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JAEA Reports

Development of the conductive glove for glove box operation; Production of prototypes and their experimental results

Kodato, Kazuo; Enuma, Masahito; Kawasaki, Takeshi; Nogami, Yoshitaka; Kaneko, Kazunori; Kimura, Masanori*; Yasumori, Tomokazu*

JAEA-Research 2013-017, 45 Pages, 2014/02

JAEA-Research-2013-017.pdf:3.98MB

The glove used at glove boxes in the nuclear fuel plants is usually made with Chlorosulfonated polyethylene rubber. The rubber is excellent in terms of resistance to radiation because it has no double bond in its main chain of the component, however, it deteriorates rapidly in high dose environment such as direct contact of alpha ray1). Plutonium oxide powder is treated in glove boxes at plutonium fuel facilities where the alpha ray from plutonium oxide power attached on surface of a glove causes the deterioration of the rubber. Therefore the effective method for prevent of the rapid deterioration is to decrease the amount of attached powder, and the glove with conductive property which can prevent static generation on its surface has been developed and tested. The results showed that the rubber has less adherent property to powder compared with conventional one.

JAEA Reports

Alpha-ray irradiation damage on diverse rubber materials applied to glove box for plutonium treatment

Saito, Kosuke; Nogami, Yoshitaka; Kodato, Kazuo; Matsuyama, Kazutomi; Endo, Hideo

JAEA-Research 2012-027, 118 Pages, 2012/09

JAEA-Research-2012-027.pdf:21.12MB

This report is compilation of 4 years tests and experiments of simulated alpha-ray irradiation on diverse materials for glove box application at Plutonium Fuel Development Center, Tokai, JAEA. Specimens prepared from the materials are irradiated with $$^{4}$$He$$^{2+}$$ ion beam whose kinetic energy was 5 MeV and sent to exterior observation, optical microscopy and tensile tests. Experiments revealed ion-irradiation generally makes tens of micrometers of deteriorated layer which is hardened and discolored on the surface of the specimens. According to dose, tensile properties such as tensile strength and elongation at break decrease generally. Tensile strength decrease is expected to ascribe to stress concentration on cracks of irradiation-damaged surface and rupture. Lead-contained glove, which is ordinarily used on highly $$gamma$$-radiative environments, saturates the decrease of its tensile strength around fluence of 1.4e+14 cm$$^{-2}$$. In addition, deterioration was accelerated for tension-loaded material and the saturation is around 4.6e+13 cm$$^{-2}$$ for 100%-extended specimens. The candidates of alternative new materials are two kinds of developed chlorosulfonated polyethylene (CSM) and conductive rubber, which were experimented and tested in like manner. From the results and inherent properties of these materials, one kind of CSM and conductive rubber are relatively promising. Gloves used at low-dose environments and vinyl chloride applied for glove ports were also experimented and tested, and quantitative data were which are useful for life-elongation measure obtained. The irradiation tests on this report are unprecedented ones with low-energy ion, and the obtained quantitative data of material properties and deterioration are scientifically rare and important.

Oral presentation

Development of the conductive glove for glove box operation; Production of prototypes and their experimental results

Kodato, Kazuo; Enuma, Masahito; Kawasaki, Takeshi; Nogami, Yoshitaka; Kaneko, Kazunori; Yoshizawa, Kosuke*; Yasumori, Tomokazu*

no journal, , 

The glove used at glove boxes in the nuclear fuel plants is usually made with Chlorosulfonated polyethylene rubber. The rubber is excellent in terms of resistance to radiation because it has no double bond in its main chain of the component, however, it deteriorates rapidly in high dose environment such as direct contact of alpha ray1). Plutonium oxide powder is treated in glove boxes at plutonium fuel facilities where the alpha ray from plutonium oxide power adhered on surface of a glove causes the deterioration of the rubber. Therefore the effective method for prevent of the rapid deterioration is to decrease the amount of adhered powder, and the glove with conductive property which can prevent static electric charge on its surface has been developed and tested. The results showed that the rubber has less adherent property to powder compared with conventional one.

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