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Journal Articles

High-pressure Raman spectroscopy of transition metal cyanides

Moritomo, Yutaka*; Matsuda, Tomoyuki*; Fuchikawa, Ryota*; Abe, Yuta; Kamioka, Hayato*

Journal of the Physical Society of Japan, 80(2), p.024603_1 - 024603_5, 2011/02

https://doi.org/10.1143/JPSJ.80.024603

Times Cited Count：4 Percentile：32.92(Physics, Multidisciplinary)

Journal Articles

Structural basis for the fast phase change of Ge $_{2}$ Sb $_{2}$ Te $_{5}$ ; Ring statistics analogy between the crystal and amorphous states

Kohara, Shinji*; Kato, Kenichi*; Kimura, Shigeru*; Tanaka, Hitoshi*; Usuki, Takeshi*; Suzuya, Kentaro; Tanaka, Hiroshi*; Moritomo, Yutaka*; Matsunaga, Toshiyuki*; Yamada, Noboru*; et al.

Applied Physics Letters, 89(20), p.201910_1 - 201910_3, 2006/11

https://doi.org/10.1063/1.2387870

Times Cited Count：216 Percentile：97.96(Physics, Applied)

The three-dimensional atomic configuration of amorphous Ge $_{2}$ Sb $_{2}$ Te $_{5}$ were derived by reverse Monte Carlo simulation with synchrotron-radiation X-ray diffraction data. The authors found that amorphous Ge $_{2}$ Sb $_{2}$ Te $_{5}$ can be regarded as "even-numbered ring structure", because the ring statistics is dominated by four- and six-fold rings analogous to the crystal phase. On the other hand, the formation of Ge-Ge homopolar bonds in amorphous GeTe constructs both odd- and even-numbered rings. They believe that the unusual ring statistics of amorphous Ge $_{2}$ Sb $_{2}$ Te $_{5}$ is the key for the fast crystallization speed of the material.

Journal Articles

Electronic excitations in hole-doped La $_{1-x}$ Sr $_{x}$ MnO $_{3}$ studied by resonant inelastic X-ray scattering

Ishii, Kenji; Inami, Toshiya; Owada, Kenji; Kuzushita, Kaori; Mizuki, Junichiro; Murakami, Yoichi; Ishihara, Sumio*; Endo, Yasuo*; Maekawa, Sadamichi*; Hirota, Kazuma*; et al.

Journal of Physics and Chemistry of Solids, 66(12), p.2157 - 2162, 2005/12

https://doi.org/10.1016/j.jpcs.2005.09.011

Times Cited Count：0 Percentile：0.00(Chemistry, Multidisciplinary)

We have studied electronic excitations of hole-doped manganese oxides La $_{1-x}$ SrMnO ( and ) by resonant inelastic X-ray scattering at Mn K absorption edge. We observed in the excitation spectra that the Mott gap of La $_{0.6}$ Sr $_{0.4}$ MnO $_{3}$ was filled by hole-doping. In La $_{0.8}$ Sr $_{0.2}$ MnO $_{3}$ , which shows a metal-insulator transition, we found that temperature dependence of scattering intensity is different between two scattering vectors. It may reflects a anisotropic electronic structure which originates from the orbital degrees of freedom in manganese oxides.

Journal Articles

Resonant O K emission spectroscopy of layered manganate La $_{1.2}$ Sr $_{1.8}$ Mn $_{2}$ O $_{7}$

Agui, Akane; Kmbre, T.*; Sthe, C.*; Nordgren, J.*; Usuda, Manabu; Saito, Tomohiko*; Moritomo, Yutaka*

Journal of Electron Spectroscopy and Related Phenomena, 144-147, p.589 - 592, 2005/06

https://doi.org/10.1016/j.elspec.2005.01.103

Times Cited Count：1 Percentile：5.61(Spectroscopy)

Current research in the perovskite and layered perovskite-type manganese oxides has expanded to include the study of electronic and magnetic properties such as the colossal magnetoresistance (CMR), orbital ordering and charge ordering. The O K soft X-ray emission and absorption spectra (XES and XAS) of La $_{1.2}$ Sr $_{1.8}$ Mn $_{2}$ O $_{7}$ were measured at selected excitation energies in order to investigate the electronic structure. The measurements were carried out by using a soft X-ray emission spectrometer at beamline BW3 at HASYLAB, Germany. The dependence of O K XES on excitation-energy was observed. It is attributed the different site of oxygen ions.

