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Journal Articles

Precious metal separations

Narita, Hirokazu*; Kasuya, Ryo*; Suzuki, Tomoya*; Motokawa, Ryuhei; Tanaka, Mikiya*

Encyclopedia of Inorganic and Bioinorganic Chemistry (Internet), 28 Pages, 2020/12

Journal Articles

Nanostructural characterization of oleyl acid phosphate in poly-$$alpha$$-olefin using small-angle X-ray scattering

Oba, Yojiro; Motokawa, Ryuhei; Hino, Masahiro*; Adachi, Nozomu*; Todaka, Yoshikazu*; Inoue, Rintaro*; Sugiyama, Masaaki*

Chemistry Letters, 49(7), p.823 - 825, 2020/07

 Times Cited Count:0 Percentile:100(Chemistry, Multidisciplinary)

Journal Articles

Anomalous small-angle X-ray scattering (ASAXS) study of irradiation-induced nanostructure change in Fe-ion beam irradiated oxide dispersion-strengthened (ODS) steel

Kumada, Takayuki; Oba, Yojiro; Motokawa, Ryuhei; Morooka, Satoshi; Tominaga, Aki; Tanida, Hajime; Shobu, Takahisa; Konno, Azusa; Owada, Kenji*; Ono, Naoko*; et al.

Journal of Nuclear Materials, 528, p.151890_1 - 151890_7, 2020/01

 Times Cited Count:0 Percentile:100(Materials Science, Multidisciplinary)

We have developed an anomalous small-angle X-ray scattering (ASAXS) diffractometer in SPring-8 to investigate irradiation-induced nanostructural change in ion-beam irradiated stainless steel. A thermally-aged MA956 stainless steel sample displays power-law scattering that follows the Porod law at the magnitude of scattering vector, Q, below 0.5 nm$$^-1$$ and an overlapped shoulder around 0.7 nm$$^-1$$. After the ion-beam irradiation, the intensity of the shoulder remained unchanged, whereas that of the power-law scattering nearly doubled. This result indicates that none of the structural parameters of the Cr-rich nanoprecipitates, such as the number density, size, and interface roughness, were changed by the irradiation.

Journal Articles

Proton chelating ligands drive improved chemical separations for rhodium

Narita, Hirokazu*; Nicolson, R. M.*; Motokawa, Ryuhei; Ito, Fumiyuki*; Morisaku, Kazuko*; Goto, Midori*; Tanaka, Mikiya*; Heller, W. T.*; Shiwaku, Hideaki; Yaita, Tsuyoshi; et al.

Inorganic Chemistry, 58(13), p.8720 - 8734, 2019/07

 Times Cited Count:1 Percentile:74.85(Chemistry, Inorganic & Nuclear)

Journal Articles

Extraction performance of a fluorous phosphate for Zr(IV) from HNO$$_{3}$$ solution; Comparison with tri-$$n$$-butyl phosphate

Ueda, Yuki; Kikuchi, Kei; Sugita, Tsuyoshi; Motokawa, Ryuhei

Solvent Extraction and Ion Exchange, 37(5), p.347 - 359, 2019/07

 Times Cited Count:1 Percentile:78.85(Chemistry, Multidisciplinary)

We have newly-designed fluorous phosphate(TFP) for the effective Zr(IV) ion extractant as an alternative extractant against the conventional organic phosphate, tri-$$n$$-butyl phosphate(TBP). Zr(IV) ion extraction system using the TBP has many problems such as the formation of the third phase during liquid-liquid extraction. Here, we develop the fluorous extraction system based on the TFP-perfluorohexane for the Zr(IV) ion extraction to improve the Zr(IV) ion extraction system with an effective extractability and without the third phase formation. Our main findings were that the significant high extraction performance of the TFP for Zr(IV) ion as compared with TBP, and the origins of the high extraction performance of the TFP are related to the water and HNO$$_{3}$$ contents in the fluorous phase and the stability of the complex, Zr(No$$_{3}$$)$$_{4}$$(TFP)$$_{3}$$.

