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Jee, H.*; Im, S.*; Kanematsu, Manabu*; Suzuki, Hiroshi; Morooka, Satoshi; Koyama, Taku*; Machida, Akihiko*; Bae, S.*
Journal of the American Ceramic Society, 103(12), p.7188 - 7201, 2020/12
Times Cited Count:0 Percentile:100(Materials Science, Ceramics)Saito, Hiroyuki*; Machida, Akihiko*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Physica B; Physics of Condensed Matter, 587, p.412153_1 - 412153_6, 2020/06
Times Cited Count:0 Percentile:100(Physics, Condensed Matter)The site occupancy of deuterium (D) atoms in face-centered-cubic nickel (fcc Ni) was measured along a cooling path from 1073 to 300 K at an initial pressure of 3.36 GPa via in situ neutron powder diffraction. Deuterium atoms predominantly occupy the octahedral (O) sites and slightly occupy the tetrahedral (T) sites of the fcc metal lattice. The O-site occupancy increases from 0.4 to 0.85 as the temperature is lowered from 1073 to 300 K. Meanwhile, the T-site occupancy remains c.a. 0.02. The temperature-independent behavior of the T-site occupancy is unusual, and its process is not yet understood. From the linear relation between the expanded lattice volume and D content, a D-induced volume expansion of 2.09(13) atom was obtained. This value is in agreement with the values of 2.14-2.2
atom previously reported for Ni and Ni
Fe
alloy.
Saito, Hiroyuki*; Machida, Akihiko*; Iizuka, Riko*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Scientific Reports (Internet), 10, p.9934_1 - 9934_8, 2020/06
Times Cited Count:0 Percentile:100(Multidisciplinary Sciences)Neutron powder diffraction profiles were collected for iron deuteride (FeDx) while the temperature decreased from 1023 to 300 K for a pressure range of 4-6 GPa. The ' deuteride with a double hexagonal close-packed (dhcp) structure, which coexisted with other stable or metastable deutrides at each temperature and pressure condition, formed solid solutions with a composition of FeD
at 673 K and 6.1 GPa and FeD
at 603 K and 4.8 GPa. Upon stepwise cooling to 300 K, the D-content x increased to a stoichiometric value of 1.0 to form monodeuteride FeD
. In the dhcp FeD
at 300 K and 4.2 GPa, dissolved D atoms fully occupied the octahedral interstitial sites, slightly displaced from the octahedral centers in the dhcp metal lattice, and the dhcp sequence of close-packed Fe planes contained hcp-stacking faults at 12%. Magnetic moments with 2.11
0.06 B/Fe-atom aligned ferromagnetically in parallel on the Fe planes.
Bae, S.*; Jee, H.*; Suh, H.*; Kanematsu, Manabu*; Shiro, Ayumi*; Machida, Akihiko*; Watanuki, Tetsu*; Shobu, Takahisa; Morooka, Satoshi; Geng, G.*; et al.
Construction and Building Materials, 237, p.117714_1 - 117714_10, 2020/03
Times Cited Count:1 Percentile:100(Construction & Building Technology)Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Scientific Reports (Internet), 9(1), p.12290_1 - 12290_9, 2019/08
Times Cited Count:3 Percentile:34.9(Multidisciplinary Sciences)Hexagonal close-packed iron hydride, hcp FeHx, is absent from the conventional phase diagram of the Fe-H system, although hcp metallic Fe exists stably over extensive temperature () and pressure (
) conditions, including those corresponding to the Earth's inner core.
X-ray and neutron diffraction measurements at temperatures ranging from 298 to 1073 K and H pressures ranging from 4 to 7 GPa revealed that the hcp hydride was formed for FeH
compositions when
. Hydrogen atoms occupied the octahedral interstitial sites of the host metal lattice both partially and randomly. The hcp hydride exhibited a H-induced volume expansion of 2.48(5)
/H-atom, which was larger than that of the face-centered cubic (fcc) hydride. The hcp hydride showed an increase in
with
, whereas the fcc hydride showed a corresponding decrease. The present study provides guidance for further investigations of the Fe-H system over an extensive
-
-
region.
