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Murata, Masaki*; Sasaki, Akira; Kanamaru, Toshiyuki*; Shirado, Tamotsu*; Isahara, Hitoshi*
Jinko Chino Gakkai Rombunshi, 23(6), p.457 - 462, 2008/11
Sasaki, Akira; Nishihara, Katsunobu*; Murata, Masaki*
Purazuma, Kaku Yugo Gakkai-Shi, 84(8), p.546 - 554, 2008/08
no abstracts in English
Wada, Atsushi*; Watanabe, Masayuki; Yamanoi, Yoshinori*; Nankawa, Takuya; Namiki, Kosuke*; Yamasaki, Mikio*; Murata, Masaki*; Nishihara, Hiroshi*
Bulletin of the Chemical Society of Japan, 80(2), p.335 - 345, 2007/02
Times Cited Count：22 Percentile：57.38(Chemistry, Multidisciplinary)Lanthanide complexes with linear and cyclic octadentate oligopyridine-amine ligands were synthesized, and their molecular structures were determined by single-crystal X-ray crystallography. All of the complexes had a distorted capped square antiprism (CSAP) geometry, and the coordination environments of lanthanide complexes were more distortedfor the complexes with the linear ligand than those with the cyclic ligand. The Eu
complexes with the linear ligand showed more intense emissions, which were attributed to the 
D
F
transition, than the complex withthe cyclic ligand in acetonitrile, which can be attributed to the distortion in the coordination environments. These results indicate that the coordination environments of lanthanide complexes, and thus the luminescence properties, can be controlled by tuning the geometrical structures of polydentate ligands.
Sasaki, Akira; Murata, Masaki*; Kanamaru, Toshiyuki*; Shirado, Tamotsu*; Isahara, Hitoshi*; Ueshima, Yutaka; Yamagiwa, Mitsuru
Purazuma, Kaku Yugo Gakkai-Shi, 81(9), p.717 - 722, 2005/09
no abstracts in English
Watanabe, Masayuki; Nankawa, Takuya*; Yamada, Teppei*; Kimura, Takaumi; Namiki, Kosuke*; Murata, Masaki*; Nishihara, Hiroshi*; Tachimori, Shoichi
Inorganic Chemistry, 42(22), p.6977 - 6979, 2003/11
Times Cited Count：34 Percentile：75.29(Chemistry, Inorganic & Nuclear)A tripodal ligand, tris(2-pyridyl)carbinol affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distance between the metal ions. Strong fluorescence of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to Eu(III) and Tb(III) center.
Sasaki, Akira; Murata, Masaki*; Kashiwagi, Hiroe*; Jo, Kazuki*; Lukas, P.*; Kato, Daiji*; Murakami, Izumi*
no journal, ,
no abstracts in English
Wada, Atsushi; Watanabe, Masayuki; Yamanoi, Yoshinori*; Murata, Masaki*; Nishihara, Hiroshi*
no journal, ,
Lanthanide complexes with linear and cyclic octadentate oligopyridine-amine ligands were newly synthesized, and their molecular structures were determined by single-crystal X-ray crystallography. All of the complexes formed with the distorted CSAP geometry, the symmetry of which was higher for the complexes with the cyclic ligand than those with the linear ligand. The Eu and Tb complexes showed intense luminescence due to energy transfer from the ligand to the metal center (antenna effect). The Eu complexes with the linear ligand showed more intense emissions attributed to the 5D07F2 transition than the complex with the cyclic ligand, which can be explained by the decrease in symmetry around the lanthanide ion. The coordination of water molecules to Eu and Tb ions was strongly inhibited by surrounding the metal ions with the cyclic ligand, resulting in an appearance of intense luminescence in water. These results indicate that the symmetry and stability of lanthanide complexes, and thus the luminescence properties, can be successfully controlled by tuning the geometrical structures of multi-dentate ligands.
Watanabe, Masayuki; Nankawa, Takuya; Wada, Atsushi*; Namiki, Kosuke*; Murata, Masaki*; Nishihara, Hiroshi*; Kimura, Takaumi
no journal, ,
A tripodal ligand, tris(2-pyridyl)carbinol affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. Structures of dinuclear complexes synthesized from triflates exhibited the same structure other than the difference in the bond lengths which was induced by lanthanide contraction across the lanthanide series from Pr to Lu. In these complexes, the distance between two lanthanide ions was remarkably short. In this study the same type of dinuclear complexes were synthesized from nitrates. The nitrate ion can coordinate in both monodentate fand bidentate fashions. Since ionic radii are dependent upon the coordination number, nitrate could affect the metal-metal distance. In fact, dinuclear complexes exhibited longer distance between lanthanide ions than the triflates due to the increase of ionic radii of lanthanide ions. Some features of these dinuclear systems, which are induced from the difference of metal-metal distance, will be discussed in the presentation.