Journal Articles

Structural approach to understanding the solubility of metal hydroxides

Kobayashi, Taishi*; Nakajima, Shogo*; Motokawa, Ryuhei; Matsumura, Daiju; Saito, Takumi*; Sasaki, Takayuki*

Langmuir, 35(24), p.7995 - 8006, 2019/06

 Times Cited Count:1 Percentile:78.85(Chemistry, Multidisciplinary)

Journal Articles

A Telescoping view of solute architectures in a complex fluid system

Motokawa, Ryuhei; Kobayashi, Toru; Endo, Hitoshi; Mu, J.*; Williams, C. D.*; Masters, A. J.*; Antonio, M. R.*; Heller, W. T.*; Nagao, Michihiro*

ACS Central Science, 5(1), p.85 - 96, 2019/01

 Times Cited Count:14 Percentile:9.23(Chemistry, Multidisciplinary)

Journal Articles

A Novel microemulsion phase transition; Toward the elucidation of third-phase formation in spent nuclear fuel reprocessing

Mu, J.*; Motokawa, Ryuhei; Akutsu, Kazuhiro*; Nishitsuji, Shotaro*; Masters, A. J.*

Journal of Physical Chemistry B, 122(4), p.1439 - 1452, 2018/02

 Times Cited Count:10 Percentile:43.52(Chemistry, Physical)

Journal Articles

Comparison of the extractabilities of tetrachloro- and tetrabromopalladate(II) ions with a thiodiglycolamide compound

Narita, Hirokazu*; Maeda, Motoki*; Tokoro, Chiharu*; Suzuki, Tomoya*; Tanaka, Mikiya*; Motokawa, Ryuhei; Shiwaku, Hideaki; Yaita, Tsuyoshi

Analytical Sciences, 33(11), p.1305 - 1309, 2017/11

 Times Cited Count:4 Percentile:77.53(Chemistry, Analytical)

Journal Articles

A Chemiluminescence sensor with signal amplification based on a self-immolative reaction for the detection of fluoride ion at low concentrations

Hisamatsu, Shugo; Suzuki, Shinichi; Komoto, Shigeo*; Kishikawa, Keiki*; Yamamoto, Yusuke*; Motokawa, Ryuhei; Yaita, Tsuyoshi

Tetrahedron, 73(27-28), p.3993 - 3998, 2017/07

 Times Cited Count:9 Percentile:39.39(Chemistry, Organic)

Journal Articles

Calcium-deficient hydroxyapatite as a potential sorbent for strontium

Sekine, Yurina; Motokawa, Ryuhei; Kozai, Naofumi; Onuki, Toshihiko; Matsumura, Daiju; Tsuji, Takuya; Kawasaki, Riku*; Akiyoshi, Kazunari*

Scientific Reports (Internet), 7(1), p.2064_1 - 2064_8, 2017/05

 Times Cited Count:13 Percentile:30.31(Multidisciplinary Sciences)

A calcium (Ca)-deficient hydroxyapatite was investigated for its potential to remove Sr$$^{2+}$$ from environmentally relevant water. We conducted sorption tests on solutions having Mg$$^{2+}$$ and Ca$$^{2+}$$ as competing cations at the Sr$$^{2+}$$ concentration of 0.05 mmol/L. The Ca-deficient hydroxyapatite maintained its high Sr$$^{2+}$$ sorption ratio: the sorption ratio was above 80% in the presence of Mg$$^{2+}$$ and Ca$$^{2+}$$ in the concentrations between 0.1 to 1.0 mmol/L, whereas stoichiometric hydroxyapatite showed a lower ratio even in the presence of small amounts of Mg$$^{2+}$$ and Ca$$^{2+}$$. The bonding states of Sr$$^{2+}$$ onto the Ca-deficient hydroxyapatite were evaluated by extended X-ray absorption fine structure measurements. The results indicated that there are specific sorption sites in Ca-deficient hydroxyapatite where Sr$$^{2+}$$ could be stably and preferentially immobilized.