Journal Articles

Resonant Mn Emission spectra of layered manganite La $_{1.2}$ Sr $_{1.8}$ Mn $_{2}$ O $_{7}$

Agui, Akane; Butorin, S. M.*; Kmbre, T.*; Sthe, C.*; Saito, Tomohiko*; Moritomo, Yutaka*; Nordgren, J.*

Journal of the Physical Society of Japan, 74(6), p.1772 - 1776, 2005/06

https://doi.org/10.1143/JPSJ.74.1772

Times Cited Count：8 Percentile：47.78(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Resonant inelastic X-ray scattering study of the hole-doped manganites La $_{1-x}$ SrMnO (, )

Ishii, Kenji; Inami, Toshiya; Owada, Kenji; Kuzushita, Kaori; Mizuki, Junichiro; Murakami, Yoichi; Ishihara, Sumio*; Endo, Yasuo*; Maekawa, Sadamichi*; Hirota, Kazuma*; et al.

Physical Review B, 70(22), p.224437_1 - 224437_6, 2004/12

https://doi.org/10.1103/PhysRevB.70.224437

Times Cited Count：23 Percentile：68.68(Materials Science, Multidisciplinary)

Electronic excitations in the hole doped manganese oxides (La $_{1-x}$ SrMnO, and ) have been elucidated by using the resonant inelastic X-ray scattering (RIXS) method. A doping effect in the strongly correlated electron systems has been observed for the first time. The scattering spectra show that a salient peak appears in low energies indicating the persistence of the Mott gap. At the same time, the energy gap is partly filled by doping holes and the spectral weight energy shifts toward lower energies. The excitation spectra show little change in the momentum space as is in undoped LaMnO. On the other hand, the scattering intensities in the low energy excitations of are anisotropic in temperature dependence, which indicates an anisotropy of magnetic interaction and underlying effect of the orbital.

Journal Articles

Addendum to $lqlq Doping-Dependent Magnetic Structure of Tb$_{1-x}$$ Ca $_{x}$ MnO $_{3}$ rqrq

Machida, Akihiko; Moritomo, Yutaka*; Oyama, Kenji*

Journal of the Physical Society of Japan, 72(5), P. 1312, 2003/05

In order to investigate interrelation between the lattice structure and the magnetic structure, we have performed Rietveld structural analysis on the neutron powder patterns for Tb $_{1-x}$ Ca $_{x}$ MnO at low temperature. In the concentration range of , we observed the Bragg reflections due to the CE-like- and C-type structures. In this range, the powder patterns were reproduce by the two-phase model with and $P2_{1}/m$ symmetries. The fractions of these phases change against concentration . This variation of the fraction for the phase is similar to the variation of the integrated intensities of the CE-like-type magnetic Bragg reflections. This indicates that the phase is responsible for the CE-like spin-ordering. Furthermore, we discussed interrelation between the detailed lattice structure and magnetic structure.

Oral presentation

Polarization dependence in RIXS of La $_{1-x}$ SrMnO

Ishii, Kenji; Inami, Toshiya; Owada, Kenji; Kuzushita, Kaori*; Mizuki, Junichiro; Murakami, Yoichi*; Ishihara, Sumio*; Endo, Yasuo*; Maekawa, Sadamichi*; Hirota, Kazuma*; et al.

no journal, ,

no abstracts in English

Oral presentation

High-pressure raman spectroscopy of transition metal cyanides

Fuchikawa, Ryota*; Abe, Yuta; Matsuda, Tomoyuki*; Kamioka, Hayato*; Moritomo, Yutaka*

no journal, ,

no abstracts in English

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High-pressure Raman spectroscopy of transition metal cyanides

Structural basis for the fast phase change of Ge $_{2}$ Sb $_{2}$ Te $_{5}$ ; Ring statistics analogy between the crystal and amorphous states

Electronic excitations in hole-doped La $_{1-x}$ Sr $_{x}$ MnO $_{3}$ studied by resonant inelastic X-ray scattering

Resonant O K emission spectroscopy of layered manganate La $_{1.2}$ Sr $_{1.8}$ Mn $_{2}$ O $_{7}$

Resonant Mn Emission spectra of layered manganite La $_{1.2}$ Sr $_{1.8}$ Mn $_{2}$ O $_{7}$

Resonant inelastic X-ray scattering study of the hole-doped manganites La $_{1-x}$ SrMnO (, )

Addendum to $lqlq Doping-Dependent Magnetic Structure of Tb$_{1-x}$$ Ca $_{x}$ MnO $_{3}$ rqrq

Polarization dependence in RIXS of La $_{1-x}$ SrMnO

High-pressure raman spectroscopy of transition metal cyanides