Unusual redox behavior of ruthenocene confined in the micropores of activated carbon

Itoi, Hiroyuki*; Ninomiya, Takeru*; Hasegawa, Hideyuki*; Maki, Shintaro*; Sakakibara, Akihiro*; Suzuki, Ryutaro*; Kasai, Yuto*; Iwata, Hiroyuki*; Matsumura, Daiju; Owada, Mao*; et al.

Journal of Physical Chemistry C, 124(28), p.15205 - 15215, 2020/07

https://doi.org/10.1021/acs.jpcc.0c02965

Synchrotron X-ray spectroscopy study on the valence state and magnetization in -YbAlFeB () at low temperatures and high magnetic fields

Terashima, Taku*; Matsuda, Yasuhiro*; Kuga, Kentaro*; Suzuki, Shintaro*; Matsumoto, Yosuke*; Nakatsuji, Satoru*; Kondo, Akihiro*; Kindo, Koichi*; Kawamura, Naomi*; Mizumaki, Masaichiro*; et al.

Journal of Physics; Conference Series, 592(1), p.012020_1 - 012020_6, 2015/03

https://doi.org/10.1088/1742-6596/592/1/012020

Valence fluctuation phenomena in rare-earth intermetallic compounds have attracted attention because the quantum criticality of the valence transition has been proposed theoretically. Recently, it was found that -YbAlB shows quantum criticality without tuning and has a strong mixed-valence state. In this study, we measured the magnetization curve and X-ray magnetoabsorption in -YbAlFeB (), which is a locally isostructural polymorph of -YbAlB. The magnetization and X-ray experiments were performed in fields up to 55 and 40 T, respectively. A small increase in the Yb valence was observed at fields where the magnetization curve exhibited a change in slope.