Heterogeneous aggregation of humic acids studied by small-angle neutron and X-ray scattering

Saito, Takumi*; Motokawa, Ryuhei; Okubo, Takahiro*; Miura, Daisuke*; Kumada, Takayuki

Environmental Science & Technology, 57(26), p.9802 - 9810, 2023/07

https://doi.org/10.1021/acs.est.3c02028

Structure analysis of asymmetric interface using spin-contrast-variation neutron reflectometry

Kumada, Takayuki; Miura, Daisuke*; Akutsu, Kazuhiro*; Oku, Takayuki; Torikai, Naoya*; Niizeki, Tomotake*

Hamon, 32(4), p.165 - 168, 2022/11

We demonstrated the advantage of spin-contrast-variation neutron reflectometry on the structure analysis of buried interface between resin and porous silica layers. The interface structure was not reproduced by the normal Gaussian model, but by the asymmetric interface model where crosslinked polymer chains neither permeate the pore nor follow the surface roughness of the silica layer.

Temporal variability of Cs concentrations in coastal sediments off Fukushima

Suzuki, Shotaro*; Amano, Yosuke*; Enomoto, Masahiro*; Matsumoto, Akira*; Morioka, Yoshiaki*; Sakuma, Kazuyuki; Tsuruta, Tadahiko; Kaeriyama, Hideki*; Miura, Hikaru*; Tsumune, Daisuke*; et al.

Science of the Total Environment, 831, p.154670_1 - 154670_15, 2022/07

https://doi.org/10.1016/j.scitotenv.2022.154670

Extraction of hydrogen location in molecular crystals in spin-contrast-variation neutron powder diffractometry

Miura, Daisuke*; Kumada, Takayuki; Iwata, Takahiro*

Nihon Kessho Gakkai-Shi, 63(4), p.287 - 293, 2021/12

https://doi.org/10.5940/jcrsj.63.287

We have developed the spin-contrast-variation neutron powder diffractometry to observe hydrogen atoms in a crystalline sample by polarized neutron and polarized proton in the crystal. L-glutamic acid crystals were dispersed in a deuterated polystyrene matrix containing a polarizing agent. The intensities of the diffraction peaks of the sample changed according to the proton polarization. The spin-contrast-variation neutron powder diffractometry can extract diffraction from hydrogen atoms because of the variation of peak intensities as a function of the proton polarization. This technique is expected to enable analyses of the structures of hydrogen-containing materials that are difficult to determine with conventional powder diffractometry.

First isolation and analysis of caesium-bearing microparticles from marine samples in the Pacific coastal area near Fukushima Prefecture

Miura, Hikaru*; Ishimaru, Takashi*; Ito, Yukari*; Kuribara, Yuichi; Otosaka, Shigeyoshi*; Sakaguchi, Aya*; Misumi, Kazuhiro*; Tsumune, Daisuke*; Kubo, Atsushi*; Higaki, Shogo*; et al.

Scientific Reports (Internet), 11, p.5664_1 - 5664_11, 2021/03

https://doi.org/10.1038/s41598-021-85085-w

For the first time, we isolated and investigated seven CsMPs (radioactive caesium-bearing microparticles) from marine particulate matter and sediment. From the elemental composition, the Cs/Cs activity ratio, and the Cs activity per unit volume results, we inferred that the five CsMPs collected from particulate matter were emitted from Unit 2 of the FDNPP, whereas the two CsMPs collected from marine sediment were possibly emitted from Unit 3. The presence of CsMPs can cause overestimation of the solid-water distribution coefficient of Cs in marine sediments and particulate matter and a high apparent radiocaesium concentration factor for marine biota. CsMPs emitted from Unit 2, which were collected from the estuary of a river that flowed through a highly contaminated area, may have been deposited on land and then transported by the river. By contrast, CsMPs emitted from Unit 3 were possibly transported eastward by the wind and deposited directly onto the ocean surface.

Development of spin-contrast-variation neutron reflectometry for structural analyses of multilayer films

Kumada, Takayuki; Miura, Daisuke*; Akutsu, Kazuhiro*; Suzuki, Junichi*; Torikai, Naoya*

Hamon, 30(4), p.207 - 211, 2020/11

https://doi.org/10.5611/hamon.30.4_207

We developed a technique of spin-contrast-variation neutron reflectivity (SCV-NR) for structural analyses of multilayer films. The SCV-NR curves of the polystyrene monolayer film were precisely reproduced using a common set of structural parameters and neutron scattering length density at each proton polarization. This result ensures that SCV-NR curves are not deformed by inhomogeneous PH due to the spin-diffusion mechanism. The number of structural parameters of the lamellar microphase-separated poly(styrene-block-isoprene) thin film is too large to determine with a single unpolarized reflectivity curve only. However, these parameters converged through the global analysis of the SCV-NR curves. In this manner, SCV-NR determines the structure of multilayer films while excluding the incorrect structural model that accidentally accounts for a single unpolarized reflectivity curve only.

Precise determination of C level structure by -ray spectroscopy

Hosomi, Kenji; Ma, Y.*; Ajimura, Shuhei*; Aoki, Kanae*; Dairaku, Seishi*; Fu, Y.*; Fujioka, Hiroyuki*; Futatsukawa, Kenta*; Imoto, Wataru*; Kakiguchi, Yutaka*; et al.

Progress of Theoretical and Experimental Physics (Internet), 2015(8), p.081D01_1 - 081D01_8, 2015/08

https://doi.org/10.1093/ptep/ptv113

Level structure of the C hypernucleus was precisely determined by means of -ray spectroscopy. We identified four -ray transitions via the C reaction using a germanium detector array, Hyperball2. The spacing of the ground-state doublet was measured to be (stat) (syst)keV from the direct transition. Excitation energies of the and states were measured to be , keV and , keV, respectively. The obtained level energies provide definitive references for the reaction spectroscopy of hypernuclei.

Application test of blast method using for decontamination and MOX powder collection from low level radioactive waste

Kobayashi, Daisuke; Iida, Masayoshi; Takahashi, Naoki; Yoshimoto, Katsunobu; Nemoto, Ryo*; Miura, Susumu*; Numao, Teruhiko*; Nakayashiki, Hiroshi*

no journal, , 

no abstracts in English

Spin contrast variation neutron diffractometry

Kumada, Takayuki; Miura, Daisuke; Iwata, Takahiro*

no journal, , 

We developed a technique of spin contrast variation neutron diffractometry. We present the fist data in this meeting.

Development of high-strength cellulose nanofiber hydrogels by freeze-crosslinking

Sekine, Yurina; Nankawa, Takuya; Miura, Daisuke*; Yunoki, Shunji*; Sugita, Tsuyoshi; Nakagawa, Hiroshi; Yamada, Teppei*

no journal, , 

We developed a crosslinking method using freeze concentration and used it to synthesize a cellulose nanofiber hydrogel with high compressive strength. The reaction between the freeze-concentrated cellulose nanofiber and citric acid created a rigid porous structure. Without the freeze crosslinking method, the complex of the cellulose nanofiber sol and citric acid produced hydrogels, which easily collapsed under compressive stress. We will give a presentation on the crosslinking method and the chemical and physical properties of the hydrogel.