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Oral presentation

Development of diffraction gratings coated with diamond like carbon (DLC)-based multilayer for high sensitivity detection of K emission of boron

Koike, Masato; Imazono, Takashi; Koeda, Masaru*; Nagano, Tetsuya*; Sasai, Hiroyuki*; Oue, Yuki*; Kuramoto, Satoshi*; Terauchi, Masami*; Takahashi, Hideyuki*; Notoya, Satoshi*; et al.

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An addition of small amount of boron to steal materials is known well that a it causes a big influence on the characteristic of steel materials, for example, an internal structure and intensity (hardness, toughness), corrosion resistance, heat resistance, and magnetic property. Although the nuclear steel which added boron attracted attention from half century ago, the research on boron steel serves as serious concerns from the standpoints to saving resources and a weight saving in the materials science field as a thin board steel plate used for vehicles etc. recently focusing on the industrial world. However, as compared with the element of others the amount of boron is remarkably small, generally 5-30 ppm, an understanding about the action of boron is not fully understood. To contribute to the X ray emission-spectrochemical-analysis research in the B-K luminescence line (wavelength: 6.76 nm, energy: 183.3 eV) neighborhood, high diffraction efficiency laminar-type diffraction gratings with multilayer film containing diamond-like carbon (DLC) system on the surface newly is under development, and, here, we report the newly designed gratings.

Oral presentation

Design of high efficiency diffraction grating by use of diamond like carbon for the detection of Li-K emission

Koike, Masato; Imazono, Takashi; Ishino, Masahiko; Nagano, Tetsuya*; Sasai, Hiroyuki*; Oue, Yuki*; Kuramoto, Satoshi*; Terauchi, Masami*; Takahashi, Hideyuki*; Notoya, Satoshi*; et al.

no journal, , 

The information about the chemical bond state when lithium ion went in and out of anode and cathode materials can be obtained by the measurements of Li-K emission of light around 22.8 nm (54.3 eV) released in the mild process of the valence band electron when a K-shell electron was activated. Conventinal amorphous carbon (C) film (density: 2.2 g/cm$$^{3}$$) or a high-density diamond like carbon (DLC) film (Tetrahedral amorphous carbon, density: 3.1 g/cm$$^{3}$$) was deposited on the diffraction gratings which the Au film which is a standard surface material to realize high sensitivity Li-K emission spectrum measurement. The DLC can be doposied by filtered arc method. In this paper we describe the design of the multilayered diffraction grating aiming at improvement of the diffraction efficiency.

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