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and CrUOAkiyama, Daisuke*; Kusaka, Ryoji; Kumagai, Yuta; Nakada, Masami; Watanabe, Masayuki; Okamoto, Yoshihiro; Nagai, Takayuki; Sato, Nobuaki*; Kirishima, Akira*
Journal of Nuclear Materials, 568, p.153847_1 - 153847_10, 2022/09
Times Cited Count：4 Percentile：54.60(Materials Science, Multidisciplinary)FeUO, CrUO, and Fe
Cr
UO are monouranates containing pentavalent U. Even though these compounds have similar crystal structures, their formation conditions and thermal stability are significantly different. To determine the factors causing the difference in thermal stability between FeUO and CrUO, their crystal structures were evaluated in detail. A Raman band was observed at 700 cm
in all the samples. This Raman band was derived from the stretching vibration of the O-U-O axis band, indicating that FeCrUO was composed of a uranyl-like structure in its lattice regardless of its "x"' value. M
ssbauer measurements indicated that the Fe in FeUO and FeCrUO were trivalent. Furthermore, FeCrUO lost its symmetry around Fe
with increasing electron densities around Fe, as the abundance of Cr increased. These results suggested no significant structural differences between FeUO and CrUO. Thermogravimetric measurements for UO
, FeUO, and CrUO showed that the temperature at which FeUO decomposed under an oxidizing condition (approximately 800 
C) was significantly lower than the temperature at which the decomposition of CrUO started (approximately 1250 C). Based on these results, we concluded that the decomposition of FeUO was triggered by an "in-crystal" redox reaction, i.e., Fe 
U
Fe
U
, which would not occur in the CrUO lattice because Cr could never be reduced under the investigated condition. Finally, the existence of Cr in FexCrUO effectively suppressed the decomposition of the FeCrUO crystal, even at a very low Cr content.
Inagawa, Jun; Kitatsuji, Yoshihiro; Otobe, Haruyoshi; Nakada, Masami; Takano, Masahide; Akie, Hiroshi; Shimizu, Osamu; Komuro, Michiyasu; Oura, Hirofumi*; Nagai, Isao*; et al.
JAEA-Technology 2021-001, 144 Pages, 2021/08
JAEA-Technology-2021-001.pdf:12.98MB
Plutonium Research Building No.1 (Pu1) was qualified as a facility to decommission, and preparatory operations for decommission were worked by the research groups users and the facility managers of Pu1. The operation of transportation of whole nuclear materials in Pu1 to Back-end Cycle Key Element Research Facility (BECKY) completed at Dec. 2020. In the operation included evaluation of criticality safety for changing permission of the license for use nuclear fuel materials in BECKY, cask of the transportation, the registration request of the cask at the institute, the test transportation, formulation of plan for whole nuclear materials transportation, and the main transportation. This report circumstantially shows all of those process to help prospective decommission.
Segawa, Yukari; Horita, Takuma; Kitatsuji, Yoshihiro; Kumagai, Yuta; Aoyagi, Noboru; Nakada, Masami; Otobe, Haruyoshi; Tamura, Yukito*; Okamoto, Hisato; Otomo, Takashi; et al.
JAEA-Technology 2016-039, 64 Pages, 2017/03
JAEA-Technology-2016-039.pdf:5.24MB
The laboratory building No.1 for the plutonium research program (Bldg. Pu1) was chosen as one of the facilities to decommission by Japan Atomic Energy Agency Reform in September, 2013. The research groups, users of Bldg. Pu1, were driven by necessity to remove used equipment and transport nuclear fuel to other facilities from Bldg. Pu1. Research Group for Radiochemistry proactively established the Used Equipment Removal Team for the smooth operation of the removal in April, 2015. The team classified six types of work into the nature of the operation, removal of used equipment, disposal of chemicals, stabilization of mercury, stabilization of nuclear fuel, transportation of nuclear fuel and radioisotope, and survey of contamination status inside the glove boxes. These works were completed in December, 2015. This report circumstantially shows six works process, with the exception of the approval of the changes on the usage of nuclear fuel in Bldg. Pu1 to help prospective decommission.
