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Journal Articles

Development of a D$$_2$$O/H$$_2$$O vapor generator for contrast-variation neutron scattering

Arima-Osonoi, Hiroshi*; Takata, Shinichi; Kasai, Satoshi*; Ouchi, Keiichi*; Morikawa, Toshiaki*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki; Iwase, Hiroki*; Hiroi, Kosuke; et al.

Journal of Applied Crystallography, 56(6), p.1802 - 1812, 2023/12

https://doi.org/10.1107/S1600576723009780
 Times Cited Count：0 Percentile：0.02(Chemistry, Multidisciplinary)

Journal Articles

Structural changes of polystyrene particles in subcritical and supercritical water revealed by in situ small-angle neutron scattering

Shibata, Motoki*; Nakanishi, Yohei*; Abe, Jun*; Arima, Hiroshi*; Iwase, Hiroki*; Shibayama, Mitsuhiro*; Motokawa, Ryuhei; Kumada, Takayuki; Takata, Shinichi; Yamamoto, Katsuhiro*; et al.

Polymer Journal, 55(11), p.1165 - 1170, 2023/11

https://doi.org/10.1038/s41428-023-00817-1
 Times Cited Count：1 Percentile：51.7(Polymer Science)

Journal Articles

Basic study on tritium monitor using plastic scintillator for treated water discharge at Fukushima Daiichi Nuclear Power Plant

Sanada, Yukihisa; Abe, Tomohisa; Sasaki, Miyuki; Kanno, Marina*; Yamada, Tsutomu*; Nakasone, Takamasa*; Miyazaki, Nobuyuki*; Oshikiri, Keisuke*; Watabe, Hiroshi*

Journal of Nuclear Science and Technology, 10 Pages, 2023/00

https://doi.org/10.1080/00223131.2023.2258880
 Times Cited Count：0 Percentile：0.01(Nuclear Science & Technology)

The "treated water" from which the main radioactive materials were removed contains tritium, and stakeholders in Japan have been debating how to treat it. The amount of treated water stored in the facility has reached its limit, and the Japanese government has decided that the treatment method will be to discharge the water into the ocean by FY 2023 (FY: Fiscal Year). The present research developed a simple and practical tritium monitor for the Fukushima Daiichi Nuclear Power Station (FDNPS) tritiated water release. A simple and practical tritium monitor was developed for FDNPS tritiated water release based on thin plastic scintillator sheets. The developed devices were calibrated using standard tritium solutions and a method for calculating the minimum detectable activity. Fifteen 0.25 mm-thick scintillators can be placed in the 0.26 L flow cell where the sample water is fed, yielding an active surface area of 3,200 mm$$^{2}$$. The efficiency of tritiated water with full water is 0.000035 cps Bq$$^{-1}$$. The minimum detectable activity under simple shielding conditions was 7,800 Bq L$$^{-1}$$ (Measurement time was 3,600 s).

Journal Articles

Event report of JHPS Symposium 2022

Yasuoka, Yumi*; Fujita, Hiroki; Tsuji, Tomoya; Tsujiguchi, Takakiyo*; Sasaki, Michiya*; Miyazaki, Tomoyuki*; Hashima, Shun*; Yasuda, Hiroshi*; Shimada, Kazumasa; Hirota, Seiko*

Hoken Butsuri (Internet), 57(3), p.146 - 155, 2022/12

https://doi.org/10.5453/jhps.57.146

no abstracts in English

Journal Articles

Neutron reflectivity study on the suppression of interfacial water accumulation between a polypropylene thin film and Si substrate using a silane-coupling agent

Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Arima-Osonoi, Hiroshi*; Nakanishi, Yohei*; Takenaka, Mikihito*; Shibata, Motoki*; Yamada, Norifumi*; Seto, Hideki*; Aoki, Hiroyuki; et al.

Langmuir, 38(41), p.12457 - 12465, 2022/10

https://doi.org/10.1021/acs.langmuir.2c01599
 Times Cited Count：0 Percentile：0(Chemistry, Multidisciplinary)

Journal Articles

Layered structure in the crystalline adsorption layer and the leaching process of poly(vinyl alcohol) revealed by neutron reflectivity

Miyazaki, Tsukasa*; Miyata, Noboru*; Arima, Hiroshi*; Kira, Hiroshi*; Ouchi, Keiichi*; Kasai, Satoshi*; Tsumura, Yoshihiro*; Aoki, Hiroyuki

Langmuir, 37(32), p.9873 - 9882, 2021/08

https://doi.org/10.1021/acs.langmuir.1c01563
 Times Cited Count：5 Percentile：38.19(Chemistry, Multidisciplinary)

