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Journal Articles

Oxygen reduction activity and interfacial structures of La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$ at initial electrochemical process in an alkaline solution

Matsuzaki, Akira*; Hirayama, Masaaki*; Oguchi, Shoya*; Komo, Mamoru*; Ikezawa, Atsunori*; Suzuki, Kota*; Tamura, Kazuhisa; Arai, Hajime*; Kanno, Ryoji*

Electrochemistry (Internet), 90(10), p.107001_1 - 107001_8, 2022/10

 Times Cited Count:0 Percentile:0.01(Electrochemistry)

Oxygen reduction and evolution reactions (ORR and OER) of perovskite-type La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$ were characterized using two-dimensional model electrodes with different reaction planes. Synthesized by pulsed laser deposition, these thin and flat electrodes can reveal the reaction plane dependence of the ORR activity. From steady-state polarization measurements in KOH (aq.), the ORR activity was the highest on the (001) film during the first ORR/OER cycle, and it decreased significantly during the second cycle. In-situ synchrotron X-ray diffraction clarified crystal structure changes in the bulk and surface regions of La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$, and these changes are associated with forming oxygen defects during the initial electrochemical process. Furthermore, the La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$ surface partially decomposed upon reacting. Therefore, the interfacial structures formed in the electrochemical reaction field is important for enhancing ORR and OER activities.

JAEA Reports

Study of ageing effect of long-term storage fuel in prototype fast breeder reactor Monju

Kato, Yuko; Umebayashi, Eiji; Okimoto, Yutaka; Okuda, Eiichi; Takayama, Koichi; Ozawa, Takayuki; Maeda, Seiichiro; Matsuzaki, Masaaki; Yoshida, Eiichi; Maeda, Koji; et al.

JAEA-Research 2007-019, 56 Pages, 2007/03

JAEA-Research-2007-019.pdf:6.79MB

In order to resume the System Startup Test (SST) of Monju, replacement fuel have to be loaded in exchange for some of initial fuel now loaded in the core to compensate core reactivity lost by decay of Pu-241 in them. The replacement fuel were being stored either in sodium in an ex-vessel storage tank or in air in a storage rack for about 10 years since their fabrication. The initial fuel were irradiated during the SST which was suspended in the end of 1995 and then stayed being loaded in the sodium-circulated core. As this long-term storage and loading may deteriorate mechanical integrity of the assemblies, a study has been made thoroughly on its thermal-hydraulic, structural and material effects on them that might be caused by irradiation in the core, sodium and mechanical environment. The study has shown that the mechanical integrity of them is well maintained even with this long-term storage and loading.

JAEA Reports

Preliminary design study of a steady state tokamak device

Miya, Naoyuki; *; Ushigusa, Kenkichi; Oikawa, Akira; Imai, Tsuyoshi; ; Nishitani, Takeo; Matsuzaki, Yoshimi; Kuriyama, Masaaki;

JAERI-M 92-140, 156 Pages, 1992/09

JAERI-M-92-140.pdf:4.19MB

no abstracts in English

Oral presentation

Study on the relationship between oxygen reduction activity and interfacial structures of La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$

Hirayama, Masaaki*; Matsuzaki, Akira*; Ikezawa, Atsunori*; Suzuki, Kota*; Arai, Hajime*; Kanno, Ryoji*; Tamura, Kazuhisa

no journal, , 

Oxygen reduction and evolution reactions (ORR and OER) of perovskite-type La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$ were characterized using two-dimensional model electrodes with different reaction planes. Synthesized by pulsed laser deposition, these thin and flat electrodes can reveal the reaction plane dependence of the ORR activity. From steady-state polarization measurements in KOH (aq.), the ORR activity was the highest on the (001) film during the first ORR/OER cycle, and it decreased significantly during the second cycle. In-situ synchrotron X-ray diffraction clarified crystal structure changes in the bulk and surface regions of La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$, and these changes are associated with forming oxygen defects during the initial electrochemical process. Furthermore, the La$$_{0.8}$$Sr$$_{0.2}$$CoO$$_{3}$$ surface partially decomposed upon reacting. Therefore, the interfacial structures formed in the electrochemical reaction field is important for enhancing ORR and OER activities.

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