Hall effect in highly conductive frustrated magnets with a distorted triangular lattice.

論文

Temperature and time dependence on extraction of Molybdenum-99 hot atoms from neutron-irradiated $$beta$$-molybdenum trioxide particles into water

Yang, Y.*; Ngo, M. C.*; 北川 大凱*; 藤田 善貴; 高橋 由紀子*; 鈴木 達也*; 中山 忠親*; Do, T. M. D.*; 新原 晧一*; 末松 久幸*

RSC Advances (Internet), 15(22), p.17222 - 17229, 2025/05

 被引用回数:1 パーセンタイル:24.56(Chemistry, Multidisciplinary)

本研究は、温度及び加熱時間が$$^{99}$$Moの水への抽出に及ぼす影響を調査したものである。$$beta$$-MoO$$_{3}$$粒子は熱蒸発により合成後、X線回折及び透過型電子顕微鏡を用いて特性評価した。これらを京都大学研究用原子炉によって中性子照射し、照射した$$beta$$-MoO$$_{3}$$粒子を、20$$sim$$50$$^{circ}$$Cの水中にそれぞれ1$$sim$$5.5時間分散させることで$$^{99}$$Moを抽出した。照射後の$$^{99}$$Moの放射能及び抽出した$$beta$$-MoO$$_{3}$$溶液中の$$^{99}$$Moの放射能は高純度ゲルマニウム半導体検出器によって測定した。その結果、水温の上昇と加熱時間の増加により、$$^{99}$$Moの抽出効率は20.31$$pm$$1.24%から66.88$$pm$$1.42%へ向上した。この抽出プロセスの活性化エネルギーは、結晶性MoO$$_{3}$$中の単純な原子拡散の活性化エネルギーよりも低く、水和MoO$$_{3}$$相の形成またはプロトン伝導の活性化エネルギーと同程度か、より高いことを明らかにした。この結果は、水和MoO$$_{3}$$相が$$^{99}$$Moの抽出を加速したことを示唆している。本研究は$$^{99}$$Moホットアトムの抽出における温度と時間依存性を初めて調査したものであり、放射性医薬品である$$^{99}$$Mo/$$^{99m}$$Tcの大規模生産に向けた有望な手法を提供する。

論文

Electrocatalytic nitrous oxide reduction reaction at Sn-modified Pd-Pt single crystalline electrodes in acidic media

加藤 優*; Zheng, J.*; Deng, Y.*; 斎藤 史恵*; 鵜沼 佑規*; 岡 紗雪*; 田村 和久; 八木 一三*

ACS Catalysis, 15(10), p.7710 - 7719, 2025/04

 被引用回数:4 パーセンタイル:60.93(Chemistry, Physical)

Nitrous oxide (N$$_{2}$$O) is a greenhouse and an ozone-depleting gas. Electrocatalytic N$$_{2}$$O reduction reaction (N$$_{2}$$ORR) is known to be catalyzed at noble metal electrodes such as Pd and Pt, and the surface modification of such noble metals with Sn is known to increase the N$$_{2}$$ORR in acidic media. However, the role of Sn at the surface remains unclear. In this work, N$$_{2}$$ORR activity was investigated for single-crystalline Pt, Pd, and Pd-Pt electrodes with the (111) or (100) plane in the presence and absence of Sn at the electrode surface in acidic media. In situ X-ray crystal truncation rod (CTR) measurements of Sn-modified Pt(111) and Pd(111) electrodes revealed the presence of metallic Sn and SnO at their surfaces. The surface Sn modification enhances the N$$_{2}$$ORR activity for Pd-Pt(100) or Pd(100) electrodes but not for the Pt(111), Pd-Pt(111), or Pt(100) electrodes.

論文

Synthesis of BaSiH$$_6$$ hydridosilicate at high pressures; A Bridge to BaSiH$$_8$$ polyhydride

Beyer, D. C.*; Spektor, K.*; Vekilova, O. Y.*; Grins, J.*; Barros Brant Carvalho, P. H.*; Leinbach, L. J.*; Sannemo-Targama, M.*; Bhat, S.*; Baran, V.*; Etter, M.*; et al.

ACS Omega (Internet), 10(15), p.15029 - 15035, 2025/04

 被引用回数:3 パーセンタイル:56.47(Chemistry, Multidisciplinary)

SiH$$_6$$八面体部位を特徴とするヒドリドケイ酸塩は、水素貯蔵と水素化物イオン伝導に関連する潜在的な性質を持つかなり新しい化合物のクラスである。ここでは、Zintl相水素化物BaSiH$$_{sim 1.8}$$を4GPa以上の圧力でH$$_2$$流体と反応させ、その後常圧まで減圧して得られた新しい代表的なBaSiH$$_6$$について報告する。SiH$$_{6}^{2-}$$イオンはBa$$^{2+}$$対イオンによって八面体に配位している。Ba原子とSi原子の配置は理想的なfcc NaCl構造からわずかにずれている。IRとラマンスペクトルからSiH$$_{6}^{2-}$$の屈曲と伸縮モードがそれぞれ800-1200と1400-1800cm$$^{-1}$$の範囲で観測された。BaSiH$$_6$$は95$$^circ$$Cまで熱的に安定であり、それ以上ではBaH$$_2$$とSiに分解する。DFT計算により、直接バンドギャップは2.5eVであることが示された。BaSiH$$_6$$の発見により、ギガパスカル圧力(10GPa以下)のシリサイドの水素化反応からアクセス可能なヒドリドケイ酸塩の化合物クラスが固まった。BaSiH$$_6$$の構造的性質は、超伝導ポリハイドライドBaSiH$$_8$$を予測されるより高い圧力で水素化するための中間体(あるいは前駆体)であることを示唆している。

論文

Residual stress measurement and lifetime evaluation of railway axles by neutron scattering technology

Hu, F.-F.*; Qin, T.-Y.*; Ao, N.*; 徐 平光; Su, Y. H.; Parker, J. D.*; 篠原 武尚; 菖蒲 敬久; Kang, G.-Z.*; Ren, M.-M.; et al.