Journal Articles

Fine-structure analysis of perhydropolysilazane-derived nano layers in deep-buried condition using polarized neutron reflectometry

Akutsu, Kazuhiro*; Kira, Hiroshi*; Miyata, Noboru*; Hanashima, Takayasu*; Miyazaki, Tsukasa*; Kasai, Satoshi*; Yamazaki, Dai; Soyama, Kazuhiko; Aoki, Hiroyuki

Polymers (Internet), 12(10), p.2180_1 - 2180_10, 2020/10

https://doi.org/10.3390/polym12102180
 Times Cited Count：2 Percentile：7.04(Polymer Science)

Journal Articles

Gas-flow humidity control system for neutron reflectivity measurements

Arima-Osonoi, Hiroshi*; Miyata, Noboru*; Yoshida, Tessei*; Kasai, Satoshi*; Ouchi, Keiichi*; Zhang, S.*; Miyazaki, Tsukasa*; Aoki, Hiroyuki

Review of Scientific Instruments, 91(10), p.104103_1 - 104103_7, 2020/10

https://doi.org/10.1063/5.0021128
 Times Cited Count：9 Percentile：56.16(Instruments & Instrumentation)

Journal Articles

Detailed structural study on the poly(vinyl alcohol) adsorption layers on a Si substrate with solvent vapor-induced swelling

Miyazaki, Tsukasa*; Miyata, Noboru*; Yoshida, Tessei*; Arima, Hiroshi*; Tsumura, Yoshihiro*; Torikai, Naoya*; Aoki, Hiroyuki; Yamamoto, Katsuhiro*; Kanaya, Toshiji*; Kawaguchi, Daisuke*; et al.

Langmuir, 36(13), p.3415 - 3424, 2020/04

https://doi.org/10.1021/acs.langmuir.9b03964
 Times Cited Count：14 Percentile：58.64(Chemistry, Multidisciplinary)

Journal Articles

Structure and function of thrombopoietin and its receptor

Kuroki, Ryota; Miyazaki, Hiroshi*; Kato, Takashi

Ketsueki Furonteia, 25(2), p.171 - 180, 2015/02

no abstracts in English

Journal Articles

Applicability of redundant pairs of SOI transistors for analog circuits and their applications to phase-locked loop circuits

Makihara, Akiko*; Yokose, Tamotsu*; Tsuchiya, Yoshihisa*; Miyazaki, Yoshio*; Abe, Hiroshi; Shindo, Hiroyuki*; Ebihara, Tsukasa*; Maru, Akifumi*; Morikawa, Koichi*; Kuboyama, Satoshi*; et al.

IEEE Transactions on Nuclear Science, 60(1), p.230 - 235, 2013/02

https://doi.org/10.1109/TNS.2012.2237039
 Times Cited Count：6 Percentile：44.02(Engineering, Electrical & Electronic)

no abstracts in English

Journal Articles

J-PARC decay muon channel construction status

Strasser, P.*; Shimomura, Koichiro*; Koda, Akihiro*; Kawamura, Naritoshi*; Fujimori, Hiroshi*; Makimura, Shunsuke*; Kobayashi, Yasuo*; Nakahara, Kazutaka*; Kato, Mineo*; Takeshita, Soshi*; et al.

Journal of Physics; Conference Series, 225, p.012050_1 - 012050_8, 2010/06

https://doi.org/10.1088/1742-6596/225/1/012050
 Times Cited Count：12 Percentile：95.21(Physics, Applied)

Journal Articles

High-magnetic-field X-ray absorption spectroscopy of field-induced valence transition in EuNi$$_2$$(Si$$_{1-x}$$Ge$$_x$$)$$_2$$

Matsuda, Yasuhiro*; Inami, Toshiya; Owada, Kenji; Murata, Yuto*; Nojiri, Hiroyuki*; Murakami, Yoichi*; Mitsuda, Akihiro*; Wada, Hirofumi*; Miyazaki, Hiroshi*; Harada, Isao*

Journal of the Physical Society of Japan, 77(5), p.054713_1 - 054713_7, 2008/05

https://doi.org/10.1143/JPSJ.77.054713
 Times Cited Count：25 Percentile：74.44(Physics, Multidisciplinary)

The magnetic-field-induced valence transition in EuNi$$_2$$(Si$$_{1-x}$$Ge$$_x$$)$$_2$$ (x=0.82, 0.85) has been studied by X-ray absorption spectroscopy at low temperatures. The field dependence of the Eu valence is directly observed for the first time. We find a significant decrease in the valences at high magnetic fields above 40 T. The valence of Eu changes from v = 2.75 at a zero field to v = 2.33 at 40 T for x = 0.82. The results are analyzed using a theoretical model. The hybridization parameter V between the Eu$$^{2+}$$ and Eu$$^{3+}$$ states and the energy separation $$Delta$$$$E$$ are determined, which are crucial for quantum mechanical mixing.