Okamoto, Yoshihiro; Shiwaku, Hideaki; Nakada, Masami; Komamine, Satoshi*; Ochi, Eiji*; Akabori, Mitsuo
Journal of Nuclear Materials, 471, p.110 - 115, 2016/02
Times Cited Count：6 Percentile：45.58(Materials Science, Multidisciplinary)Extended X-ray Absorption Fine Structure (EXAFS) analyses were performed to evaluate REDOX (REDuction and OXidation) state of platinoid elements in simulated high-level nuclear waste glass samples prepared under different conditions of temperature and atmosphere. At first, EXAFS functions were compared with those of standard materials such as RuO
. Then structural parameters were obtained from a curve fitting analysis. In addition, a fitting analysis used a linear combination of the two standard EXAFS functions of a given elements metal and oxide was applied to determine ratio of metal/oxide in the simulated glass. The redox state of Ru was successfully evaluated from the linear combination fitting results of EXAFS functions. The ratio of metal increased at more reducing atmosphere and at higher temperatures. Chemical form of rhodium oxide in the simulated glass samples was RhO unlike expected RhO
. It can be estimated rhodium behaves according with ruthenium when the chemical form is oxide.
Sn conductor for ITER central solenoidTakahashi, Yoshikazu; Nabara, Yoshihiro; Ozeki, Hidemasa; Hemmi, Tsutomu; Nunoya, Yoshihiko; Isono, Takaaki; Matsui, Kunihiro; Kawano, Katsumi; Oshikiri, Masayuki; Uno, Yasuhiro; et al.
IEEE Transactions on Applied Superconductivity, 24(3), p.4802404_1 - 4802404_4, 2014/06
Times Cited Count：28 Percentile：74.09(Engineering, Electrical & Electronic)Japan Atomic Energy Agency (JAEA) is procuring all amounts of NbSn conductors for Central Solenoid (CS) in the ITER project. Before start of mass-productions, the conductor should be tested to confirm superconducting performance in the SULTAN facility, Switzerland. The original design of cabling twist pitches is 45-85-145-250-450 mm, called normal twist pitch (NTP). The test results of the conductors with NTP was that current shearing temperature (Tcs) is decreasing due to electro-magnetic (EM) load cycles. On the other hand, the results of the conductors with short twist pitches (STP) of 25-45-80-150-450 mm show that the Tcs is stabilized during EM load cyclic tests. Because the conductors with STP have smaller void fraction, higher compaction ratio during cabling is required and possibility of damage on strands increases. The technology for the cables with STP was developed in Japanese cabling suppliers. The several key technologies will be described in this paper.
Okamoto, Yoshihiro; Nakada, Masami; Akabori, Mitsuo; Komamine, Satoshi*; Fukui, Toshiki*; Ochi, Eiji*; Nitani, Hiroaki*; Nomura, Masaharu*
Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 81(7), p.543 - 546, 2013/07
Times Cited Count：8 Percentile：19.22(Electrochemistry)The molten state of simulated high-level waste glass and the behavior of ruthenium element in the melt were investigated by using synchrotron radiation based X-ray imaging technique. Melting, generating and moving of bubbles, condensation and sedimentation of ruthenium element were observed dynamically in continuous 12-bit gray-scale images from the CCD camera. X-ray intensity was obtained easily by digitizing gray-scale values in the image. The existence of ruthenium element is emphasized as a black color in the CCD image at X-ray energy higher than the Ru K-absorption edge. Position sensitive imaging X-ray absorption fine structure (XAFS) measurement was also performed to clarify the chemical state of ruthenium element in the melt.
Okamoto, Yoshihiro; Nakada, Masami; Akabori, Mitsuo; Komamine, Satoshi*; Fukui, Toshiki*; Ochi, Eiji*; Nitani, Hiroaki*; Nomura, Masaharu*
Proceedings of 4th Asian Conference on Molten Salt Chemistry and Technology & 44th Symposium on Molten Salt Chemistry, Japan, p.47 - 52, 2012/09
The molten state of the simulated high-level waste glass and the behavior of ruthenium element in the melt were investigated by using synchrotron radiation based X-ray imaging technique. Melting, generating and moving of bubbles, condensation and sedimentation of ruthenium element were observed dynamically in continuous 12-bit gray-scale images from the CCD camera. The existence of ruthenium in the X-ray CCD image was emphasized over the energy of Ru K-absorption edge. X-ray intensity was obtained easily by digitalizing gray-scale values in the image. Position sensitive imaging X-ray absorption fine structure (XAFS) measurement was performed to clarify the chemical state of ruthenium element in the melt.