Journal of Traffic and Transportation Engineering, 25(2), p.75 - 93, 2025/04

To accurately predict the remaining lifetime of surface-strengthened railway axles, a damage tolerance method considering three-dimensional (3D) residual stresses was proposed. By taking the induction-hardened carbon steel S38C axle as an example, two-dimensional (2D) distribution characterization of residual strain and 3D residual stress measurement were performed through comprehensive application of the neutron Bragg-edge transmission imaging and angle-dispersive neutron diffraction experiments. A numerical method was employed to implant the 3D residual stress into the axle model, and the remaining lifetime of the full-scale axle was studied by coupling the measured load spectrum, press-fit loads, and residual stresses. Experimental results shows that, both axial and hoop directions present a compressive residual strain gradient layer of about 3 mm, with a maximum compressive residual strain of up to -4500 $$mu$$$$varepsilon$$ in the surface layer, yet a maximum tensile strain of up to 1000 $$mu$$$$varepsilon$$ in the core. The maximum axial and hoop compressive stresses of the axle are about -500 MPa and -303 MPa respectively, while radial stresses overall fluctuate in the zero mean stress range. At depths beyond 4.5 mm from the surface layer, all three components are tensile stresses. The axle surface layer is subjected to compressive residual stresses, and crack propagation does not occur if the crack depth is less than 4.5 mm. Nevertheless, cracks propagate accelerates when the crack depth is greater than 4.5 mm. Different crack propagation depth thresholds lead to a larger calculated remaining lifetime for the residual stress-free condition than for the case where 3D residual stresses are taken into account. However, the axle remaining service mileage of the axle of 227000 Km under the most conservative conditions exceeds 3.5 non-destructive inspection (NDI) cycles, with a large safety margin. The experimental results can provide a scientific reference for the development and optimization of NDI cycles for surface-strengthened railway axles.

論文

Structural behaviors of lead zirconate titanate-based ferroelectric ceramics during pyroelectric-power generation cycles

川崎 卓郎; 福田 竜生; 山中 暁*; 村山 一郎*; 加藤 孝典*; 馬場 将亮*; 橋本 英樹*; Harjo, S.; 相澤 一也; 田中 裕久*; et al.

Journal of Applied Physics, 137(9), p.094101_1 - 094101_7, 2025/03

 被引用回数:1 パーセンタイル:28.15(Physics, Applied)

Energy harvesting from waste heat can improve energy efficiency in society. This research investigated the structural behaviors of lead zirconate titanate-based ferroelectric ceramics using operando neutron diffraction measurements under the conditions of two energy-harvesting cycles that involve consideration of the temperature changes of automobile exhaust gas for achieving good harvesting efficiencies. Input and output electrical energies and neutron diffraction data were simultaneously collected. The obtained time-resolved neutron-diffraction intensity data indicate that the applied electric fields and temperature changes induced 90$$^{circ}$$ domain rotation and lattice strain. These structural changes and their variations depending on cycle conditions, such as temperature changes, applied electric fields, and circuit switching, provide insight into the origins of the differences in the behaviors of electrical input/output energies in the cycles.

論文

Stress and plastic strain partitioning behaviors and those contributions to martensitic transformation of retained austenite in medium manganese and transformation-induced plasticity-aided bainitic ferrite steels

北條 智彦*; 小山 元道*; 熊井 麦弥*; Zhou, Y.*; 柴山 由樹; 城 鮎美*; 菖蒲 敬久; 齋藤 寛之*; 味戸 沙耶*; 秋山 英二*

ISIJ International, 65(2), p.284 - 296, 2025/02

 被引用回数:0 パーセンタイル:0.00(Metallurgy & Metallurgical Engineering)

Stress and plastic strain distributions and those partitioning behaviors of ferrite and retained austenite were investigated in the medium manganese (Mn) and the transformation-induced plasticity-aided bainitic ferrite (TBF) steels, and the martensitic transformation behaviors of retained austenite during Luders elongation and work hardening were analyzed using synchrotron X-ray diffraction at SPring-8. The stress and plastic strain of retained austenite and volume fraction of retained austenite were remarkably changed during Luders deformation in the medium Mn steel, implying that the medium Mn steel possessed inhomogeneous deformation at the parallel part of the tensile specimen. On the other hand, the distributions of the stress, plastic strain and volume fraction of retained austenite were homogeneous and the homogeneous deformation occurred at the parallel part of the tensile specimen at the plastic deformation regime with work hardening in the medium Mn and TBF steels. The martensitic transformation of retained austenite at uders deformation in the medium Mn steel was possessed owing to the application of high stress and preferential deformation at retained austenite, resulting in a significant increase in the plastic deformation and reduction of stress in the retained austenite. The martensitic transformation of retained austenite at the plastic deformation regime with work hardening was induced by the high dislocation density and newly applied plastic deformation in retained austenite in the medium Mn steel whereas the TBF steel possessed gradual transformation of retained austenite which is applied high tensile stress and moderate plastic deformation.

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