Journal Articles

Radiation-induced radical polyaddition of Bis($$alpha$$-trifluoromethyl-$$beta$$, $$beta$$-difluorovinyl) terephthalate with excess of various ethers

Enomoto, Kazuyuki*; Maekawa, Yasunari; Katsumura, Yosuke*; Miyazaki, Toyoaki*; Yoshida, Masaru; Hamana, Hiroshi*; Narita, Tadashi*

Macromolecules, 38(23), p.9584 - 9593, 2005/11

https://doi.org/10.1021/ma051147j
 Times Cited Count：9 Percentile：30.73(Polymer Science)

Radiation-induced radical polyaddition of bis($$alpha$$-trifluoromethyl-$$beta$$,$$beta$$-difluorovinyl) terephthalate [CF$$_{2}$$=C(CF3)OCOC$$_{6}$$H$$_{4}$$COOC(CF$$_{3}$$)=CF$$_{2}$$] (BFP) in the presence of an excess of cyclic and acyclic ethers in feed was examined at 0$$^{circ}$$C using $$gamma$$-rays irradiation. Irradiation of BFP with an 8-fold excess of 1,4-dioxane (DOX) and diethyl ether (EE) gave monomodal polymers consisting of the $$alt$$ ernating unit of BFP and DOX moieties (poly(BFP-$$alt$$-DOX), $$overline{M}$$$$_{n, as-prepared}$$ = 5.1$$times$$10$$^{3}$$) and of BFP and EE (poly(BFP-$$alt$$-EE), $$overline{M}$$$$_{n, as-prepared}$$ =3.9$$times$$10$$^{3}$$), respectively. The irradiation of BFP with an 8-fold excess of tetrahydrofuran or tetrahydropyran provided only 1:2 addition products in high yields. Mono-functional 2-benzoxypentafluoropropene [CF$$_{2}$$=C(CF$$_{3}$$)OCOC$$_{6}$$H$$_{5}$$] (BPFP) as a model compound showed preferential formation of the 2:1 adduct to the 1:1 adduct with DOX and EE. The kinetic analysis of the model reactions revealed that the rate constants for the formation of the 2:1 adducts ($$k_{rm d}$$) of BPFP with DOX and EE were two orders of magnitude higher than those of the 1:1 adducts ($$k_{rm m}$$). Poly(BFP-$$alt$$-DOX) showed higher radiation resistance than poly(BFP-$$alt$$-EE) in solid states as well as in solution. It was concluded that radiation-induced step-growth polymerization under the stoichiometric imbalance of the two compounds requires a high $$k_{rm d}$$/$$k_{rm m}$$ value as well as high radiation resistance for the formation of high molecular weight polymers.

Oral presentation

Neutron and X-ray study of residual stress measurement on carburized component

Suzuki, Hiroshi; Miyazaki, Takasato*; Kawamura, Hideki*; Akiniwa, Yoshiaki

no journal, , 

no abstracts in English

Oral presentation

Heat capacity measurements of cement materials

Sasada, Yuto*; Miyazaki, Yuji*; Nakano, Motohiro*; Matsuo, Yusuke*; Walker, C.*; Sasamoto, Hiroshi; Mihara, Morihiro

no journal, , 

Cementitous materials are to be used in large quantities in the geological disposal of highly radioactive TRU waste. Thermodynamic data on cement hydrate minerals are important to model the long-term dissolution behavior of cement materials during the reaction of these materials with groundwater. Portlandite (Ca(OH)$$_{2}$$) is a major component (20 to 25 wt%) of hydrated Portland cement. Low temperature heat capacity measurements of three types of portlandite (low purity, high purity, and large crystal) showed purity dependence. The large crystal sample followed Debye's T$$^{3}$$ rule at low temperatures, while the high and low purity samples showed upturn of heat capacity, possibly due to difference in absorbed water vapor and/or calcite (CaCO$$_{3}$$) contamination. Heat capacities of the cement hydrates (ettringite:Ca$$_{6}$$(Al(OH)$$_{6}$$)$$_{2}$$(SO$$_{4}$$)$$_{3}$$(H$$_{2}$$O)$$_{n}$$ and monosulfate:Ca$$_{4}$$Al$$_{2}$$(OH)$$_{12}$$(SO$$_{4}$$)(H$$_{2}$$O)$$_{n}$$) exhibited phase transitions associated with the hydration water.

16 (Records 1-16 displayed on this page)
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