Journal Articles

Recent research in solvent extraction of platinum group metals

Narita, Hirokazu*; Suzuki, Tomoya*; Motokawa, Ryuhei

Nippon Kinzoku Gakkai-Shi, 81(4), p.157 - 167, 2017/04

 Times Cited Count:4 Percentile:60.39(Metallurgy & Metallurgical Engineering)

Journal Articles

Selective extraction of Pt(IV) over Fe(III) from HCl with an amide-containing tertiary amine compound

Maeda, Motoki*; Narita, Hirokazu*; Tokoro, Chiharu*; Tanaka, Mikiya*; Motokawa, Ryuhei; Shiwaku, Hideaki; Yaita, Tsuyoshi

Separation and Purification Technology, 177, p.176 - 181, 2017/04

 Times Cited Count:9 Percentile:49.88(Engineering, Chemical)

Journal Articles

Small-angle neutron scattering study of specific interaction and coordination structure formed by mono-acetyl-substituted dibenzo-20-crown-6-ether and cesium ions

Motokawa, Ryuhei; Kobayashi, Toru; Endo, Hitoshi*; Ikeda, Takashi; Yaita, Tsuyoshi; Suzuki, Shinichi; Narita, Hirokazu*; Akutsu, Kazuhiro*; Heller, W. T.*

Journal of Nuclear Science and Technology, 53(8), p.1205 - 1211, 2016/08

 Times Cited Count:0 Percentile:100(Nuclear Science & Technology)

Journal Articles

Photonic crystals fabricated by block copolymerization-induced microphase separation

Motokawa, Ryuhei; Taniguchi, Tatsuo*; Kumada, Takayuki; Iida, You*; Aoyagi, Shota*; Sasaki, Yusuke*; Kori, Michinari*; Kishikawa, Keiki*

Macromolecules, 49(16), p.6041 - 6049, 2016/08

 Times Cited Count:4 Percentile:74.99(Polymer Science)

Journal Articles

Neutron polarization analysis for biphasic solvent extraction systems

Motokawa, Ryuhei; Endo, Hitoshi*; Nagao, Michihiro*; Heller, W. T.*

Solvent Extraction and Ion Exchange, 34(5), p.399 - 406, 2016/07

 Times Cited Count:3 Percentile:86.63(Chemistry, Multidisciplinary)

Journal Articles

Comparative molecular dynamics study on tri-$$n$$-butyl phosphate in organic and aqueous environments and its relevance to nuclear extraction processes

Mu, J.*; Motokawa, Ryuhei; Williams, C. D.*; Akutsu, Kazuhiro*; Nishitsuji, Shotaro*; Masters, A. J.*

Journal of Physical Chemistry B, 120(23), p.5183 - 5193, 2016/06

 Times Cited Count:16 Percentile:40.55(Chemistry, Physical)

Journal Articles

Mesoscopic structures of vermiculite and weathered biotite clays in suspension with and without cesium ions

Motokawa, Ryuhei; Endo, Hitoshi*; Yokoyama, Shingo*; Ogawa, Hiroki*; Kobayashi, Toru; Suzuki, Shinichi; Yaita, Tsuyoshi

Langmuir, 30(50), p.15127 - 15134, 2014/12

 Times Cited Count:17 Percentile:40.22(Chemistry, Multidisciplinary)

Journal Articles

Mesoporous silica particles as topologically crosslinking fillers for poly($$N$$-isopropylacrylamide) hydrogels

Miyamoto, Nobuyoshi*; Shimasaki, Kotaro*; Yamamoto, Kosuke*; Shintate, Morio*; Kamachi, Yuichiro*; Bastakoti, B. P.*; Suzuki, Norihiro*; Motokawa, Ryuhei; Yamauchi, Yusuke*

Chemistry; A European Journal, 20(46), p.14955 - 14958, 2014/11

 Times Cited Count:14 Percentile:48.57(Chemistry, Multidisciplinary)

Journal Articles

Collective structural changes in vermiculite clay suspensions induced by cesium ions

Motokawa, Ryuhei; Endo, Hitoshi*; Yokoyama, Shingo*; Nishitsuji, Shotaro*; Kobayashi, Toru; Suzuki, Shinichi; Yaita, Tsuyoshi

Scientific Reports (Internet), 4, p.6585_1 - 6585_6, 2014/10

 Times Cited Count:27 Percentile:24.02(Multidisciplinary Sciences)

110 (Records 1-20 displayed on this page)