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-edgesIshimatsu, Naoki*; Sasada, Ryohei*; Maruyama, Hiroshi*; Ichikawa, Takayuki*; Miyaoka, Hiroki*; Kimura, Toru*; Tsubota, Masami*; Kojima, Yoshitsugu*; Tsumuraya, Takao*; Oguchi, Tamio*; et al.
Journal of Physics; Conference Series, 190, p.012070_1 - 012070_4, 2009/11
Times Cited Count：5 Percentile：79.33(Physics, Condensed Matter)We have investigated the effect of hydrogenation on La 
and 
electronic states in metallic LaH
by X-ray absorption near edge structure at the La -edges. As the hydrogen content 
increases from 0 to 2.6, white-line intensity at the La 
-edges shows a remarkable increase in the range of 
2.0. This is interpreted as the increase in La hole induced by interstitial H atoms on the octahedral sites. On the other hand, the shoulder structure at the La 
-edge disappears in the process of = 0.0 
2.0, indicating that the 
-
hybridization is weakened by H atoms on the tetrahedral sites. This study demonstrates that H atoms on the two interstitial H sites provide different contribution to the modification of the electronic states.
Kamakura, Nozomu; Takeda, Yukiharu; Okane, Tetsuo; Fujimori, Shinichi; Saito, Yuji; Yamagami, Hiroshi; Miyaoka, Hiroki*; Tsubota, Masami*; Ichikawa, Takayuki*; Kojima, Yoshitsugu*; et al.
no journal, ,
no abstracts in English
Kamakura, Nozomu; Yamagami, Hiroshi; Takeda, Yukiharu; Okane, Tetsuo; Saito, Yuji; Miyaoka, Hiroki*; Tsubota, Masami*; Ichikawa, Takayuki*; Kojima, Yoshitsugu*; Muro, Takayuki*; et al.
no journal, ,
In this research, the electronic states of the insulator alkali metal amide (
, 
) and alkaline earth metal amide (
), which are lightweight complex hydrides being considered as a high-capacity hydrogen storage material, are investigated by the soft X-ray emission (XES)and absorption spectroscopies. The sharp three peak structure commonly observed in the XES spectrum of alkali metal amides shows the localized character of the valence electrons, while the importance of the number of the amide ion is shown by the XES spectrum of which is clearly different from that of alkali metal amide. The comparison with the band calculation clarifies the electronic sates of .
Kamakura, Nozomu; Takeda, Yukiharu; Yamagami, Hiroshi; Miyaoka, Hiroki*; Tsubota, Masami*; Ichikawa, Takayuki*; Kojima, Yoshitsugu*; Muro, Takayuki*; Kinoshita, Toyohiko*
no journal, ,
Metal amide has been attracted much attention as a lightweight hydride being considered for high capacity hydrogen storage materials. In this research, the electronic states of the insulator alkali metal amide (KNH
, NaNH) and alkaline earth metal amide (Ca(NH), Mg(NH)) are investigated by the soft X-ray emission spectroscopy (XES) and absorption spectroscopy (XAS) in the total fluorescence yield mode. The localized character of the valence electrons is shown by the sharp three peak structure commonly observed in the XES spectrum of alkali metal amide. The localized character of the valence electrons is shown by the sharp peak structure commonly observed in the XES spectrum of alkali metal amide. The broadening of the N 2p states by the hybridization is observed in the XES spectrum of the alkaline earth metal amide. Decomposition temperature of the metal amide is found to relate to the character of the chemical bond observed in the XAS.
