Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Yamaguchi, Tetsuji; Kataoka, Masaharu; Sawaguchi, Takuma; Mukai, Masayuki; Hoshino, Seiichi; Tanaka, Tadao; Marsal, F.*; Pellegrini, D.*
Clay Minerals, 48(2), p.185 - 197, 2013/05
Times Cited Count:3 Percentile:9.54(Chemistry, Physical)Highly alkaline environments induced by cement based materials are likely to deteriorate the physical and/or chemical properties of the bentonite buffer materials in radioactive waste repositories. Predicting long-term alteration of concrete/clay systems requires physico-chemical models and a number of input parameters. In order to provide reliability to the long-term prediction of bentonite buffer performance under disposal conditions, it is necessary to develop and verify reactive transport codes for concrete/clay systems. In this study, a PHREEQC-based, reactive transport analysis code (MC-CEMENT ver.2) was developed and was verified by comparing results of the calculations with observations of the mineralogical evolution at the concrete/argillite interface. The calculation reproduced the observations such as the mineralogical changes limited within one cm in thickness, formation of CaCO and CSH, dissolution of quartz, decrease of porosity in argillite and increase in concrete. These agreements indicate possibility that the models based on lab-scale ( 1 y) experiments can be applied to longer time scale. The fact that the calculation did not reproduce the dissolution of clays and the formation of gypsum indicates that there is still room for improvement in our model.
Yamaguchi, Tetsuji; Mitsumoto, Yoshibumi; Kadowaki, Mitsushi; Hoshino, Seiichi; Maeda, Toshikatsu; Tanaka, Tadao; Nakayama, Shinichi; Marsal, F.*; Pellegrini, D.*
no journal, ,
It is important to assess long-term alteration of engineered barrier composed of bentonite and cement for the safety assessment of radioactive waste disposal. A mineral model for bentonite-cement-seawater systems and a hydraulic conductivity model for bentonite buffer materials were developed and verified by comparing results of the model calculations with experimental observations. Changes in mineralogy of bentonite buffer materials and accompanying changes in the hydraulic conductivity over 10,000 y were calculated to identify key issues in the long-term alteration analysis. The calculation showed that the temperature, the slow kinetics of the dissolution of montmorillonite, the diffusive mass transfer and the initial (1000 y) mineralogical changes were identified as the key issues. The salinity of the groundwater was identifies as another key issue, which has both positive and negative effects on the hydraulic conductivity.