Watanabe, Masayuki; Ishimori, Kenichiro; Wada, Atsushi*; Kataoka, Yumiko*; Murata, Masaki*; Shinoda, Satoshi*; Nishihara, Hiroshi*; Tsukube, Hiroshi*; Kimura, Takaumi
no journal, ,
Soft-donor extractants containing sulfur- or nitrogen-donor are applicable to the separation of trivalent actinides (An(III)) from lanthanides (Ln(III)) by solvent extraction method. We designed two ligand systems which are expected to efficiently separate An(III) from Ln(III). The one is "Oligo-pyridine" ligand containing multiple pyridine moieties. The other is "Chirality-controlled" ligand containing chiral centers in the ligand. We synthesized more than thirty ligands and found out the ability on the separation of An(III) from Ln(III). In this presentation, we will discuss about the comprehensive results on the separation ability of An(III) from Ln(III) by means of "Oligo-pyridine" and "Chirality-controlled" ligands, and the extraction equilibrium of An(III) with selected tripodal ligands in detail.
Yamaguchi, Hiromi; Miyamoto, Yasuaki; Sakakibara, Tetsuro; Hanamoto, Yukio; Aoyama, Yoshio; Sasaki, Nao*; Nishikawa, Tsutomu*; Murata, Minoru*; Muroi, Masayuki*; Park, J.*; et al.
no journal, ,
no abstracts in English
Yamaguchi, Hiromi; Miyamoto, Yasuaki; Sakakibara, Tetsuro; Hanamoto, Yukio; Aoyama, Yoshio; Sasaki, Nao*; Nishikawa, Tsutomu*; Murata, Minoru*; Muroi, Masayuki*; Park, J.*; et al.
no journal, ,
no abstracts in English
Aoyama, Yoshio; Yamaguchi, Hiromi; Miyamoto, Yasuaki; Sakakibara, Tetsuro; Hanamoto, Yukio; Sasaki, Nao*; Nishikawa, Tsutomu*; Murata, Minoru*; Muroi, Masayuki*; Park, J.*; et al.
no journal, ,
no abstracts in English
Aoyama, Yoshio; Yamaguchi, Hiromi; Sakakibara, Tetsuro; Hanamoto, Yukio; Murata, Minoru*; Sasaki, Nao*; Nishikawa, Tsutomu*; Taniguchi, Shoji*; Shimazaki, Shinichi*; Park, J.*; et al.
no journal, ,
no abstracts in English
Aoyama, Yoshio; Yamaguchi, Hiromi; Sakakibara, Tetsuro; Hanamoto, Yukio; Murata, Minoru*; Sasaki, Nao*; Nishikawa, Tsutomu*; Taniguchi, Shoji*; Shimazaki, Shinichi*; Park, J.*; et al.
no journal, ,
no abstracts in English
Aoyama, Yoshio; Yamaguchi, Hiromi; Sakakibara, Tetsuro; Hanamoto, Yukio; Murata, Minoru*; Sasaki, Nao*; Nishikawa, Tsutomu*; Taniguchi, Shoji*; Shimazaki, Shinichi*; Park, J.*; et al.
no journal, ,
no abstracts in English
Sasaki, Akira; Nishihara, Katsunobu*; Sunahara, Atsushi*; Furukawa, Hiroyuki*; Nishikawa, Takeshi*; Koike, Fumihiro*; Murata, Masaki*
no journal, ,
We present calculation of atomic data and development of atomic model of Sn and Xe ions, for the theoretical investigation and optimization of the EUV source for the next generation microlithography. In order to evaluate radiative properties of Sn and Xe ions, measurement of accurate wavelengths of strong emission lines as well as determination of dominant satellite channels from multiply- and inner-shell excited states are essential. We apply database technologies to choose a set of atomic levels, which has significant contribution to the emission. After iterative calculation, an appropriate atomic model which gives reasonable values of coefficients of radiative transfer is obtained.