Bae, S.*; Jee, H.*; Kanematsu, Manabu*; Shiro, Ayumi*; Machida, Akihiko*; Watanuki, Tetsu*; Shobu, Takahisa; Suzuki, Hiroshi
Journal of the American Ceramic Society, 101(1), p.408 - 418, 2018/01
Times Cited Count:6 Percentile:41.07(Materials Science, Ceramics)Despite enormous interest in calcium silicate hydrate (C-S-H), its detailed atomic structure and intrinsic deformation under an external load are lacking. This study demonstrates the nanostructural deformation process of C-S-H in tricalcium silicate (CS) paste as a function of applied stress by interpreting atomic pair distribution function (PDF) based on in situ X-ray scattering. Three different strains in C
S paste under compression were compared using a strain gauge and the real and reciprocal space PDFs. PDF refinement revealed that the C-S-H phase mostly contributed to PDF from 0 to 20
whereas crystalline phases dominated that beyond 20
. The short-range atomic strains exhibited two regions for C-S-H: I) plastic deformation (0-10 MPa) and II) linear elastic deformation (
10 MPa), whereas the long-range deformation beyond 20
was similar to that of Ca(OH)
. Below 10 MPa, the short-range strain was caused by the densification of C-S-H induced by the removal of interlayer or gel-pore water. The strain is likely to be recovered when the removed water returns to C-S-H.
Matsuura, Kohei*; Mizukami, Yuta*; Arai, Yuki*; Sugimura, Yuichi*; Maejima, Naoyuki*; Machida, Akihiko*; Watanuki, Tetsu*; Fukuda, Tatsuo; Yajima, Takeshi*; Hiroi, Zenji*; et al.
Nature Communications (Internet), 8, p.1143_1 - 1143_6, 2017/10
Times Cited Count:37 Percentile:9.91(Multidisciplinary Sciences)Motai, Satoko*; Mukai, Hiroki*; Watanuki, Tetsu; Owada, Kenji; Fukuda, Tatsuo; Machida, Akihiko; Kuramata, Chisaki*; Kikuchi, Ryosuke*; Yaita, Tsuyoshi; Kogure, Toshihiro*
Journal of Mineralogical and Petrological Sciences, 111(5), p.305 - 312, 2016/10
Times Cited Count:11 Percentile:38.29(Mineralogy)no abstracts in English
Suzuki, Hiroshi; Yamada, Rui*; Tsubaki, Shinki*; Imafuku, Muneyuki*; Sato, Shigeo*; Watanuki, Tetsu; Machida, Akihiko; Saida, Junji*
Metals, 6(1), p.12_1 - 12_11, 2016/01
Times Cited Count:2 Percentile:78.91(Materials Science, Multidisciplinary)Elastic deformation behaviors of as-cast and annealed eutectic and hypoeutectic Zr-Cu-Al bulk metallic glasses (BMGs) were investigated on a basis of different strain-scales determined by X-ray scattering and the strain gauge. The microscopic strains determined by Direct-space method (DSM) and Q-space method (QSM) were compared with the macroscopic strain measured by the strain gauge, and the difference in the deformation mechanism between eutectic and hypoeutectic Zr-Cu-Al BMGs was investigated by their correlation. The eutectic ZrCu
Al
BMG obtains more homogeneous microstructure by free-volume annihilation after annealing, improving a resistance to deformation but degrading ductility because of a decrease in the volume fraction of WBRs (Weakly-Bonded Regions) with relatively high mobility. On the other hand, the as-cast hypoeutectic Zr
Cu
Al
BMG originally has homogeneous microstructure, but loses its structural and elastic homogeneities because of nanocluster formation after annealing. Such structural changes after annealing might develop unique mechanical properties showing no degradations of ductility and toughness for the structural-relaxed hypoeutectic BMGs.
Endo, Naruki*; Saito, Hiroyuki; Machida, Akihiko; Katayama, Yoshinori
Journal of Alloys and Compounds, 645(Suppl.1), p.S61 - S63, 2015/10
Times Cited Count:0 Percentile:100(Chemistry, Physical)Yu, R.*; Hojo, Hajime*; Watanuki, Tetsu; Mizumaki, Masaichiro*; Mizokawa, Takashi*; Oka, Kengo*; Kim, H.*; Machida, Akihiko; Sakaki, Koji*; Nakamura, Yumiko*; et al.
Journal of the American Chemical Society, 137(39), p.12719 - 12728, 2015/10
Times Cited Count:15 Percentile:45.43(Chemistry, Multidisciplinary)no abstracts in English
Watanuki, Tetsu; Kashimoto, Shiro*; Ishimasa, Tsutomu*; Machida, Akihiko; Yamamoto, Shin*; Tanaka, Yukinori*; Mizumaki, Masaichiro*; Kawamura, Naomi*; Watanabe, Shinji*
Solid State Communications, 211, p.19 - 22, 2015/06
Times Cited Count:3 Percentile:79.82(Physics, Condensed Matter)The thermal expansion of a Au-Al-Yb intermediate-valence quasicrystal has been studied by X-ray diffraction measurements. We have found anomalous thermal expansion behavior, namely zero thermal expansion below 50 K. By comparison with an isostructural Au-Al-Tm quasicrystal, the contribution of the Yb valence variation was extracted, and it was shown that its negative thermal expansion component due to the valence shift toward the divalent state by cooling compensated for the positive thermal expansion of the original lattice.