Okamoto, Yoshihiro; Nakada, Masami; Akabori, Mitsuo; Shiwaku, Hideaki; Komamine, Satoshi*; Fukui, Toshiki*; Ochi, Eiji*; Nitani, Hiroaki*; Nomura, Masaharu*
Nihon Genshiryoku Gakkai Wabun Rombunshi, 11(2), p.127 - 132, 2012/06
Distribution and the chemical state of Ru element in the simulated high-level waste glass were examined by using the synchrotron radiation based X-ray imaging technique. In this technique, a direct X-ray CCD camera is used in place of an ion chamber. Position sensitive X-ray absorption spectra were obtained by analyzing gray scale in images of the X-ray CCD camera. At first, we measured a test sample containing RuO and Ru metal powder. We successfully obtained information on the Ru distribution in the sample. In addition, the chemical state (oxide or metal ?) of each small Ru-rich spot was evaluated by the corresponding position sensitive XAFS spectrum. The imaging XAFS technique was applied to some simulated high-level waste glass samples. The Ru distribution of the glass sample and their chemical state were confirmed by image analyses. It can be seen that Ru element scattered in the glass sample exists as oxide RuO.
Am
)O
Nishi, Tsuyoshi; Nakada, Masami; Suzuki, Chikashi; Shibata, Hiroki; Okamoto, Yoshihiro; Akabori, Mitsuo; Hirata, Masaru
Journal of Nuclear Materials, 418(1-3), p.311 - 312, 2011/11
Times Cited Count：20 Percentile：79.81(Materials Science, Multidisciplinary)The XAFS measurements at U-L
and Am-L absorption edge of (UAm)O were performed in transmission mode. Moreover, to clarify the valence state of Am in (U,Am)O
, the XANES spectrum of Am-L absorption edge of (UAm)O was verified using those of Am-L absorption edge of AmO and AmO. It was found that the XANES spectrum of the Am-L edge of (UAm)O is in good accordance with that of AmO. Thus, Am in (UAm)O is almost trivalent state.
Amamoto, Ippei; Mitamura, Naoki*; Tsuzuki, Tatsuya*; Takasaki, Yasushi*; Shibayama, Atsushi*; Yano, Tetsuji*; Nakada, Masami; Okamoto, Yoshihiro
Proceedings of 13th International Conference on Environmental Remediation and Radioactive Waste Management (ICEM 2010) (CD-ROM), p.503 - 508, 2010/10
The main objective of this development is to recycle the purified eutectic medium of the pyroreprocessing, delaying its disposal for as long as possible. We have introduced the simple filtration method to remove the rare earth element (REE) particles which were formed due to the conversion of REE chlorides to phosphates. Here, the iron phosphate glass is used as a filtration medium for the removal of FP particles. However, some soluble FP such as compounds of alkali-metals, alkaline-earth metals, etc. still remain in the eutectic medium. This time around, on an experimental basis, the iron phosphate glass has been used as a sorbent instead, to remove the soluble FP. We have obtained some positive results and have intention to incorporate it into the spent electrolyte recycle process as a part of the FP separation and immobilization system.
Okamoto, Yoshihiro; Shiwaku, Hideaki; Nakada, Masami; Takano, Masahide; Akabori, Mitsuo; Komamine, Satoshi*; Fukui, Toshiki*; Ochi, Eiji*
no journal, ,
Chemical properties and behavior of insoluble residue in the cold cap of simulated high-level waste glass was examined by using synchrotron radiation based imaging and XAFS analyses. From XAFS analyses of Zr, Mo and Ce, (1) Zr is in a complex oxide like ZrSiO
or Zr(MoO), (2) The complex MoO
ion is predominant for Mo element, (3) Redox state for cerium element was evaluated from Ce L-edge XAFS, and (4) Chemical state of cerium was determined from Ce K-edge XAFS. Chemical state and bubble growth at molten state was investigated by using X-ray imaging analysis.
Nishi, Tsuyoshi; Nakada, Masami; Suzuki, Chikashi; Shibata, Hiroki; Okamoto, Yoshihiro; Akabori, Mitsuo; Hirata, Masaru
no journal, ,
no abstracts in English
Okamoto, Yoshihiro; Nakada, Masami; Akabori, Mitsuo; Minato, Kazuo; Shiwaku, Hideaki; Komamine, Satoshi*; Fukui, Toshiki*; Nitani, Hiroaki*; Nomura, Masaharu*
no journal, ,
Chemical state analysis of Ru element scattered in an imitative glass matrix was performed by using the Imaging XAFS technique. Information on distribution of Ru element in the matrix was obtained from contrast values of CCD images before and after the Ru K-absorption edge. It is confirmed that the feature of the distributed element can be examined by getting XAFS spectra from the contrast information. We can get two kinds of XAFS spectra corresponding to Ru metal and oxide separately in the Imaging XAFS analysis.
