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K
Li
)NbO
synthesized by malic acid complex solution methodYoneda, Yasuhiro; Takada, Eri*; Nagai, Haruka*; Kikuchi, Takeyuki*; Morishita, Masao*; Kobune, Masafumi*
Japanese Journal of Applied Physics, 56(10S), p.10PB07_1 - 10PB07_7, 2017/10
Times Cited Count：4 Percentile：16.32(Physics, Applied)A monoclinic phase was discovered in (NaKLi)NbO solid solution ceramics grown by a malic acid complex solution method. The average and local structures of this monoclinic phase were analyzed by synchrotron X-ray measurements. The local structure can be reproduced by assuming a rhombohedral model, that is the same local structure of KNbO. The results demonstrate that the monoclinic average structure is observed as a disordered rhombohedral structure.
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
Radiation Physics and Chemistry, 80(2), p.149 - 152, 2011/02
Times Cited Count：25 Percentile：83.71(Chemistry, Physical)Carboxymethyl cellulose (CMC), one of polysaccharide derivatives, at highly concentrated aqueous solution undergoes radiation-crosslinking reactions. In this topic, CMC radical, formed by reaction with OH radical attributed to radiation-induced crosslinking reaction, were studied by ESR method to understand the radiation-induced reaction mechanism of CMC aqueous solution. At first, it was succeeded to observe ESR spectra of the CMC radical using photolysis of hydrogen peroxide as the origin of OH radical. Observed ESR spectra were identified as radicals located on the secondary carbon of carboxymethyl groups. Secondly, N
O saturated CMC aqueous solution 6 min after electron beam irradiation was measured by ESR method. The spectra were almost same shape as the case of photolysis of hydrogen peroxide, and were assigned as long-lived radicals located on carboxymethyl groups. Next, in the case of N and O saturation, spectra intensity become half or 0. This means that these long-lived radicals are produced by reaction with OH radical.
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Muroya, Yusa*; Kudo, Hisaaki*; Katsumura, Yosuke*
Radiation Physics and Chemistry, 79(3), p.276 - 278, 2010/03
Times Cited Count：17 Percentile：70.56(Chemistry, Physical)Carboxymethyl chitosan (CMCTS) is one kind of polysaccharide derivatives and has a good water-solubility. At a high concentrated aqueous solution, CMCTS forms gel by ionizing irradiation, though polysaccharide derivatives are generally radiation-degradation type. In general, OH radical, which is one of main water radiolysis products and very oxidative species, is said to induce crosslinking reaction of polymer solution. The purpose of this study is to understand the radiation-crosslinking mechanism of CMCTS at a high concentrated aqueous solution. In this study, identification of CMCTS radical produced by reaction with OH radical was introduced. CMCTS radical in an aqueous solution was observed directly by ESR method using photolysis of hydrogen peroxide. The ESR spectra have a large doublet split and small triplet split like [Triplet 
Doublet]. However, some species seemed to be overlapped on ESR spectra, because right-and-left triplet spectra are not equiform. Compared with some radicals, which have analogical structure to CMCTS, about hyperfine coupling constant, [Triplet Doublet], assigned as radical on carboxymethyl group linked to C6, and [Doublet], assigned as radical on carboxymethyl group linked to C2 or C3, were isolated from ESR spectra of experimental results. In conclusion, these spectra were identified as radicals located on secondary carbon of carboxymethyl groups.
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Muroya, Yusa*; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Kodama, Shohei*; Kurosawa, Shunsuke*; Morishita, Yuki; Usami, Hiroshi; Hayashi, Masateru*; Tanaka, Hiroki*; Yoshino, Masao*; Kamada, Kei*; Yoshikawa, Akira*; Torii, Tatsuo
no journal, ,
After Fukushima 1st Nuclear Plant accident, a large number of radioactive pollutants or nuclear debris with very high dose of more than a few Sv/h still have existed. To estimate the dose of such pollutants, a Japan Atomic Energy Agency research group has suggested a new technique to use a long optical fiber and a red-emitting scintillator, and the scintillation photons are read outside of high dose area. We tested the gamma-ray detection performance of a ruby (Cr:AlO
) and a newly developed CsHfI
scintillators as a scintillating probe coupled with an optical fiber in this study.
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Muroya, Yusa*; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
Polysaccharide derivatives, for example carboxymethyl cellulose (CMC), at a concentrated aqueous solution form gels by irradiation. Radiation-crosslinking mechanism of polysaccharide derivatives is not well known, and polysaccharide radicals formed after ionizing irradiation have not been assigned clearly. The purpose of this study is to observe directly ESR spectrum of CMC radicals in an aqueous solution reacted with OH and to analyze radical sites of CMC radical in detail. It was succeeded to detect CMC radicals in an aqueous solution by ESR using OH radicals from photolysis of hydrogen peroxide (sample: CMC 10 mM / hydrogen peroxide 10 mM). It was identified that a radical on carboxymethyl group linked with C2 and C3 appears as doublet spectrum and that a radical on carboxymethyl group linked with C6 appears as triplet-doublet spectrum from study of hydrogen atom position around the radical and of hyperfine coupling constant.
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Muroya, Yusa*; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Tamada, Masao; Kudo, Hisaaki*; Katsumura, Yosuke*
no journal, ,
no abstracts in English