Yu, R.*; Hojo, Hajime*; Oka, Kengo*; Watanuki, Tetsu; Machida, Akihiko; Shimizu, Keisuke*; Nakano, Kiho*; Azuma, Masaki*
Chemistry of Materials, 27(6), p.2012 - 2017, 2015/03
Times Cited Count:18 Percentile:35.73(Chemistry, Physical)no abstracts in English
Endo, Naruki*; Saita, Itoko*; Nakamura, Yumiko*; Saito, Hiroyuki; Machida, Akihiko
International Journal of Hydrogen Energy, 40(8), p.3283 - 3287, 2015/03
Times Cited Count:10 Percentile:63.58(Chemistry, Physical)Machida, Akihiko; Higuchi, Kensuke*; Katayama, Yoshinori; Sakaki, Koji*; Kim, H.*; Nakamura, Yumiko*
Nippon Kinzoku Gakkai-Shi, 79(3), p.124 - 130, 2015/03
Times Cited Count:4 Percentile:66.57(Metallurgy & Metallurgical Engineering)Structural changes on hydrogen absorption process of hydrogen absorbing alloy LaNiSn
have been investigated by time-resolved X-ray diffraction measurements using synchrotron radiation source. We have found the transient intermediate phase between the solid solution and hydride phases of LaNi
Sn
under non-equilibrium hydrogen pressure condition at room temperature. LaNi
Sn
has transformed into the hydride through three phase co-existing state. The hydrogen content of the intermediate phase estimated from the unit cell volume is independent of the induced hydrogen gas pressure. The variation of lattice constants indicate that the hydrogen atoms are located at the La
Ni
(Ni,Sn)
octahedron and La
(Ni,Sn)
tetrahedron in the intermediate phase.
Sakaki, Koji*; Kim, H.*; Machida, Akihiko; Watanuki, Tetsu; Nakamura, Yumiko*
Nippon Kinzoku Gakkai-Shi, 79(3), p.112 - 117, 2015/03
Times Cited Count:0 Percentile:100(Metallurgy & Metallurgical Engineering)no abstracts in English
Kim, H.*; Sakaki, Koji*; Asano, Kota*; Ikeda, Kazutaka*; Otomo, Toshiya*; Machida, Akihiko; Watanuki, Tetsu; Nakamura, Yumiko*
Nippon Kinzoku Gakkai-Shi, 79(3), p.131 - 136, 2015/03
Times Cited Count:0 Percentile:100(Metallurgy & Metallurgical Engineering)no abstracts in English
Saito, Hiroyuki; Machida, Akihiko; Matsuoka, Takehiro*; Aoki, Katsutoshi*
Solid State Communications, 205, p.24 - 27, 2015/03
Times Cited Count:4 Percentile:73.73(Physics, Condensed Matter)Aoki, Katsutoshi*; Machida, Akihiko; Saito, Hiroyuki; Hattori, Takanori; Sano, Asami
Hamon, 25(1), p.26 - 31, 2015/02
The deuterization process of fcc Fe to form solid-solution fcc FeD was investigated by in situ neutron diffraction measurements at high temperature and high pressure. In a completely deuterized specimen at 988 K and 6.3 GPa, deuterium atoms occupy the octahedral and tetrahedral interstitial sites with an occupancy of 0.532(9) and 0.056(5), respectively, giving a deuterium composition
of 0.64(1). During deuterization, the metal-lattice expands approximately linearly with deuterium composition at a rate of 2.21
per deuterium atom. The minor occupation of tetrahedral site is likely driven by the intersite movement of deuterium atoms along the
direction in the fcc metal lattice. These results provide implications for the light elements in the Earth's core and the mechanism of hydrogen embrittlement of ferrous metals.
Aoki, Katsutoshi*; Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori; Sano, Asami
Hamon, 25(1), p.26 - 31, 2015/02
The deuterization process of fcc Fe to form solid1solution fcc FeD was investigated by
neutron diffraction measurements at high temperature and high pressure. In a completely deuterized specimen at 988 K and 6.3 GPa, deuterium atoms occupy the octahedral and tetrahedral interstitial sites with an occupancy of 0.532(9) and 0.056(5), respectively, giving a deuterium composition
of 0.64(1). During deuterization, the metal-lattice expands approximately linearly with deuterium composition at a rate of 2.21
per deuterium atom. The minor occupation of tetrahedral site is likely driven by the intersite movement of deuterium atoms along the
111
direction in the fcc metal lattice. These results provide implications for the light elements in the Earth's core and the mechanism of hydrogen embrittlement of ferrous metals.