Sato, Kaoru; Takahashi, Fumiaki; Koba, Yusuke*; Ono, Koji*; Yoshitake, Takayasu*; Hasegawa, Takayuki*; Katsunuma, Yasushi*; Kasahara, Tetsuji*; Okuda, Yasuo*; Nakada, Yoshihiro*; et al.
no journal, ,
JAEA is now developing CT dose calculator named WAZA-ARIv2 in cooperation with the National Institute of Radiological Sciences. WAZA-ARIv2 has been opened to the public as full-dress uses on January 2015. WAZA-ARIv2 can perform dose assessment against 4 different body physiques by using the organ dose database, which were constructed on the basis of adult Japanese phantoms with 4 body sizes (-2
, average, +2, +5). In this study, it was found that salivary gland doses are independent on BMI, whereas lung doses are dependent on BMI. The differences in the effects of BMI on absorbed doses between salivary glands and lungs might be caused by the difference in thickness of subcutaneous soft tissues between head and thorax.
Sato, Kaoru; Takahashi, Fumiaki; Koba, Yusuke*; Ono, Koji*; Yoshitake, Takayasu*; Hasegawa, Takayuki*; Katsunuma, Yasushi*; Kasahara, Tetsuji*; Okuda, Yasuo*; Nakada, Yoshihiro*; et al.
no journal, ,
WAZA-ARIv2 is developed as the web-based open system for CT dose calculator under joint research of JAEA, NIRS (now, QST) and Oita University of Nursing and Health Sciences. WAZA-ARIv2 can provide organ doses under consideration of the body physiques (BMI = 18, 22, 28, 37) of patients with average height of adult Japanese by using voxel phantoms developed by JAEA. In this study, we analyzed the relationship between variations of organ doses and body indices. It was found that effects of weight variations on organ doses were larger than those of height variations. Generally, thickness of the subcutaneous soft tissues is easily changed by variations of weight rather than those of height. This fact may cause the differences in variations of organ doses between weight and height.
-emitting nuclides analysis of the stagnant water including sediments in Fukushima Daiichi NPS, 4; Fe analysis of particulate solids in the contaminated water at Fukushima Daiichi NPS by Mssbauer spectroscopyOuchi, Kazuki; Nakada, Masami; Yomogida, Takumi; Oka, Toshitaka; Koma, Yoshikazu; Kitatsuji, Yoshihiro
no journal, ,
In order to understand the chemical form of particulate solids contained in the retained water at three locations of Fukushima Daiichi NPS, the chemical species of Fe which is the main constituent element of solids were analyzed with Mssbauer spectroscopy. Most Fe was found to be 
-form Fe(III) oxyhydroxide. Small amounts of Fe(II) hydroxide and magnetic substance were also detected in the torus and tank samples, respectively.
ssbauer spectroscopyMorii, Shiori; Yomogida, Takumi; Nakada, Masami; Oka, Toshitaka; Kitatsuji, Yoshihiro; Takahashi, Yoshio*
no journal, ,
To understand the influence of redox properties of structural Fe in clay minerals on removal and immobilization of radionuclides in geological disposal environment, we are investigating redox and structural properties of Fe in clay minerals over a large range of redox potentials. Clay mineral sample was reduced by controlled-potential electrolysis. Redox state and structural properties of Fe in this prepared clay mineral sample was investigated by Fe-57 Mssbauer spectroscopy. From the Mssbauer spectra, we obtained information about the amount of structural Fe(II) which reduced from structural Fe(III) and structural properties of Fe(II).
Okamoto, Yoshihiro; Nakada, Masami; Takano, Masahide; Akabori, Mitsuo; Komamine, Satoshi*; Fukui, Toshiki*; Ochi, Eiji*
no journal, ,
no abstracts in English
Nagayama, Sachiko; Okamoto, Yoshihiro; Shiwaku, Hideaki; Nakada, Masami; Akabori, Mitsuo; Kawashima, Hidenori*; Komamine, Satoshi*; Ochi, Eiji*
no journal, ,
no abstracts in English
Osugi, Takeshi; Okamoto, Yoshihiro; Shiwaku, Hideaki; Kobayashi, Toru; Nakada, Masami; Nakashio, Nobuyuki; Akabori, Mitsuo; Yaita, Tsuyoshi
no journal, ,
High-energy quick-scan XAFS(QXAFS) technique was used to study chemical state of Ce element in molten slug matrix. The QXAFS measurement for Ce-K absorption edge (E
= 40.443 keV) was carried out for the sample (5% CeO in SiO-CaO-FeO matrix) at 1500C. As the result of EXAFS analysis, it can be seen that the nearest Ce-O distance and its coordination number decrease by melting and the similar structure having low structural order is kept after solidifying. These results suggests that Ce exists stably as trivalent in glass phase.
